日用化学工业（中英文）

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十二烷基三甲基己酸铵/SDBS复配体系的表面活性和应用性能研究
Surface activities and application performance of
dodecyltrimethylammonium hexanoate-SDBS blend systems

柯回春, 耿涛, 姜亚洁, 张春桥, 鞠洪斌, 王亚魁

2017 (11): 603-606. doi: 10.13218/j.cnki.csdc.2017.11.001

摘要 ( 278 )

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研究了十二烷基三甲基己酸铵(C₁₂NC₆)与十二烷基苯磺酸钠(SDBS)复配体系的表面活性及应用性能。结果表明,复配体系的临界胶束浓度(cmc)和临界胶束浓度下的表面张力(γ_cmc)均比单一表面活性剂的低,其扩散吸附速率较单一表面活性剂的慢;复配体系中SDBS的加入可提高C₁₂NC₆的稳泡性、润湿性;当n(C₁₂NC₆)∶n(SDBS)＝1∶1时,复配体系的cmc和γ_cmc达到最低,具有较好的稳泡性和润湿性,但发泡性和乳化性变差。 Surface activities and application performances of dodecyltrimethylammonium hexanoate (C₁₂NC₆) and sodium dodecyl benzene sulfonate (SDBS) blend systems were measured.Results show that the critical micelle concentration and surface tension of the blend systems are lower than each single component surfactant of the system;and the rate of diffusion adsorption of the blend systems is slower than that of each single component surfactant.The foam stability and wetting power of C₁₂NC₆ are improved by the addition of SDBS.As n(C₁₂NC₆)∶n(SDBS)＝1∶1,the critical micelle concentration and surface tension of the blend system achieve the lowest value,and the blend system displays better foam stability and wetting power,but the foaming power and emulsifying power of the blend system become worse.

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离子液体表面活性剂的合成与应用(Ⅺ)——与生物活性分子的相互作用
Synthesis and application of ionic liquid surfactants (Ⅺ)
Interactions between bioactive molecules

吴磊, 杨许召, 邹文苑, 徐清杰, 王军

2017 (11): 607-611. doi: 10.13218/j.cnki.csdc.2017.11.002

摘要 ( 335 )

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从3方面综述了离子液体表面活性剂与生物活性分子的相互作用。亲油性的离子液体表面活性剂可与β-环糊精形成1∶1,1∶2或2∶1型包合物,而亲水性的离子液体表面活性剂不能与β-环糊精形成包合物,这些包合物的形成影响了表面活性剂的cmc和在界面的吸附。离子液体表面活性剂能够与牛血清蛋白、β-酪蛋白、溶菌酶等蛋白质相互作用,影响蛋白质的分子构型以及在油/水界面的吸附状态。离子液体表面活性剂与DNA的相互作用主要来源于静电吸引和疏水作用。 Interactions between ionic liquid surfactants and bioactive molecules were summarized in three aspects.Hydrophobic ionic liquid surfactants can form inclusion complexes with β-cyclodextrin (β-CD) according to ratio of 1∶1,1∶2 or 2∶1;while hydrophilic ionic liquid surfactants cannot.The cmc and adsorption of ionic liquid surfactants at interface are affected by the inclusion complexes.The molecular structure and adsorption of protein at the interface between water and oil are affected by the interaction of ionic liquid surfactants with varied kinds of protein,such as bovine serum albumin,β-casein and lysozyme.The interactions between ionic liquid surfactants and DNA are caused by electrostatic attraction and hydrophobic action.

