两亲聚合物设计合成及其增效体系研究（VIII）—— 剪切降解与恢复特性

doi:10.3969/j.issn.1001-1803.2020.08.002

摘要/Abstract

摘要：

阐述了不同结构和浓度的两亲聚合物的剪切降解及恢复特性,同时对两亲聚合物增效体系的剪切性能进行了相关拓展。进一步从注入速度、温度、矿化度、老化时间等油田实际影响因素出发,探讨了不同因素对两亲聚合物剪切特性和黏度恢复特性的影响规律。最后对抗剪切两亲聚合物的发展趋势进行了展望,可为抗剪切功能两亲聚合物的设计及应用提供理论和技术基础。

关键词: 两亲聚合物, 剪切降解, 剪切恢复, 影响因素

Abstract:

The shear degradation and recovery characteristics of amphiphilic polymers with various structure and concentration have been described, and the shear-resistance and viscosity-recovery performances of the supramolecular systems based on amphiphilic polymers have been introduced. Considering the actual oilfield factors, such as injection rate, temperature, salinity, and aging time, the shear characteristics and viscosity-recovery performance of amphiphilic polymers under the influence of various factors have been summarized. Finally, the development trend of anti-shear amphiphilic polymers has been prospected, which can provide theoretical and technical basis for the design and application of anti-shear amphiphilic polymers.

Key words: amphiphilic polymer, shear degradation, shear recovery, influencing factor

中图分类号:

TQ423

康万利,王芳,杨红斌,朱彤宇,Bauyrzhan Sarsenbekuly. 两亲聚合物设计合成及其增效体系研究（VIII）—— 剪切降解与恢复特性[J]. 日用化学工业, 2020, 50(8): 516-522.

KANG Wan-li,WANG Fang,YANG Hong-bin,ZHU Tong-yu,Bauyrzhan Sarsenbekuly. Study on the design and synthesis of amphiphilic polymers and their synergistic systems （VIII）Shear degradation and recovery characteristics[J]. China Surfactant Detergent & Cosmetics, 2020, 50(8): 516-522.

