胺基CO2开关型表面活性剂的合成与性能研究

doi:10.13218/j.cnki.csdc.2017.07.003

摘要/Abstract

摘要： 以溴代十四烷和二乙烯三胺为原料,合成了表面活性剂十四烷基二乙烯三胺(C₁₄DETA)。采用红外光谱和核磁共振氢谱对C₁₄DETA进行了结构表征。通过研究其电导率可逆、pH可逆和与SDS协同作用的开启,证明了C₁₄DETA具有良好的CO₂开关性能。测定了十四烷基二乙烯三胺碳酸氢盐(C₁₄DETA-CO₂)和SDS/C₁₄DETA-CO₂复配体系的临界胶束浓度,分别为1.0×10^-2和1.0×10^-4 mol/L。通过测定C₁₄DETA-CO₂对正癸烷/水体系的乳化性能,证明了C₁₄DETA-CO₂具有良好的乳化性能,所制得乳状液为W/O型,其较佳乳化条件为:C₁₄DETA-CO₂的质量分数4%,油水体积比1∶1或1∶2。

关键词: CO₂开关型表面活性剂, 表征, 临界胶束浓度, 性能

Abstract: Surfactant tetradecyldiethylenetriamine (C₁₄DETA) was synthesized with 1-bromotetradecane and diethylenetriamine as starting materials.Its structure was characterized by FT-IR and ¹H NMR spectrum.Measurement of reversibility of conductivity,reversibility of pH values,and the opening action of synergistic effect with SDS demonstrate the good CO₂ switchability of C₁₄DETA.The critical micelle concentrations (cmc) of tetradecyldiethylenetriamine bicarbonate (C₁₄DETA-CO₂) and the mixed system of SDS/C₁₄DETA-CO₂ are 1.0×10^-2 and 1.0×10^-4 mol/L respectively.Results of emulsifying performance of C₁₄DETA-CO₂ for n-decane/water system prove the good emulsifying power of C₁₄DETA-CO₂.The emulsion is water-in-oil type,and its better emulsifying conditions are:mass fraction of C₁₄DETA-CO₂,4%;and the volume ratio of oil/water,1∶1 or 1∶2.

Key words: CO₂ switchable surfactant, characterization, critical micelle concentration, performance

中图分类号:

TQ423

张鹏, 梅平, 赖璐. 胺基CO₂开关型表面活性剂的合成与性能研究[J]. 日用化学工业, 2017, 47(7): 369-373.

ZHANG Peng, MEI Ping, LAI Lu. Synthesis and performance of CO₂ switchable amine surfactants[J]. China Surfactant Detergent & Cosmetics, 2017, 47(7): 369-373.

参考文献

[1]柴明峰.长链烷基咪唑类表面活性剂的合成与性能研究[D].大连:大连理工大学,2014.
[2]梅平,闵红博,赖路.CO₂开关型表面活性剂的合成及应用研究进展[J].油田化学,2016,33(3):564-570.
[3]Brown P,Butts C P,Eastoe J.Stimuli-responsive surfactants [J].Soft Matter,2013,9(8):2365-2374.
[4]Yang Y,Yue L,Li H,et al.Photo-responsive self-assembly of an azobenzene-ended surfactant-encapsulated polyoxometalate complex for modulating catalytic reactions [J].Small,2012,8(20):3105-3110.
[5]Shang T,Smith K A,Hatton T A.Photoresponsive surfactants exhibiting unusually large,reversible surface tension changes under varying illumination conditions [J].Langmuir,2003,19(26):10764-10773.
[6]Wang Y P,Ma N,Wang Z,et al.Photocontrolled reversible supramolecular assemblies of an azobenzene-containing surfactant with α-cyclodextrin [J].Angewandte Chemie International Edition,2007,46(16):2823-2826.
[7]Chu Z L,Feng Y J.pH-switchable wormlike micelles [J].Chemical Communications,2010,46(47):9028-9030.
[8]Jiang Z,Li X,Yang G,et al.pH-responsive surface activity and solubilization with novel pyrrolidone-based Gemini surfactants [J].Langmuir,2012,28(18):7174-7181.
[9]Li X F,Yang Y,Eastoe J,et al.Rich self-assembly behavior from a simple amphiphile [J].ChemPhysChem,2010,11(14):3074-3077.
[10] Tsuchiya K,Sakai H,Saji T,et al.Electrochemical reaction in an aqueous solution of a ferrocene-modified cationic surfactant mixed with an anionic surfactant [J].Langmuir,2003,19(22):9343-9350.
[11] Datwani S S,Nguyen T V,Rosslee C A,et al.Redox-dependent surface tension and surface phase transitions of a ferrocenyl surfactant:equilibrium and dynamic analyses with fluorescence images [J].Langmuir,2003,19(20):8292-8301.
[12] Kakizawa Y,Sakai H,Yamaguchi A,et al.Electrochemical control of vesicle formation with a double-tailed cationic surfactant bearing ferrocenyl moieties [J].Langmuir,2001,17(26):8044-8048.
[13] Patel A R,Drost E,Blijdenstein T B J,et al.Stable and temperature-responsive surfactant-free foamulsions with high oil-volume fraction [J].ChemPhysChem,2012,13(17):3777-3781.
[14] Lin Y Y,Qiao Y,Yan Y,et al.Thermo-responsive viscoelastic wormlike micelle to elastic hydrogel transition in dual-component systems [J].Soft Matter,2009,5(16):3047-3053.
[15] Chu Z L,Feng Y J.Thermo-switchable surfactant gel [J].Chemical Communications,2011,47(25):7191-7193.
[16] Fowler C I,Jessop P G,Cunningham M F.Aryl amidine and tertiary amine switchable surfactants and their application in the emulsion polymerization of methyl methacrylate [J].Macromolecules,2012,45(7):2955-2962.
[17] Zhang Y M,Feng Y J,Wang J,et al.CO₂-switchable wormlike micelles [J].Chemical Communications,2013,49(43):4902-4904.
[18] Limanov V E,Rapin S A,Ivanov S B.Synthesis of higher aliphatic alkylpolyamines [J].Pharmaceutical Chemistry Journal,1981,15(3):213-214.
[19] Chai M F,Zheng Z B,Bao L,et al.CO₂/N₂ triggered switchable surfactants with imidazole group [J].Journal of Surfactants and Detergents,2014,17(3):383-390.
[20] Zhang Y M,Chu Z L,Dreiss C A,et al.Smart wormlike micelles switched by CO₂ and air [J].Soft Matter,2013,9(27):6217-6221.
[21] Zhang Y M,Guo S,Wu W,et al.CO₂-triggered pickering emulsion based on silica nanoparticles and tertiary amine with long hydrophobic tails [J].Langmuir,2016,32(45):11861-11867.
[22] Qiao W H,Zheng Z B,Shi Q.Synthesis and properties of a series of CO₂ switchable surfactants with imidazoline group [J].Journal of Surfactants and Detergents,2012,15(5):533-539.
[23] Lai L,Mei P,Wu X M,et al.Interfacial dynamic properties and dilational rheology of mixed anionic and cationic gemini surfactant systems at air-water interface [J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2016,509:341-350.

胺基CO₂开关型表面活性剂的合成与性能研究

Synthesis and performance of CO₂ switchable amine surfactants

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