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响应面优化脱除直链烷基苯磺酸中的游离硫酸
Response surface test optimization of removal of free sulfuric acid
mixed in linear alkyl benzene sulfonic acid product

徐坤华, 史立文, 葛赞, 计晓黎, 王文德

2017 (11): 612-615. doi: 10.13218/j.cnki.csdc.2017.11.003

摘要 ( 285 )

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以单因素试验为基础,采用响应面法优化了直链烷基苯磺酸(LABSA)中的游离硫酸脱除工艺,并比较了游离硫酸脱除前后的LABSA样品的金属腐蚀性和贮存稳定性。结果表明,当氢氧化钙的质量分数1.25%,反应时间3.4 h,反应温度69 ℃,游离硫酸脱除率可达到100%。游离硫酸完全脱除后,金属的腐蚀性可显著降低,上部的ST37-2钢板质量损耗降低了63.16%,中部降低了71.88%,下部降低了67.82%。LABSA样品在35 ℃贮存2个月后,色泽基本保持不变,为29 Hazen。 Based upon results obtained from single factor experiments and in combination with response surface method,the eliminating technique of free sulfuric acid mixed in linear alkyl benzene sulfonic acid product was optimized.Performance of corrosion on metals caused by treated LABSA and untreated LABSA samples as well as their storage stability was compared.Results show that the optimum removal conditions are as follows:adding 1.25% Ca(OH)₂,reacting at 69 ℃ for 3.4 h.Under the above conditions,the removal rate of free sulfuric acid can be near to 100%.When the free sulfuric acid is removed completely,the corrosion on steel is reduced obviously.The weight loss of upper part of the ST37-2 steel plate sample is reduced by 63.16%,whiles the middle part and lower parts is 71.88% and 67.82% respectively.After storage at 35 ℃ for 2 months,the color of treated LABSA is 29 Hazen,which indicates that no significant color change happens.

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壳聚糖与CTAB复合缓蚀剂对Q235钢的缓蚀性能研究
Corrosion inhibition performance of chitosan and CTAB
blend system for Q235 steel in acidic medium

唐旭东, 刘金彦

2017 (11): 616-620. doi: 10.13218/j.cnki.csdc.2017.11.004

摘要 ( 288 )

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采用失重法、交流阻抗法和极化曲线法研究了盐酸介质中壳聚糖及其与十六烷基三甲基溴化铵(CTAB)复合缓蚀剂对Q235钢的缓蚀性能。测试结果表明,单独使用壳聚糖作为缓蚀剂,对Q235钢表面有较强的缓蚀性能。当壳聚糖的质量浓度为0.1 g/L时,在1.0 mol/L的盐酸介质中30 ℃腐蚀24 h,3种方法测得的缓蚀效率均达到85%以上;加入CTAB后,缓蚀性能明显增强,CTAB的质量分数为10%时,缓蚀效率达到了92%以上。2种缓蚀剂在Q235钢表面吸附机理不同且吸附过程相互补充,因此二者复配后缓蚀性能加强。 Corrosion inhibition performance for Q235 steel in acidic medium with chitosan and chitosan/cetyltrimethylammonium bromide (CTAB) blend system was studied with three methods (weight loss,potentio-dynamic polarization and electrochemical ac-impedance spectroscopy (EIS)).Results indicated that the inhibition efficiency is good that achieves 85% when the chitosan with mass concentration of 0.1 g/L is used as inhibitor alone and under conditions of corrosion medium,1.0 mol/L HCl;temperature,30 ℃ for 24 h.After addition of CTAB,the corrosion efficiency is significantly enhanced.When the mass fraction of CTAB is 10%,the inhibition efficiency reaches 92% and even higher.Both chitosan and CTAB show the corrosion inhibition performance.Their surface adsorption mechanism is different.However,when they are blended together,there is synergic effect and the corrosion inhibition efficiency is enhanced.

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再生木浆纤维素的制备及其稳定辛酸/癸酸甘油三酯乳液的性能研究
Properties of GTCC emulsions stabilized by regenerated
wood pulp cellulose

周倩倩, 王碧佳, 徐红, 隋晓锋, 施波波

2017 (11): 621-626. doi: 10.13218/j.cnki.csdc.2017.11.005

摘要 ( 419 )

