CaCO3纳米晶体稳定非水相泡沫实验研究

doi:10.3969/j.issn.2097-2806.2023.06.005

摘要/Abstract

摘要：

非水相泡沫在油田开发、功能材料、食品工业和日化等领域有着广泛的应用，对非水相泡沫性能的调控在相关行业的发展中发挥着重要的影响。然而，由于非水相溶剂具有的低界面张力和低介电常数，导致其发泡难度较大。为解决非水相溶剂发泡困难的问题，文章通过制备CaCO₃纳米晶体，并经TEM，FT-IR及XRD等对晶体颗粒进行了表征，采用1H，1H，2H，2H-全氟癸基三乙氧基硅烷对CaCO₃纳米晶体的润湿性进行了调控，研究CaCO₃纳米晶体对非水相溶剂发泡性能的影响。研究发现：随CaCO₃纳米晶体质量分数的增加，不同接触角的CaCO₃纳米晶体所产生的泡沫体积呈现先增后减的趋势，当晶体质量分数为5%时，非水相溶剂发泡性能最佳，泡沫体积最高可达到120 mL；非水相泡沫的稳定性随CaCO₃纳米晶体接触角的增加呈现先增强后减弱的趋势，当接触角范围在47.5°~73.9°时，非水相泡沫的稳定性最佳，排液半衰期最高可达到100 h。

关键词: 泡沫, CaCO₃纳米晶体, 润湿性, 发泡性能

Abstract:

Non-aqueous foams are widely used in fields such as oilfield development, functional materials, food industry and daily chemicals. The regulation of the properties of non-aqueous foams plays an important role in the development of related industries. Due to the low interfacial tension and low dielectric constant of non-aqueous solvents, foaming is difficult. Therefore, in this work, to solve the problems in non-aqueous solvent foaming, CaCO₃ nanocrystals were prepared. The crystal particles were characterized by TEM, FT-IR and XRD. 1H, 1H, 2H, 2H-perfluorodecyl triethoxy silane was used to regulate the wettability of CaCO₃ nanocrystals. The effects of CaCO₃ nanocrystals on the foaming performance of non-aqueous solvents were studied. It was found that, with the increase of mass fraction of CaCO₃ nanocrystals, the foam volume produced by CaCO₃ nanocrystals with different contact angles first increased and then decreased. When the crystal mass fraction was 5%, the foaming performance of non-aqueous solvent was the best, and the foam volume could reach 120 mL. The stability of the non-aqueous foam first increased and then decreased with the increase of the contact angle of CaCO₃ nanocrystals. When the contact angle was in the range from 47.5° to 73.9°, the stability of the non-aqueous foam was the best, and the draining half-life was up to 100 h.

Key words: foam, CaCO₃ nanocrystal, wettability, foaming performance

中图分类号:

O648.24

张佩亮, 燕永利, 吕博, 曹玉霞, 吴春生, 贺炳成. CaCO₃纳米晶体稳定非水相泡沫实验研究[J]. 日用化学工业（中英文）, 2023, 53(6): 642-648.

Zhang Peiliang, Yan Yongli, Lv Bo, Cao Yuxia, Wu Chunsheng, He Bingcheng. Experimental study on non-aqueous foams stabilized by CaCO₃ nanocrystals[J]. China Surfactant Detergent & Cosmetics, 2023, 53(6): 642-648.

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CaCO₃纳米晶体稳定非水相泡沫实验研究

Experimental study on non-aqueous foams stabilized by CaCO₃ nanocrystals

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