聚醚有机硅表面活性剂与经典阴离子表面活性剂复配体系

doi:10.3969/j.issn.2097-2806.2024.10.002

摘要/Abstract

摘要：

聚醚有机硅表面活性剂因其良好的表面活性近年来受到广泛关注。为了进一步扩展其下游应用空间，开发复合表面活性剂配方，文章将一种寡聚醇聚醚三硅氧烷表面活性剂与经典阴离子表面活性剂（烷基糖苷磺酸盐和醇醚磷酸盐）复配，详细探究了二元表面活性剂混合体系的混合吸附参数和混合胶束参数。随后围绕精选的复配比例，对二元表面活性剂的分散（泡沫、乳液、悬浮液）性能在常见模型体系中进行了初步探究，为聚醚硅表面活性剂体系的应用开发提供了重要的基础参考。

关键词: 表面活性, 阴-非离子表面活性剂复配, 分散性能

Abstract:

Polyether organosilicon surfactants have received widespread attention in recent years due to their excellent surface activities. To further expand the downstream application and develop a surfactant formula, in this work, a polyether modified trisiloxane surfactant was mixed with a classical anionic surfactant （alkyl glycoside sulfonate or fatty-alcohol polyethoxylate phosphate）, and the mixed adsorption parameters and mixed micellization parameters of the binary surfactant mixtures were investigated in detail. For the selected mixing ratio, the dispersing performance of binary surfactant mixtures was evaluated in common model systems （foam, emulsion, suspension）, which could provide an important reference for the application and development of systems of polyether modified silicone surfactants.

Key words: surface activity, mixture of anionic and nonionic surfactants, dispersion

中图分类号:

TQ423

梁馨支, 孙婷, 叶馨遥, 王宇凯, 白亮, 李洪光. 聚醚有机硅表面活性剂与经典阴离子表面活性剂复配体系[J]. 日用化学工业（中英文）, 2024, 54(10): 1155-1165.

Xinzhi Liang, Ting Sun, Xinyao Ye, Yukai Wang, Liang Bai, Hongguang Li. Study on the mixed systems of polyether organosilicon surfactant and classic anionic surfactants[J]. China Surfactant Detergent & Cosmetics, 2024, 54(10): 1155-1165.

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	α₁^*	cmc/ （mol/L）	γ_cmc/ （mN/m）	pc₂₀	Г_max/ （μmol/m²）	A_min/nm²	cmc _ideal/ （mol/L）	Γ_{max, ideal}/ （μmol/m²）	A_{min, ideal}/nm²
APG-SS/PTS	1	4.15×10^-4	31.78	3.15	4.58	0.36
	0.8	3.56×10^-4	25.46	5.12	2.68	0.62	3.067×10^-4	2.99	0.55
	0.5	3.18×10^-4	21.97	5.22	2.29	0.73	2.204×10^-4	2.85	0.58
	0.2	1.85×10^-4	21.79	5.39	2.37	0.70	1.720×10^-4	2.75	0.60
	0	1.50×10^-4	21.42	5.58	2.48	0.67
AEP-K/PTS	1	3.05×10^-5	39.91	5.26	3.34	0.50
	0.8	3.89×10^-5	39.70	5.04	3.47	0.48	3.594×10^-5	3.001 8	0.55
	0.5	4.49×10^-5	38.96	5.20	1.98	0.84	5.028×10^-5	2.595 0	0.64
	0.2	1.14×10^-4	30.91	5.31	2.19	0.76	8.364×10^-5	2.564 1	0.65
	0	1.50×10^-4	21.42	5.58	2.48	0.67

	α₁^*	X^m₁	β^m	f ^m₁	f ^m₂	X^σ₁	β^σ	f ^σ₁	f ^σ₂
APG-SS/PTS	0.8	0.562	-4.970	0.386	0.208	0.373	-7.593	0.051	0.347
	0.5	0.209	-4.035	0.080	0.839	0.285	-8.642	0.012	0.495
	0.2	0.190	-6.214	0.017	0.799	0.212	-9.535	0.003	0.652
AEP-K/PTS	0.8	0.752	-8.122	0.608	0.010	0.678	-2.632	0.761	0.299
	0.5	0.678	-6.601	0.504	0.048	0.172	-4.217	0.056	0.882
	0.2	0.547	-4.310	0.413	0.275	0.127	-6.044	0.010	0.907

	α₁	ΔG_{mic, ideal}/ （KJ/mol）	ΔG_mic/ （KJ/mol）	ΔH_mic/ （KJ/mol）	TΔS_mic/ （KJ/mol）
APG-SS/PTS	0.8	-1.699	-4.731	-3.032	1.699
	0.5	-1.270	-2.923	-1.653	1.270
	0.2	-1.205	-3.574	-2.369	1.205
AEP-K/PTS	0.8	-1.387	-5.137	-3.75	1.387
	0.5	-1.558	-5.132	-3.574	1.558
	0.2	-1.707	-4.354	-2.647	1.707

样品名称	n	t^*/s	t_i/s	t_m/s	R_1/2/（mN/（m·s））
APG-SS/PTS	0.352	0.372	5.37×10^-4	258	50.86
AEP-K/PTS	0.417	0.023	9.41×10^-5	5.89	804.78