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以高纯木浆板为原料制得再生木浆纤维素(W-RC),并用TEM、FT-IR和XRD对其进行表征,说明W-RC属于典型的纳米基纤维素Ⅱ型颗粒。以辛酸/癸酸甘油三酯(GTCC)为油相,W-RC为乳化剂,制得O/W型Pickering乳液,并通过光学显微镜、荧光显微镜、FE-SEM及流变仪对乳液进行表征。荧光显微镜与FE-SEM的结果显示W-RC吸附在油/水界面并在微球表面及微球间形成三维网状结构。流变学表明W-RC及由其稳定的乳液具有典型的剪切变稀特性。W-RC具有优良的乳化性能,在W-RC质量分数为0.6%、分散相体积分数高达60%时,也能得到稳定的乳液。 The regenerated wood pulp cellulose (W-RC) was prepared with high purity wood pulp board as raw material and the product was characterized by TEM,FT-IR and XRD.Results indicate that W-RC belongs to the typical nanometer cellulose Ⅱ particles.O/W Pickering emulsion was prepared using caprylic/capric triglycerides (GTCC) as the oil phase and W-RC as the emulsifier.The Pickering emulsions were characterized by optical microscopy,fluorescence microscopy,FE-SEM and rheometer.Results show that W-RC is adsorbed at the oil-water interface and a three-dimensional network structure is formed on and in between oily microspheres from fluorescence microscopy and FE-SEM image.The rheology study illustrates that W-RC and the resulting emulsions feature the typical shear-thinning property of emulsions.W-RC displays excellent emulsifying properties,and a stable emulsion can be obtained when the W-RC mass fraction is 0.6% and even if the dispersed phase volume fraction is as high as 60%.

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改性蒙脱土的制备及其协同海藻酸衍生物稳定Pickering乳液的研究
Preparation of modified montmorillonite and its function for stabilizing
Pickering emulsions in cooperation with alginic acid derivative

胡德平, 张雪琴, 戴子豪, 陈秀琼, 颜慧琼, 林强

2017 (11): 627-632. doi: 10.13218/j.cnki.csdc.2017.11.006

摘要 ( 290 )

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以十六烷基三甲基溴化铵(CTAB)作为疏水改性剂,利用湿法球磨对蒙脱土(MMT)进行改性,制备了插层型的改性蒙脱土(CMMT)。采用SEM、zeta电位分析仪、FT-IR、XRD、TEM和TGA对CMMT进行表征。进而,以两亲性海藻酸衍生物(Ugi-Alg)协同CMMT来稳定Pickering乳液,探究改性剂添加量不同时制备的CMMT对Pickering乳液稳定性的影响。实验结果显示,CTAB在湿法球磨的机械作用下插入了MMT微粒片层中。Ugi-Alg吸附于CMMT微粒表面,使CMMT微粒在油/水界面的聚集能力增强。当CTAB的添加量为1.0倍CEC时,CMMT微粒的带电量最低,乳液稳定性最高。 The intercalating modified montmorillonite (CMMT) was prepared by wet type ball mill process with montmorillonite (MMT) as basic material and hexadecyltrimethylammonium bromide (CTAB) as hydrophobic modifying agent.Then the product CMMT was characterized by SEM,zeta potential analyzer,FT-IR,XRD,TEM and TGA.Furthermore,stable Pickering emulsions were prepared by CMMT in cooperation with amphiphilic alginic acid derivative (Ugi-Alg),and then the effect of the CMMT that modified with varied amount of CTAB on the stability of Pickering emulsion was investigated.Experimental results show that the CTAB is intercalated into the lamella interlayers of MMT micro-particulates by the mechanical action of the ball mill.Ugi-Alg is adsorbed on surface of the CMMT,that enhancing the aggregation capacity of the CMMT particulates at the oil-water interface.When the addition amount of CTAB is 1.0CEC,the charge of CMMT particulates is at the lowest while the emulsion stability is the highest.

