改性TiO2纳米材料的制备及防晒化妆品的应用性能分析

doi:10.3969/j.issn.1001-1803.2023.01.006

摘要/Abstract

摘要：

通过超声水解法制备了SiO₂包覆的SiO₂/TiO₂纳米材料，研究了不同热处理温度对SiO₂/TiO₂纳米材料性能的影响，测试发现SiO₂/TiO₂纳米材料结构未发生变化，均为金红石型TiO₂，SiO₂包覆后通过物理包覆作用与TiO₂发生了结合。微观测试发现SiO₂/TiO₂材料均为球形颗粒，直径为1.5~2 μm，随着热处理温度的增加，尺寸轻微增大。亲水亲油测试表明SiO₂/TiO₂纳米材料具有较强的亲油性。其对亚甲基蓝的褪色率低于纯TiO₂，随着热处理温度的增加，褪色率先降低后升高，550 ℃处理的SiO₂/TiO₂纳米材料对亚甲基蓝的褪色率最低为18.7%。将SiO₂/TiO₂纳米材料自制成防晒乳液，其对于紫外光屏蔽效果优于纯TiO₂，热处理温度为550 ℃时，复合材料的透射率最低，对紫外光的屏蔽效果最佳。综合来看，SiO₂包覆后的SiO₂/TiO₂复合材料在防晒化妆品的应用中具有较高的潜力。

关键词: 二氧化钛, 纳米材料, 防晒化妆品, 包覆, 微观形貌, 催化性能

Abstract:

SiO₂-coated SiO₂/TiO₂ nanomaterials were prepared by ultrasonic hydrolysis. The effects of different heat treatment temperatures on the properties of SiO₂/TiO₂ nanomaterials were studied. It was found that the structure of SiO₂/TiO₂ nanomaterials did not change, and they were all rutile-type TiO₂. SiO₂ was combined with TiO₂ by bonding after SiO₂ coating. The results of microscopic test showed that the SiO₂/TiO₂ materials were spherical particles with diameter of 1.5-2 μm, and the size was slightly increased with the increase of heat treatment temperature. Hydrophilic and lipophilic tests showed that the SiO₂/TiO₂ nanomaterials had strong lipophilicity. The fading rate of methylene blue by SiO₂/TiO₂ nanomaterials was lower than that of pure TiO₂. With the increase of heat treatment temperature, the fading rate first decreased and then increased. The fading rate of methylene blue by SiO₂/TiO₂ nanomaterials treated at 550 ℃ was the lowest （18.7%）. The SiO₂/TiO₂nanomaterials were introduced into sunscreen lotions, indicative of better UV shielding effect than pure TiO₂. When the heat treatment temperature was 550 ℃, the transmittance of the composite material was the lowest and the UV shielding effect was the best. Overall, the SiO₂/TiO₂ composites coated with SiO₂ had high potential of application in sunscreen cosmetics.

Key words: TiO₂, nanomaterial, sunscreen cosmetics, coating, microscopic morphology, catalytic performance

中图分类号:

TQ658

徐婧, 范春霞. 改性TiO₂纳米材料的制备及防晒化妆品的应用性能分析[J]. 日用化学工业（中英文）, 2023, 53(1): 41-46.

Xu Jing, Fan Chunxia. Preparation of modified TiO₂ nanomaterials and application performance analysis of sunscreen cosmetics[J]. China Surfactant Detergent & Cosmetics, 2023, 53(1): 41-46.

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试样	1 h	4 h	24 h	48 h
纯TiO₂	亲水、无沉淀	亲水、稍有沉淀	亲水、少量沉淀	亲水、大量沉淀
SiO₂/TiO₂（350 ℃）	亲油、无沉淀	亲油、无沉淀	亲油、稍有沉淀	亲油、少量沉淀
SiO₂/TiO₂（450 ℃）	亲油、无沉淀	亲油、无沉淀	亲油、稍有沉淀	亲油、少量沉淀
SiO₂/TiO₂（550 ℃）	亲油、无沉淀	亲油、无沉淀	亲油、无沉淀	亲油、稍有沉淀
SiO₂/TiO₂（650 ℃）	亲油、无沉淀	亲油、无沉淀	亲油、稍有沉淀	亲油、稍有沉淀

改性TiO₂纳米材料的制备及防晒化妆品的应用性能分析

Preparation of modified TiO₂ nanomaterials and application performance analysis of sunscreen cosmetics

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