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日用化学工业 ›› 2016, Vol. 46 ›› Issue (10): 571-575.doi: 10.13218/j.cnki.csdc.2016.10.005

• 开发与应用 • 上一篇    下一篇

Gemini双季铵盐表面活性剂与SDBS和SDS的复配行为

杨晶晶,吴文英,魏文珑,常宏宏   

  1. 太原理工大学 化学化工学院,山西 太原 030024
  • 出版日期:2016-10-22 发布日期:2019-04-18
  • 通讯作者: 常宏宏,副教授,博士,电话:(0351)6111165,E-mail:changhonghong@tyut.edu.cn。
  • 作者简介:杨晶晶(1985-),女,山西隰县人,硕士,电话:(0351)6111165,E-mail:275806675@qq.com。
  • 基金资助:
    国家自然科学基金资助项目(21206103,21076135);道路结构与材料交通运输行业重点实验室开放基金资助项目(KF201403);山西省科技攻关项目(20140321018-05);山西省自然科学基金资助项目(2015011023);表面活性剂山西省重点实验室开放基金资助项目(201503)

Synergistic effect of bis-quaternary ammonium salt Gemini surfactant blended separately with sodium dodecylbenzene sulfonate and sodium dodecane sulfonate

YANG Jing-jing,WU Wen-ying,WEI Wen-long,CHANG Hong-hong   

  1. College of Chemistry and Chemical Engineering,Taiyuan University of Technology,Taiyuan,Shanxi 030024,China
  • Online:2016-10-22 Published:2019-04-18

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摘要： 采用荧光分光光度法和Zeta电位法考察了系列Gemini双季铵盐表面活性剂与阴离子表面活性剂十二烷基苯磺酸钠(SDBS)和十二烷基磺酸钠(SDS)的复配效果。结果表明,Gemini双季铵盐表面活性剂疏水链和连接基越长,cmc越小,且疏水链长度对表面活性剂性能的影响较大;Gemini双季铵盐表面活性剂的加入可显著提高阴离子表面活性剂SDBS和SDS的表面活性,当Gemini双季铵盐表面活性剂与SDBS或SDS的摩尔比为3∶7时,复配体系的cmc最小,且与SDS复配体系的性能优于与SDBS的复配体系。

关键词: Gemini双季铵盐表面活性剂, 十二烷基苯磺酸钠, 十二烷基磺酸钠, 复配

Abstract: Synergistic effect of bis-quaternary ammonium salt Gemini surfactant blended separately with sodium dodecylbenzene sulfonate (SDBS) and sodium dodecane sulfonate (SDS) were investigated by fluorospectrophotometry and Zeta potential method.Results showed that the longer the hydrophobic chains and the space group of the bis-quaternary ammonium salt Gemini surfactant,the lower the cmc value;while length of the hydrophobic chain displays bigger effect on performance of the surfactant.Addition of bis-quaternary ammonium salt Gemini surfactant can significantly increase the surface activity of anionic surfactants such as SDBS and SDS.When molar ratio of the bis-quaternary ammonium salt Gemini surfactant to SDBS (SDS) is 3∶7,cmc of the blended surfactant achieves the least.Synergistic effect of the bis-quaternary ammonium salt Gemini surfactant with SDS is better than that with SDBS.

Key words: bis-quaternary ammonium salt Gemini surfactant, sodium dodecylbenzene sulfonate, sodium dodecane sulfonate, blend

中图分类号: 

  • TQ423