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3D皮肤模型的构建及其在化妆品原料活性物功效检测中的应用研究
Reconstruction of 3D skin model and its application in evaluation
the efficacy of cosmetic raw materials to be used as active ingredients

宋肖洁, 周春霞, 吴越

2017 (11): 633-636. doi: 10.13218/j.cnki.csdc.2017.11.007

摘要 ( 537 )

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使用Mimedisc作为支架,接种正常人真皮成纤维细胞,经过3周培养形成类似真皮结构,然后在其上接种正常人表皮角质细胞,依次经过浸没培养阶段和气-液相培养阶段,最终在体外形成3D皮肤结构模型。通过Masson染色及一系列免疫荧光染色显示此3D皮肤模型有近似真实皮肤的结构及关键蛋白表达。以此模型为工具研究了活性物喜马拉雅雪松精粹对皮肤真表皮连接处(DEJ)的作用。结果显示喜马拉雅雪松精粹可以明显提高表皮的厚度,增加皮肤抵抗外界环境的屏障能力,并且可以显著促进DEJ重要蛋白层粘连蛋白5(Laminin 5)和VII型胶原蛋白(Collagen VII,Col VII)的表达,使Laminin 5上调20%,Col VII上调47%,具有应用于抗衰老类化妆品的潜力。 Via the use of Mimedisc^® as a scaffold,the normal human dermal fibroblasts were first seeding into the scaffold to form a dermal equivalent after 3 weeks;and then seeding normal human epidermal keratinocytes on it,followed by immersion and air-liquid inter-phase culture stage,to finally form a 3D sponge matrix skin model which has a very similar structure of normal human skin (NHS).The results of Masson staining,immuno-histochemical (IHC) and immuno-fluorescence (IF) staining show that this skin model displays a very similar structure and key protein expression of NHS.Meanwhile,this model was used as a tool to investigate the effect of Himalaya cedar extract on Dermal-Epidermal Junction (DEJ) in vitro.Results show that the Himalayan cedar extract can significantly increase the thickness of the epidermis,thus increase the barrier capacity of the skin to resist external environment.Further,the Himalaya cedar extract can promote the expression of Laminin 5 and Collagen VII of DEJ.The expression of the Laminin 5 and Collagen VII increases 20% and 47% respectively.So the Himalaya cedar extract displays the potential to be applied in development of anti-aging cosmetics.

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裂褶多糖磷酸化衍生物的制备与性能研究
Preparation and properties of schizophyllan polysaccharide
phosphorylated derivative

冯小玲, 方兆华, 刘建欣, 孙永, 周立武

2017 (11): 637-640. doi: 10.13218/j.cnki.csdc.2017.11.008

摘要 ( 316 )

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以三聚磷酸钠和三偏磷酸钠为原料对裂褶多糖进行磷酸化改性制得裂褶多糖磷酸化衍生物,通过单因素试验探究了反应物质量比、反应温度和反应时间对产物取代度的影响。结果表明较佳反应条件为:m(三聚磷酸钠-三偏磷酸钠)∶m(裂褶多糖)=2∶1,反应温度60 ℃,反应时间3 h,在此条件下磷酸化反应的取代度为0.052。研究了磷酸化改性前后裂褶多糖的水溶性、抗氧化能力和保湿性。实验结果表明磷酸化改性极大地改善了裂褶多糖的水溶性,抗氧化能力略有提高,保湿性有明显提高。 Schizophyllan polysaccharide phosphorylated derivative was prepared from schizophyllan polysaccharide by modification with sodium tripolyphosphate and sodium trimetaphosphate.The effects of mass ratio of reactants, reaction temperature and reaction time on the degree of substitution were examined by single factor experiments.Experimental results show that the better conditions for the preparation are:mass ratio,m(sodium tripolyphosphate + sodium trimetaphosphate,with equal molar blend)∶m(schizophyllan polysaccharide) = 2∶1;reaction temperature,60 ℃;and reaction time,3 h.Under these conditions,the degree of substitution of phosphorylation achieves 0.052.The solubility,antioxidantion activity and moisturizing capacity of schizophyllan polysaccharide before and after phosphorylation were studied.Results show that the solubility and moisturizing capacity of schizophyllan polysaccharide are greatly improved by phosphorylation modification.The phosphorylation modification displays little effectiveness on improving antioxidation activity of the schizophyllan polysaccharide.