图/表 6

图 1

图 2

图 3

图 4

图 5

图 6

参考文献 36

[1]	Liao Guangzhi, Wang Qiang, Wang Hongzhuang, et al. Chemical flooding development status and prospect[J]. Acta Petrolei Sinica, 2017,38(2) : 82-93.
[2]	Shen Pingping Technical progress of enhanced oil recovery [M]. Beijing: Petroleum Industry Press, 2006.
[3]	Yuan Shiyi, Wang Qiang. New progress and prospect of oilfields development technologies in China[J]. Petroleum Exploration and Development, 2018,45(4) : 657-668.
[4]	Chen Hong, Yang Hailing, Shu Zheng. Research on shearing simulation experiment of associating polymer through near-wellbore device[J]. Applied Chemical Industry, 2012,41(5) : 920-927.
[5]	Li Meirong, Huang Man, Qu Caixia, et al. Effect of shear action on the microcosmic structure and performance of functional polymer used in oil displacement[J]. Journal of Fuel Chemistry and Technology, 2013,41(4) : 449-455.
[6]	Zhang Zhenhua, Cheng Jiecheng, Li Lin Pilot test technology of polymer flooding [M]. Beijing: Petroleum Industry Press, 1996.
[7]	Wang Youqi, Zhang Yigen, Jiang Yanbo, et al. Some problems influencing on field results of polymer flooding[J]. Oilfield Chemistry, 1999,16(3) : 244-246.
[8]	Chen Mingqiang, Sun Zhiqiang, Wang Jiangshun, et al. Analysis of the viscosity loss of polymer solution in the process of injection allocation[J]. Journal of Xian Shiyou University (Natural Science Edition) , 2007,22(3) : 60-63.
[9]	Guo Yongjun, Zheng Chao, Yang Hongmei, et al. Association behaviors of carbazole-labeled polyacrylamide in water studied by fluorescence spectroscopy[J]. RSC Advances, 2016,6:86989-86997. doi: 10.1039/C6RA15898F
[10]	Qiu J. Stability of the oil-water emulsion formed during amphiphilic polymer flooding[J]. Petroleum Science and Technology, 2013,31(2) : 142-147. doi: 10.1080/10916466.2011.603006
[11]	Jiang Jiatong, Wu Hairong, Lu Yao, et al. Application of α-amylase as a novel biodemulsifier for destabilizing amphiphilic polymer-flooding produced liquid treatment[J]. Bioresource Technology, 2018,259:349-356. pmid: 29574315
[12]	Wang Jigang, Wu Peng, Du Quanqing, et al. Shear studies on polymer flooding systems with high concentrations[J]. Advanced Materials Research, 2012,535:1189-1192.
[13]	Francois J. Association in water of model hydrophobically end-capped poly (ethylene oxide)[J]. Progress in Organic Coatings, 1994,24:67-79. doi: 10.1016/0033-0655(94)85007-0
[14]	Shi Leiting. Research on the association of hydrophobic association water-soluble polymer in porous media[D]. Chengdu: Southwest Petroleum University, 2003.
[15]	Pu Wanfen, Yan Zhaopeng, Liu Rui, et al. Preparation and performance evaluation of an hyperbranched hydrophobic associating polymer[J]. Chemical Research and Application, 2015,5:589-594.
[16]	Kang Wanli, Zhang Hongwen, Lu Yao, et al. Study on the enhanced viscosity mechanism of the cyclodextrin polymer and betaine-type amphiphilic polymer inclusion complex[J]. Journal of Molecular Liquids, 2019,296:111792. doi: 10.1016/j.molliq.2019.111792
[17]	Cao Baoge, Li Huabin, Luo Pingya, et al. Rheologic behavior of hydrophobically associating polymer AP4 solutions in fresh water[J] . Oilfield Chemistry, 2005,22(2) : 168-172.
[18]	Peng Tianjie, Liu Jianxin, Zhao Zhongcong, et al. Effect of micro-block length on rheological performance of hydrophobically associating polymer[J]. Oilfield Chemistry, 2016,33(4) : 670-676.
[19]	Lv Xin, Zheng Yan. The influence of chain stiffness on the performance of associating water-soluble polymer[J]. Journal of Southwest Petroleum University (Science ＆ Technology Edition) , 2009,31(1) : 125-127.
[20]	Zhang Xiangfeng, Yang Hongbin, Wang Pengxiang, et al. Construction and thickening mechanism of amphiphilic polymer supramolecular system based on polyacid[J]. Journal of Molecular Liquids, 2019,286:110921. doi: 10.1016/j.molliq.2019.110921
[21]	Kang Wanli, Zhang Min, Zhang Hongwen, et al. Study on the design and synjournal of amphiphilic polymers and their synergistic systems (Ⅳ) : Host-guest inclusion[J]. China Surfactant Detergent & Cosmetics, 2020,50(4) : 220-226.
[22]	Feng Sisi, Chen Hong, Ye Zhongbin, et al. Interaction between hydrophobically associating polymer and amphoteric surfactant[J]. Applied Chemical Industry, 2015,44(1) : 87-91.
[23]	Tang Wenyue, Zou Changjun, Da Chang, et al. A review on the recent development of cyclodextrin-based materials used in oilfield applications[J]. Carbohydrate Polymers, 2020,240:116321. doi: 10.1016/j.carbpol.2020.116321 pmid: 32475582
[24]	Cao Baoge, Dai Qian, Chen Dingchao, et al. Study on the anti-shear mechanism of hydrophobic associative polymer solution[J]. Drilling & Production Technology, 2007,30(3) : 121-124.
[25]	Ji Chaofeng. Study on the association mechanism of hydrophobic association water-soluble polymer in porous media[D]. Chengdu: Southwest Petroleum University, 2004.
[26]	Luo Kaifu, Ye Lin, Huang Ronghua. Solution properties of water-soluble hydrophobically associating polymers: A review[J]. Oilfield Chemistry, 1999 (3) : 286-290.
[27]	Shi Leiting, Jia Tianze, Ye Zhongbin, et al. Effect of shearing on molecule aggregation behavior of hydrophobic associative polymer solution[J]. Petroleum Geology and Recovery Efficiency, 2011,18(2) : 49-51.
[28]	Zhang Jifeng. The behavios of adsorption and retention and characteristic of flowing through the porous media of hydrophobically associating polymers[D]. Chengdu: Southwest Petroleum University, 2004.
[29]	Wang Fang, Yang Hongbin, Li Menglan, et al. Study on stabilization of emulsion formed by the supramolecular system of amphiphilic polymer and sodium polyacrylic acid[J]. Journal of Molecular Liquids, 2020,314:113644. doi: 10.1016/j.molliq.2020.113644
[30]	Zhang Hongwen, Yang Hongbin, Zhou Bobo, et al. Effects of cyclodextrin polymer on the gelation of amphiphilic polymer in inclusion complex[J]. Journal of Molecular Liquids, 2020,305:112850. doi: 10.1016/j.molliq.2020.112850
[31]	Zhang Hongwen, Yang Hongbin, Wang Fang, et al. Study on the stabilization of emulsion formed by two different inclusion complexes[J]. Colloids and Surfaces A, 2020,594:124651. doi: 10.1016/j.colsurfa.2020.124651
[32]	Zhou Hong, Mei Yongjun, Wei Yongqiang, et al. Advances in rheological behavior of hydropobically modified polymer solution under shear[J]. Materials Review, 2012 (5) : 79-83.
[33]	Zhang Rui, Qin Ni, Peng Lin, et al. The effect of injection rate on recovery behaviors of hydrophobically associating water-soluble[J]. Acta Petrolei Sinica, 2013,34(1) : 122-127.
[34]	Zhou Changjing. Study on rheology and viscoelasticity of hydrophobic associative polymer solution[D]. Chengdu: Southwest Petroleum University, 2006.
[35]	Xue Xinsheng, Guo Yongjun, Ma Junlong, et al. Effect of ion on viscosity shear retention rate of associating polymer solution[J]. Oil Drilling & Production Technology, 2008,30(4) : 96-99.
[36]	Zhang Xiangfeng, Shan Xiuhua, Wang Fang, et al. Effect of aging time on the viscoelastic properties of amphiphilic polymer-polyacid supramolecular solution[J]. Physics of Fluids, 2020,32:23101. doi: 10.1063/1.5143002