烷基糖苷磺基琥珀酸酯盐与烷基糖苷的复配性能和相行为

doi:10.3969/j.issn.1001-1803.2020.01.004

摘要/Abstract

摘要：

分别对烷基糖苷磺基琥珀酸酯盐（APG-SS）和烷基糖苷（APG）不同摩尔比复配体系的表面张力和泡沫性能进行研究,同时研究烷基糖苷/烷基糖苷磺基琥珀酸酯盐/水三元体系的相行为。结果表明：APG-SS与APG摩尔比为2∶8时,表面张力达到27.90 mN/m,cmc=0.044 mmol/L,Γ_max=10.86 μmol/m ²,A_min=0.15 nm ²,与其他摩尔比复配体系相比,表面性能较好,具有较好的协同效应。在蒸馏水和硬水中,APG-SS与APG摩尔比为2∶8和4∶6的复配体系的起泡性能均优于单一表面活性剂,具有较好的协同效应。同时,复配体系的泡沫稳定性优于APG,可改善APG的抗硬水能力。APG-SS/APG/H₂O体系的三元相图出现胶束相、胶束-液晶共存区和双水相区。

关键词: 烷基糖苷, 烷基糖苷磺基琥珀酸酯盐, 复配, 表面活性, 泡沫性能, 相行为

Abstract:

The mixtures of alkyl polyglycoside （APG） and alkyl polyglycoside sulfosuccinate （APG-SS） with different mixing ratios were studied by measuring their surface activity and foaming properties. The phase behavior of the ternary system of APG/APG-SS/H₂O was also studied. The results show that the best synergism is found in surface activity （γ_cmc=27.90 mN/m, cmc=0.044 mmol/L, Γ_max=10.86 μmol/m ², A_min=0.15 nm ²） when n_APG-SS∶n_APG=2∶8. The mixed system has higher foaming ability in distilled water and hard water than single surfactant when n_APG-SS∶n_APG=2∶8 and 4∶6, so it has synergism. At the same time, the foam stability of the mixed system is better than APG, which can improve the hard water resistance of APG. The phase diagrams of the APG-SS/APG/H₂O ternary systems were characterized by micellar phase, a region where lamellar liquid crystal and micellar phases coexisted and a region of “aqueous two-phase”.

Key words: alkyl polyglycoside, alkyl polyglycoside sulfosuccinate, compounding, surface activity, foaming ability, phase behavior

中图分类号:

TQ423

周媛,杨秀全,张军. 烷基糖苷磺基琥珀酸酯盐与烷基糖苷的复配性能和相行为[J]. 日用化学工业, 2020, 50(1): 20-25.

ZHOU Yuan,YANG Xiu-quan,ZHANG Jun. Performance and phase behavior of the mixture of alkyl polyglycoside sulfosuccinate and alkyl polyglycoside[J]. China Surfactant Detergent & Cosmetics, 2020, 50(1): 20-25.

