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日用化学工业 ›› 2020, Vol. 50 ›› Issue (4): 220-226.doi: 10.3969/j.issn.1001-1803.2020.04.002

• 科技讲座 • 上一篇    下一篇

两亲聚合物设计合成及其增效体系研究(Ⅳ)——主客体包合作用

康万利1,2,张敏1,2,张弘文1,2,康鑫1,2,杨红斌1,2,王芳1,2   

  1. 1. 非常规油气开发教育部重点实验室(中国石油大学(华东)),山东 青岛 266580
    2. 中国石油大学(华东) 石油工程学院,山东 青岛 266580
  • 收稿日期:2020-03-05 出版日期:2020-04-22 发布日期:2020-04-24
  • 作者简介:康万利(1963-),男,吉林松原人,泰山学者特聘教授,博士生导师,电话:13589332193,E-mail:kangwanli@upc.edu.cn。
  • 基金资助:
    国家自然科学基金资助项目(51774309)

Study on the design and synthesis of amphiphilic polymers and their synergistic systems (Ⅳ) Host-guest inclusion

KANG Wan-li1,2,ZHANG Min1,2,ZHANG Hong-wen1,2,KANG Xin1,2,YANG Hong-bin1,2,WANG Fang1,2   

  1. 1. Key Laboratory of Unconventional Oil & Gas Development (China University of Petroleum (East China)) ,Ministry of Education, Qingdao, Shandong 266580, China;
    2. School of Petroleum Engineering,China University of Petroleum (East China), Qingdao, Shandong 266580, China
  • Received:2020-03-05 Online:2020-04-22 Published:2020-04-24

摘要:

综述了近些年两亲聚合物体系的主客体包合作用,主要介绍了环糊精的基本结构与性质、主客体包合原理、环糊精与两亲聚合物的包合作用以及包合体系性能的影响因素。环糊精与两亲聚合物的包合作用包括了环糊精分别与金刚烷疏水基团、单尾结构基团以及孪尾结构基团的包合作用。最后分别从矿化度、温度以及剪切作用等方面阐述了包合体系性能的影响,展望了在三次采油中的应用前景。

关键词: 两亲聚合物, 主客体包合作用, 环糊精, 疏水基团, 性能

Abstract:

The host-guest inclusion of amphiphilic polymer systems in recent years has been reviewed. The basic structure and properties of cyclodextrins, the principle of host-guest inclusion, the inclusion of cyclodextrins with amphiphilic polymers, and the factors affecting the performance of the system have been introduced. The inclusion of cyclodextrins with amphiphilic polymers with adamantane hydrophobic group, single-tailed structure group and twin-tailed structure group has been introduced, respectively. Finally, the effects of the properties of inclusion systems were described in terms of salinity, temperature and shear. The application in tertiary oil recovery is also prospected.

Key words: amphiphilic polymer, host-guest inclusion, cyclodextrin, hydrophobic group, performance

中图分类号: 

  • TQ423