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SBA-15复合材料的制备及其催化合成环己酮乙二醇缩酮
Preparation of SBA-15 and its catalytic performance in
synthesis of cyclohexanone ethylene ketal

向诗银, 李志鹏, 杨水金

2017 (11): 641-644. doi: 10.13218/j.cnki.csdc.2017.11.009

摘要 ( 375 )

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将金属离子嫁接在SBA-15的孔道中作为催化剂,考察其催化合成环己酮乙二醇缩酮的性能。使用FT-IR、SEM和XRD对催化剂的结构进行表征,结果表明合成的催化剂为目标催化剂。固定环己酮用量为0.2 mol,当乙二醇与环己酮的摩尔比为1.7∶1,催化剂的用量为反应底物质量的1.2%,带水剂环己烷的用量为14 mL,反应时间为100 min时,Co/SBA-15催化合成效果最好,环己酮乙二醇缩酮的收率为89.8%。 Metal ions were grafted into the pores of SBA-15 and the grafted product was examined for using as catalyst in synthesis of cyclohexanone ethylene ketal.Structure of the catalyst was characterized by FT-IR,SEM and XRD.And the characterizing results show that the catalyst prepared is the targeted one.Then,experiment for the synthesis of cyclohexanone ethylene ketal was carried out with various catalysts.Experimental results show that as dosage of cyclohexanone is fixed at 0.2 mol;molar ratio of glycol to cyclohexanone is 1.7∶1;dosage of the catalyst is 1.2% (mass) of the reactants;volume of water stripping agent,cyclohexane is 14 mL;reaction time is 100 min;catalyst Co/SBA-15 displays the best result that the yield of cyclohexanone ethylene ketal achieves 89.8%.

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腰果酚表面活性剂的合成研究进展
Research progress on synthesis of cardanol-based surfactants

葛赞, 史立文, 代永昌, 华文高, 刘荣

2017 (11): 645-650. doi: 10.13218/j.cnki.csdc.2017.11.010

摘要 ( 426 )

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综述了腰果酚表面活性剂的合成研究进展,重点介绍了腰果酚磺酸盐、腰果酚硫酸盐、腰果酚羧酸盐及腰果酚聚氧乙烯醚等表面活性剂的合成方法,并分别对其性能进行了概述。腰果酚表面活性剂除了具有优良的性能,其绿色的原料来源也更符合发展潮流。 The progress in the research work field for cardanol-based surfactants were described,which focused on the development of synthesis methods for production as well as properties of the cardanol-based surfactants,covering sulfonates,sulfates,carboxylates and cardanol polyoxyethylene ethers were summarized separately.In addition to their excellent performance,the green source of raw materials used for producing cardanol-based surfactants is more consistent with the worldwide development trend.

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变性淀粉在化妆品中的应用研究进展
Progress in research work field for applications of
modified starch in cosmetics

王秋丽, 高合意, 王立丹, 王瑞航, 黄立新

2017 (11): 651-654. doi: 10.13218/j.cnki.csdc.2017.11.011

摘要 ( 505 )

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简述了变性淀粉的分类,主要综述了变性淀粉在不同剂型的普通化妆品、功能性化妆品及化妆品新品中的开发和应用以及国内外的研究现状与进展,并对相关的技术问题进行探讨和展望。 The classifications of modified starch were briefed.Status with respect to development and applications of modified starch in conventional cosmetics of varied dose forms,functional cosmetics and new cosmetics in China domestic and worldwide were reviewed.Meanwhile,the related technical problems were discussed and prospected.

