再生木浆纤维素的制备及其稳定辛酸/癸酸甘油三酯乳液的性能研究

doi:10.13218/j.cnki.csdc.2017.11.005

日用化学工业 ›› 2017, Vol. 47 ›› Issue (11): 621-626.doi: 10.13218/j.cnki.csdc.2017.11.005

再生木浆纤维素的制备及其稳定辛酸/癸酸甘油三酯乳液的性能研究

周倩倩¹, 王碧佳¹, 徐红¹, 隋晓锋¹, 施波波²

1.东华大学化学化工与生物工程学院生态纺织教育部重点实验室,上海 201620;
2.杭州语晗科技有限公司,浙江杭州 311215

收稿日期:2017-08-07 出版日期:2017-11-22 发布日期:2019-03-21
通讯作者: 隋晓锋,教授,电话:13661471328,E-mail:suixf@dhu.edu.cn。
作者简介:周倩倩(1993-),女,河南周口人,硕士研究生,电话:18302139325,E-mail:2808234681@qq.com。
基金资助:
国家自然科学基金资助项目(51403035)

Properties of GTCC emulsions stabilized by regenerated
wood pulp cellulose

ZHOU Qian-qian¹, WANG Bi-jia¹, XU Hong¹, SUI Xiao-feng¹, SHI Bo-bo²

1.Key Laboratory of Science and Technology of Eco-Textile,Ministry of Education,College of Chemistry, Chemical Engineering and Biotechnology,Donghua University,Shanghai 201620,China;
2.Hangzhou Yeuha Technology Co.,Ltd.,Hangzhou,Zhejiang 311215,China

Received:2017-08-07 Online:2017-11-22 Published:2019-03-21

摘要/Abstract

摘要： 以高纯木浆板为原料制得再生木浆纤维素(W-RC),并用TEM、FT-IR和XRD对其进行表征,说明W-RC属于典型的纳米基纤维素Ⅱ型颗粒。以辛酸/癸酸甘油三酯(GTCC)为油相,W-RC为乳化剂,制得O/W型Pickering乳液,并通过光学显微镜、荧光显微镜、FE-SEM及流变仪对乳液进行表征。荧光显微镜与FE-SEM的结果显示W-RC吸附在油/水界面并在微球表面及微球间形成三维网状结构。流变学表明W-RC及由其稳定的乳液具有典型的剪切变稀特性。W-RC具有优良的乳化性能,在W-RC质量分数为0.6%、分散相体积分数高达60%时,也能得到稳定的乳液。

关键词: Pickering乳液, 再生木浆纤维素, 辛酸/癸酸甘油三酯, 流变学

Abstract: The regenerated wood pulp cellulose (W-RC) was prepared with high purity wood pulp board as raw material and the product was characterized by TEM,FT-IR and XRD.Results indicate that W-RC belongs to the typical nanometer cellulose Ⅱ particles.O/W Pickering emulsion was prepared using caprylic/capric triglycerides (GTCC) as the oil phase and W-RC as the emulsifier.The Pickering emulsions were characterized by optical microscopy,fluorescence microscopy,FE-SEM and rheometer.Results show that W-RC is adsorbed at the oil-water interface and a three-dimensional network structure is formed on and in between oily microspheres from fluorescence microscopy and FE-SEM image.The rheology study illustrates that W-RC and the resulting emulsions feature the typical shear-thinning property of emulsions.W-RC displays excellent emulsifying properties,and a stable emulsion can be obtained when the W-RC mass fraction is 0.6% and even if the dispersed phase volume fraction is as high as 60%.

Key words: Pickering emulsion, regenerated wood pulp cellulose, caprylic/capric triglyceride, rheology

中图分类号:

O648.23

周倩倩, 王碧佳, 徐红, 隋晓锋, 施波波. 再生木浆纤维素的制备及其稳定辛酸/癸酸甘油三酯乳液的性能研究[J]. 日用化学工业, 2017, 47(11): 621-626.

ZHOU Qian-qian, WANG Bi-jia, XU Hong, SUI Xiao-feng, SHI Bo-bo. Properties of GTCC emulsions stabilized by regenerated
wood pulp cellulose[J]. China Surfactant Detergent & Cosmetics, 2017, 47(11): 621-626.

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再生木浆纤维素的制备及其稳定辛酸/癸酸甘油三酯乳液的性能研究

Properties of GTCC emulsions stabilized by regenerated
wood pulp cellulose

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再生木浆纤维素的制备及其稳定辛酸/癸酸甘油三酯乳液的性能研究

Properties of GTCC emulsions stabilized by regenerated wood pulp cellulose

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Properties of GTCC emulsions stabilized by regenerated
wood pulp cellulose