新型聚醚基三硅氧烷表面活性剂的制备及表面活性

doi:10.3969/j.issn.1001-1803.2019.01.001

日用化学工业 ›› 2019, Vol. 49 ›› Issue (1): 1-4.doi: 10.3969/j.issn.1001-1803.2019.01.001

• 基础研究 • 下一篇

新型聚醚基三硅氧烷表面活性剂的制备及表面活性

缪永翔¹,谭景林^1,²(),林苗苗¹,何子妍¹

1.九江学院化学与环境工程学院,江西九江 332005
2.江西省生态化工研究中心,江西九江 332005

收稿日期:2018-07-06 修回日期:2018-12-20 出版日期:2019-01-20 发布日期:2019-03-06
通讯作者: 谭景林
作者简介:缪永翔（1996-）,男,江西上饶人,电话：13576313709,E-mail：myxyq@foxmail.com。
基金资助:
国家自然科学基金资助项目(21563016)

Synthesis and surface activities of novel polyether based trisiloxane surfactants

MIAO Yong-xiang¹,TAN Jing-lin^1,²(),LIN Miao-miao¹,HE Zi-yan¹

1.School of Chemical and Environmental Engineering, Jiujiang University, Jiujiang, Jiangxi 332005, China
2.Jiangxi Province Engineering Research Center of Ecological Chemical Industry, Jiujiang, Jiangxi 332005, China

Received:2018-07-06 Revised:2018-12-20 Online:2019-01-20 Published:2019-03-06
Contact: Jing-lin TAN

摘要/Abstract

摘要：

以巯丙基三硅氧烷与聚乙二醇烯丙基甲基醚经thiol-ene反应合成了新型聚醚基三硅氧烷表面活性剂,并对其结构进行了FT-IR和 ¹H NMR表征,通过表面张力的测定考察了其表面活性。结果表明,该法可以高效合成高纯度的聚醚基三硅氧烷表面活性剂,该表面活性剂能将水的表面张力降低至21~23 mN/m,具有优良的表面活性。

关键词: 三硅氧烷, 聚醚基, thiol-ene反应, 表面活性

Abstract:

Polyether based trisiloxane surfactants were synthesized by thiol-ene reaction of thiopropyl-trisiloxane and polyethylene glycol allyl methyl ether and its structure were characterized by FT-IR and ¹H NMR. Its surface activity were investigated by measuring surface tension. The results show that the method can efficiently synthesize high-purity polyether based trisiloxane surfactants, which can reduce the surface tension of water to 21~23 mN/m and has excellent surface activity.

Key words: trisiloxane, polyether, thiol-ene reaction, surface activities

中图分类号:

TQ423

缪永翔,谭景林,林苗苗,何子妍. 新型聚醚基三硅氧烷表面活性剂的制备及表面活性[J]. 日用化学工业, 2019, 49(1): 1-4.

Yong-xiang MIAO,Jing-lin TAN,Miao-miao LIN,Zi-yan HE. Synthesis and surface activities of novel polyether based trisiloxane surfactants[J]. China Surfactant Detergent & Cosmetics, 2019, 49(1): 1-4.

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表面活性剂	cmc×10⁵/（mol·L^-1）	γ_cmc/（mN·m^-1）	π_cmc	pc₂₀
Si₃EO₇	4.25	22.9	49.6	5.52
Si₃EO₈	13.5	23.1	49.4	5.08
Si₃EO₁₀	14.5	21.5	51.0	5.43

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新型聚醚基三硅氧烷表面活性剂的制备及表面活性

Synthesis and surface activities of novel polyether based trisiloxane surfactants

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