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参考文献 20

[1]	Yin Daiyin, Jiang Tingting . Research on the mechanism of anionic/nonionic surfactants applied in low permeability reservoirs[J]. Chemical Engineer, 2017,261(6) : 6-10.
[2]	Wang Jun, Yang Xuzhao, Li Nini , et al. Study of the perform ance of the blends of sugar-based cationic Gemini surfactants and sodium dodecyl sulfate[J]. China Surfactant Detergent & Cosmetics, 2019,49(1) : 16-19.
[3]	Weil I. Skin treatment composition containing monoester of citric acid: US5047166[P]. 1991 -09-10.
[4]	Liang Liyun, Lan Renhua, Chen Huanqin . Research on the application and complex in cosmetic of APG and China herbal medicine[J]. China Surfactant Detergent & Cosmetics, 2002,32(2) : 36-39.
[5]	Sohrabi B, Gharibi H, Tajik B , et al. Molecular interactions of cationic and anionic surfactants in mixed monolayers and aggregates[J]. Journal of Physical Chemistry B, 2008,112:14869-14876.
[6]	Herrington K L, Kaler E W . Phase behavior of aqueous mixtures of dodecyltrimethylammonium bromide (DTAB) and sodium dodecyl sulfate (SDS)[J]. Journal of Physical Chemistry, 1997,97:13792-13802.
[7]	Han Zhiguo, Yang Xiuquan, Liu Yong . Micellar and interfacial behavior of mixed systems containing glycoside-based surfactant and cationic didecyldimethylammonium chloride[J]. Journal of Surfactant Detergent, 2015,18:873-880.
[8]	Zhang Xiaolan, Zhou Yuan, Yang Xiuquan . Physicochemical properties of alcohol polyoxyethylene ether acetate/alkyl ethoxy polyglycoside surfactant mixtures[J]. Journal of Dispersion Science and Technology, 2017,38(9) : 1252-1257.
[9]	Zhai Limin, Wang Hui, Xu Jian , et al. Salt-induced spontaneous vesicle formation from aqueous mixture of anionic/nonionic surfactants[J]. Acta Chimica Sinica, 2007,65(1) : 27-31.
[10]	Balzer D, Lüders H . Nonionic surfactants alkyl polyglucosides[M]. New York: Marcel Dekker, 2000: 85-278.
[11]	Balzer D . Alkylpolyglucosides, their physico-chemical properties and their uses[J]. Tenside Surfactants Deterg, 1991,28(6) : 419-427.
[12]	O’Lenick Jr A J .Alkoxylated surfactants based upon alkyl polyglycoside: US6800741 [P]. 2014 -10-05.
[13]	Gao Yuyang, Yang Xiuquan, Bai Liang , et al. Preparation and physiochemical properties of disodium lauryl glucosides sulfosuccinate[J]. Journal of Surfactant Detergent, 2014,17:603-608.
[14]	Gao Yuyang, Yang Xiuquan . Equilibrium and dynamic surface properties of sulfosuccinate surfactants[J]. Journal of Surfactant Detergent, 2014,17:1117-1123.
[15]	Zhang Qinghong, Li Yunling, Song Yongbo , et al. Adsorption behavior of branched polyoxyethylene ether carboxylate surfactants[J] . Colloids and Surfaces A, 2018,538:361-370.
[16]	Bai Liang, Yang Xiuquan, Wu Zhiyu . Study of physical and chemical properties of alkyl polyxylosidase[J]. China Surfactant Detergent ＆ Cosmetics, 2018,48(11) : 622-626.
[17]	Ziyafaddin H Asadov, Shafiga M Nasibova, Gulnara A Ahmadova , et al. Head-group effect of surfactants of cationic type in interaction with propoxylated sodium salt of polyacrylic acid in aqueous solution[J] . Colloids and Surfaces A, 2017,527:95-100.
[18]	Sierra M L, Svensson M . Mixed micelles containing alkylglycosides: effect of the chain length and the polar head group[J]. Langmuir, 1999,15:2301-2306.
[19]	Rosen M J . Surfactants and interfacial phenomena[M]. New York: Wiley, 2004.
[20]	Farajzadeh R, Krastev R ,Zitha Pacelli L J.Foam film permeability: Theory and experiment[J]. Advances in Colloid and Interface Science, 2008,137:21-44.

n_APG-SS∶n_APG	cmc/ （mmol·L^-1）	γ_cmc/ （mN·m^-1）	Γ_max/ （μmol·m^-2）	A_min/nm²	pc₂₀
10∶0	0.125	30.94	1.72	0.97	5.00
8∶2	0.075	29.40	5.20	0.32	5.20
6∶4	0.058	29.21	5.62	0.30	5.23
4∶6	0.048	28.02	8.03	0.21	5.35
2∶8	0.044	27.90	10.86	0.15	5.36
0∶10	0.049	28.33	9.88	0.17	5.36

样品	w/%
样品	APG-SS	APG	H₂O
1	0.136 2	0.222 1	0.641 7
2	0.344 5	0.096 8	0.558 7
3	0.213 5	0.248 9	0.537 6
4	0.023 1	0.438 2	0.538 8