增稠剂及工艺对蔗糖酯乳化体系产品的影响

doi:10.3969/j.issn.2097-2806.2025.06.007

摘要/Abstract

摘要：

文章旨在深入探究增稠剂种类及工艺对蔗糖酯乳化体系产品特性的影响。通过对比分析样品的理化特性、乳化颗粒的尺寸分布以及稳定性测试结果，系统评估了不同增稠剂（包括需中和的Pemulen TR-1、Carbopol Ultrez 21、Carbopol Ultrez 30，以及无需中和的Aristoflex AVC、SEPIMAX ZEN、Aristoflex BLV）的加入方式及工艺对蔗糖酯乳化剂乳化效能及最终产品特性的影响。实验结果显示，预先将需中和的增稠剂加入乳化体系显著降低了蔗糖酯的乳化能力，导致生成的乳液粒径增大且分布不均。相比之下，无需中和的增稠剂对蔗糖酯乳化剂的乳化能力无显著影响。因此，对于需中和的增稠剂，建议以分散液形式在乳化过程结束后、低温阶段下，并伴随适当的混合强度加入蔗糖酯乳化体系，以制得粒径较小、稳定性优越且外观细腻的产品。研究揭示了增稠剂选择及加入工艺对产品特性的影响，为增稠剂在乳化体系中的高效应用提供了新思路和新方法。

关键词: 蔗糖酯乳化剂, 乳化, 增稠剂, 水解

Abstract:

The effects of thickeners and processes on the product properties of emulsion systems were studied, in which sucrose polystearate was used as an emulsifier. The physical and chemical properties, the size distribution of droplets and the stability of the samples were analyzed to evaluate the emulsification efficiency of sucrose polystearate in presence of different thickeners. In this study, two categories of thickeners were used, including neutralizable ones such as Pemulen TR-1, Carbopol Ultrez 21, and Carbopol Ultrez 30, and non-neutralizable ones such as Aristoflex AVC, SEPIMAX ZEN, and Aristoflex BLV. The experimental results indicated that, those neutralizable thickeners pre-added into the system had significantly reduced the emulsifying ability of sucrose polystearate, resulting in the formation of emulsions with larger particle size and uneven distribution. In contrast, no significant influence was observed for non-neutralizable thickeners upon the emulsifying ability of sucrose polystearate. Therefore, for neutralizable thickeners, it was recommended to incorporate them into the system in a dispersion form after the emulsification process, during the low-temperature stage, and with appropriate mixing intensity, thus to prepare products with smaller particle size, good stability and fine appearance. This study revealed the influences of selection and addition of thickeners, which might provide new ideas and methods for application of thickeners in emulsion systems. It could be helpful for the design and optimization of thickeners and emulsion systems.

Key words: sucrose ester emulsifier, emulsification, thickener, hydrolysis

中图分类号:

TQ658

吴巧霞, 程颖, 王飞飞. 增稠剂及工艺对蔗糖酯乳化体系产品的影响[J]. 日用化学工业（中英文）, 2025, 55(6): 731-738.

Qiaoxia Wu, Ying Cheng, Feifei Wang. Effects of thickeners and processes on the emulsion systems emulsified with sucrose polystearate[J]. China Surfactant Detergent & Cosmetics, 2025, 55(6): 731-738.

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相	组分	w/%
A	水	至100
	增稠剂	0.35
	甘油	5.00
	S-1170	3.50
B	鲸蜡硬脂醇	1.50
	角鲨烷	1.50
	聚二甲基硅氧烷	2.00
	矿脂	6.00
C	氨甲基丙醇	0.12
D	Euxyl PE 9010	0.60

增稠剂	配方（w/%）
增稠剂	F1	F2	F3	F4	F5	F6
Pemulen TR-1	0.35	—	—	—	—	—
Carbopol Ultrez 21	—	0.35	—	—	—	—
Carbopol Ultrez 30	—	—	0.35	—	—	—
Aristoflex AVC	—	—	—	0.35	—	—
SEPIMAX ZEN	—	—	—	—	0.35	—
Aristoflex BLV	—	—	—	—	—	0.35

商品名	增稠剂INCI	蔗糖酯+不同类型增稠剂溶液	pH （25 ℃直测）	黏度（40 r/min）/（mPa·s）
S-1170	蔗糖多硬脂酸酯	3.5% S-1170	6.91	3 750.0
Pemulen TR-1	丙烯酸（酯）类/C10-30烷醇丙烯酸酯交联聚合物	增稠剂溶液 +3.5% S-1170	3.26	347.50
Pemulen TR-1	丙烯酸（酯）类/C10-30烷醇丙烯酸酯交联聚合物	增稠剂溶液 +3.5% S-1170	4.00	3 550.0
Carbopol Ultrez 21	丙烯酸（酯）类/C10-30烷醇丙烯酸酯交联聚合物	增稠剂溶液 +3.5% S-1170	3.41	7.500 0
Carbopol Ultrez 21	丙烯酸（酯）类/C10-30烷醇丙烯酸酯交联聚合物	增稠剂溶液 +3.5% S-1170	4.15	4 275.0
Carbopol Ultrez 30	卡波姆	增稠剂溶液 +3.5% S-1170	3.38	235.00
Carbopol Ultrez 30	卡波姆	增稠剂溶液 +3.5% S-1170	3.98	8 100.0
Aristoflex AVC	丙烯酰二甲基牛磺酸铵/VP共聚物	增稠剂溶液 +3.5% S-1170	6.99	2 225.0
Aristoflex AVC	丙烯酰二甲基牛磺酸铵/VP共聚物	增稠剂溶液 +3.5% S-1170	6.74	10 980
SEPIMAX ZEN	聚丙烯酸酯交联聚合物-6	增稠剂溶液 +3.5% S-1170	7.00	2 270.0
SEPIMAX ZEN	聚丙烯酸酯交联聚合物-6	增稠剂溶液 +3.5% S-1170	6.50	4 450.0
Aristoflex BLV	丙烯酰二甲基牛磺酸铵/山嵛醇聚醚-25甲基丙烯酸酯交联聚合物	增稠剂溶液 +3.5% S-1170	6.85	1 213.0
Aristoflex BLV	丙烯酰二甲基牛磺酸铵/山嵛醇聚醚-25甲基丙烯酸酯交联聚合物	增稠剂溶液 +3.5% S-1170	6.63	7 525.0

	Pemulen TR-1	Carbopol Ultrez 21	Carbopol Ultrez 30	Aristoflex AVC	SEPIMAX ZEN	Aristoflex BLV
价格（元/kg）	≈300	≈300	≈300	≈500	≈500	≈700
黏度（0.5%水溶液，pH≈6.0） / （mPa·s）	≈13 600	≈35 400	≈38 800	≈18 250	≈4 950	≈5 700

相	组分	w/%
A	水	至100
	甘油	5.00
	S-1170	3.50
B	鲸蜡硬脂醇	1.50
	角鲨烷	1.50
	聚二甲基硅氧烷	2.00
	矿脂	6.00
	牛油果树果酯	2.00
	胡萝卜籽油	0.05
	扁核木油	0.50
C	水	3.15
C	Carbopol Ultrez 30	0.35
D	氨甲基丙醇	0.12
E	Euxyl PE 9010	0.60
	马齿苋提取物	2.00
	β-葡聚糖	2.00
	胶原	0.05