两亲聚合物设计合成及其增效体系研究(IX)— 流变性能

doi:10.3969/j.issn.1001-1803.2020.09.002

摘要/Abstract

摘要：

综述了两亲聚合物及其增效体系的流变特性的研究进展。首先概述了两亲聚合物的流变特性,总结了其黏浓关系、稳态与动态剪切条件下的流变性能以及流变模式。其次探讨了温度、矿化度和时间对两亲聚合物流变性能的影响规律。最后对3种增效体系,即两亲聚合物静电作用增效体系、两亲聚合物疏水缔合作用增效体系和两亲聚合物主客体包合作用增效体系的流变特性进行了阐述。

关键词: 两亲聚合物, 功能单体, 增效体系, 流变特性

Abstract:

The rheological properties of amphiphilic polymers and their synergistic systems are reviewed. Firstly, the rheological properties of amphiphilic polymers are summarized, including the viscosity relationship, rheological properties under steady and dynamic shear conditions and rheological model. Secondly, the effects of temperature, salinity and time on the rheological properties of amphiphilic polymers are discussed. Finally, the rheological properties of three synergetic systems containing amphiphilic polymers are described, which are electrostatic synergetic system, hydrophobic associative synergetic system and host/guest package synergetic system.

Key words: amphiphilic polymer, functional monomer, synergistic system, rheology

中图分类号:

TQ423

康万利,何瑛琦,杨红斌,王芳,Bauyrzhan Sarsenbekuly. 两亲聚合物设计合成及其增效体系研究(IX)— 流变性能[J]. 日用化学工业, 2020, 50(9): 588-595.

KANG Wan-li,HE Ying-qi,YANG Hong-bin,WANG Fang,Bauyrzhan Sarsenbekuly. Study on the design and synthesis of amphiphilic polymers and their synergistic systems (IX)Rheological properties[J]. China Surfactant Detergent & Cosmetics, 2020, 50(9): 588-595.

图/表 5

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w(ACS210)/ %	μ=Kγⁿ^-1	K	n	R²
0.1	μ=0.108 8γ^{-0.399 6}	0.108 8	0.600 4	0.989 2
0.2	μ=0.135 4γ^{-0.457 0}	0.135 4	0.543 0	0.994 7
0.3	μ=0.108 8γ^{-0.441 1}	0.108 8	0.558 9	0.967 7