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日用化学工业 ›› 2020, Vol. 50 ›› Issue (3): 149-154.doi: 10.3969/j.issn.1001-1803.2020.03.002

• 科技讲座 • 上一篇    下一篇

两亲聚合物设计合成及其增效体系研究(III)—疏水缔合作用

康万利1,2,蒋海壮1,2,康鑫1,2,李梦栏1,2,杨红斌1,2,张向峰1,2   

  1. 1. 非常规油气开发教育部重点实验室(中国石油大学(华东)),山东 青岛 266580
    2. 中国石油大学(华东) 石油工程学院,山东 青岛 266580
  • 收稿日期:2020-02-05 出版日期:2020-03-22 发布日期:2020-04-02
  • 作者简介:康万利(1963-),男,吉林松原人,泰山学者特聘教授,博士生导师,电话:13589332193,E-mail: kangwanli@upc.edu.cn
  • 基金资助:
    国家自然科学基金资助项目(51774309)

Study on the design and synthesis of amphiphilic polymers and their synergistic systems (III)Hydrophobic association

Wan-li KANG1,2,Hai-zhuang JIANG1,2,Xin KANG1,2,Meng-lan LI1,2,Hong-bin YANG1,2,Xiang-feng ZHANG1,2   

  1. 1. Key Laboratory of Unconventional Oil & Gas Development (China University of Petroleum (East China)), ministry of Education, Qingdao, Shandong 266580, China;
    2. School of Petroleum Engineering, China University of Petroleum (East China), Qingdao, Shandong 266580, China
  • Received:2020-02-05 Online:2020-03-22 Published:2020-04-02

摘要:

综述了近些年两亲聚合物体系的疏水缔合作用,主要包括两亲聚合物自身疏水缔合作用,两亲聚合物与表面活性剂复配体系的疏水缔合作用和疏水缔合两亲聚合物的性能。两亲聚合物自身的疏水缔合作用包括低浓度分子内缔合以及超过临界缔合浓度分子间缔合;两亲聚合物与表面活性剂的疏水缔合作用包括不同种类表面活性剂与聚合物的疏水缔合作用以及疏水基团对复配体系的影响;最后给出了基于疏水缔合作用增效的两亲聚合物体系的优良性能。

关键词: 两亲聚合物, 疏水缔合作用, 疏水基团, 表面活性剂, 性能

Abstract:

The hydrophobic association of amphiphilic polymer systems in recent years has been summarized, including the self hydrophobic association of amphiphilic polymers, the hydrophobic association in the mixed systems of amphiphilic polymers and surfactants, and the application of the hydrophobic association of amphiphilic polymers. The hydrophobic association in amphiphilic polymer systems includes the intramolecular association and the intermolecular association below and above the critical association concentration, respectively. The hydrophobic association in the mixed systems of amphiphilic polymers and surfactants includes the hydrophobic association of different kinds of surfactants with polymers and the influence of hydrophobic groups on the mixed systems. Finally, the excellent properties of amphiphilic polymer systems based on the synergy of hydrophobic association are summarized.

Key words: amphiphilic polymer, hydrophobic association, hydrophobic group, surfactant, performance

中图分类号: 

  • TQ423