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高效液相色谱法检测氨基酸表面活性剂中脂肪酸的含量
Detection of content of fatty acids in amino acid-based surfactants by
high performance liquid chromatography

李泽勇, 陈磊, 刘康, 汤仲标, 张利萍

2017 (11): 655-658. doi: 10.13218/j.cnki.csdc.2017.11.012

摘要 ( 467 )

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建立了一种快速检测氨基酸表面活性剂中脂肪酸残留的高效液相色谱分析方法。采用Welch Ultimate AQ-C₁₈色谱柱(250 mm×4.6 mm,5 μm)分离,以乙腈-0.1%甲酸水溶液为流动相进行梯度洗脱,样品经过酸化、衍生化处理后用紫外可见可变波长检测器(VWD)检测。结果表明,该方法的线性范围为5~500 mg/L,相关系数均大于0.999,平均回收率为93.2%~103.0%,检出限为0.03%,定量限为0.1%。方法耗时短、操作简单、准确度高、通用性强,适用于氨基酸表面活性剂产品的脂肪酸残留检测。 A high performance liquid chromatography (HPLC) method for the detection of content of fatty acids in amino acid-based surfactants was established.Separation is performed by a Welch Ultimate AQ-C₁₈ column (250 mm×4.6 mm,5 μm) with acetonitrile-0.1% formic acid aqueous solution as the mobile phase for gradient elution.After acidification and derivatization,the sample is detected with a UV and visible light wavelength variable detector (VWD).Results show that,all linearity ranges of the fatty acids are within 5-500 mg/L with the correlation coefficients greater than 0.999.The spiked recoveries vary from 93.2%-103.0%.The limits of determination and quantification are 0.03% and 0.1%,respectively.The method is simple,time-saving and precise,which may be suitable for fatty acids determination in amino acid-based surfactants.

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高效液相色谱-蒸发光散射法测定蛇皮中胶原蛋白含量
Determination of collagen content in snake skin by HPLC-ELSD

丁瑞敏, 周华锋, 李赟高, 蔡衡, 段明星, 靳清贤

2017 (11): 659-662. doi: 10.13218/j.cnki.csdc.2017.11.013

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建立高效液相色谱-蒸发光散射检测(HPLC-ELSD)法测定蛇皮胶原蛋白含量的方法。胶原蛋白经盐酸水解后,采用Thermo Hypersil Gold C₁₈(250 mm×4.6 mm,5 μm)色谱柱进行分离,以乙腈(含0.2%甲酸,A相)-0.2%甲酸水溶液(B相)为流动相进行梯度洗脱,洗脱时间15 min,柱温30 ℃,流速0.4 mL/min。ELSD参数:雾化器温度85 ℃,蒸发器温度85 ℃,氮气作载气,蒸发器气流1.2 L/min。进样量10 μL。在此条件下,羟脯氨酸的线性范围为10~100 mg/L,R²=0.999 6,检测限为5.56 mg/L,定量限为10 mg/L。蛇皮胶原蛋白的平均回收率为94.53%,RSD为2.15%。蛇皮中胶原蛋白质量分数平均值为40.21%,为蛇皮的主要蛋白质。 A high performance liquid chromatography-evaporative light scattering detection (HPLC-ELSD) method for determination of content of collagen in snake skin was established.After the collagen in snake skin sample was hydrolyzed with hydrochloric acid,separation was performed by a Thermo Hypersil Gold C₁₈(250 mm×4.6 mm,5 μm) chromatographic column and acetonitrile (containing 0.2% formic acid,mobile phase A)-water (containing 0.2% formic acid,mobile phase B) as the mobile phase were used for gradient elution.The elution time is 15 min.The column temperature is 30 ℃;and the flow rate is 0.4 mL/min.The ELSD detector parameters are as follows:nebulization temperature,85 ℃;evaporation temperature,85 ℃;carrier gas,N₂;air flow of the evaporator,1.2 L/min.The injection volume of the sample is 10 μL.Under these chromatographic conditions,the linearity range of hydroxyproline is 10 - 100 mg/L,R² = 0.999 6;the lowest limit of detection is 5.56 mg/L,and the lowest limit of quantification is 10 mg/L.The average recovery rate of snake skin collagen is 94.53%;the RSD is 2.15%;and the average of the mass fraction of collagen in snake skin is 40.21%.

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