改性油脂乙氧基化物与平平加二元复配体系的性能研究

doi:10.3969/j.issn.1001-1803.2019.03.005

日用化学工业 ›› 2019, Vol. 49 ›› Issue (3): 162-166.doi: 10.3969/j.issn.1001-1803.2019.03.005

改性油脂乙氧基化物与平平加二元复配体系的性能研究

张勇,周婧洁,孙永强(),孙晋源,梁慧斌,武华萍

中国日用化学研究院有限公司,山西太原 030001

收稿日期:2018-09-04 修回日期:2019-02-27 出版日期:2019-03-22 发布日期:2019-04-04
通讯作者: 孙永强
作者简介:张勇（1984-）,男,山西人,工程师,电话：13934146593,E-mail：ridcizhy@163. com。
基金资助:
国家重点研发计划资助项目(2017YFB0308800)

Study on performance of modified oil ethoxylates and peregal blend system

Yong ZHANG,Jing-jie ZHOU,Yong-qiang SUN(),jin-yuan SUN,Hui-bin LIANG,Hua-ping WU

China Research Institute of Daily Chemistry Co., Ltd., Taiyuan, Shanxi 030001, China

Received:2018-09-04 Revised:2019-02-27 Online:2019-03-22 Published:2019-04-04
Contact: Yong-qiang SUN

摘要/Abstract

摘要：

通过水溶性、凝固点、润湿、乳化、去污及泡沫性能的测试,研究了非离子表面活性剂改性油脂乙氧基化物（SOE-N-60）与平平加O-20、平平加O-25的二元复配体系的性能。结果表明,25 ℃时,对于总质量分数为70%的SOE-N-60与平平加二元复配产品,SOE-N-60与平平加O-25的质量比大于5:5时;SOE-N-60与平平加O-20的质量比大于4:6时;均能形成均一透明的体系,且产品的凝固点均低于10 ℃;SOE-N-60与平平加O-20及平平加O-25的二元复配体系的去污性能以及对液体石蜡的乳化性能均表现出一定的协同增效作用;复配体系的泡沫略高于单一SOE-N-60。此类复配产品有望用于低温低泡浓缩液体洗涤剂配方中。

关键词: 改性油脂乙氧基化物, 平平加, 复配, 性能

Abstract:

Through the tests of water solubility, freezing point, wetting, emulsification, decontamination and foam properties, the performance of the binary blend system of non-ionic surfactant modified SOE-N-60 with peregal O-25 and peregal O-20 respectively were estimated. The results show that the binary compound system of SOE-N-60 with a total mass fraction of 70% and peregal at 25 ℃ is uniform and transparent and the freezing points of the products are all below 10 ℃, when the mass ratio of SOE-N-60 to peregal O-25 is greater than 5:5 and the mass ratio of SOE-N-60 to peregal O-20 is greater than 4:6. The decontamination performance and liquid paraffin emulsifying performance of the compound products exhibit a certain synergistic effect. The foaming properties of the compound products are slightly higher than the single SOE-N-60. Therefore, the compound products are suitable for the development of low temperature and low foam concentrated liquid detergent.

Key words: modified oil ethoxylates, peregal products, blend, performance

中图分类号:

TQ423

张勇,周婧洁,孙永强,孙晋源,梁慧斌,武华萍. 改性油脂乙氧基化物与平平加二元复配体系的性能研究[J]. 日用化学工业, 2019, 49(3): 162-166.

Yong ZHANG,Jing-jie ZHOU,Yong-qiang SUN,jin-yuan SUN,Hui-bin LIANG,Hua-ping WU. Study on performance of modified oil ethoxylates and peregal blend system[J]. China Surfactant Detergent & Cosmetics, 2019, 49(3): 162-166.

图/表 10

图1

图2

表1

表2

图3

图4

图5

图6

图7

图8

参考文献 9

[1]	Wang Zeyun, Chen Hailan . Recent progress in green surfactants for washing in China[J]. Detergent & Cosmetics, 2011,34(7) : 21-23.
[2]	Wang Fazeng . Liquid detergents - trends in laundry detergents in the United States[J]. Fine and Specialty Chemicals, 2000,8(3) : 15-16.
[3]	Xu Qing, Guo Jingping, Wu Wenhao , et al. How to improve the competitiveness of liquid detergents[J]. Detergent & Cosmetics, 2013,36(9) : 1-3. doi: 10.4018/jismd.2013070101
[4]	Jiang Li . The impact of domestic consumer appeals on the development trend of liquid detergent technology[J]. Detergent & Cosmetics, 2011,34(10) : 5-7.
[5]	He Jianjun . Development of a low foam concentrated laundry liquid[D]. Guangzhou: South China University of Technology, 2016.
[6]	Wen Pengpeng, Guo Jianguo, Liu Wei , et al. Study on properties of modified oil ethoxylates and their complex systems[J]. Detergent & Cosmetics, 2016,39(10) : 21-25.
[7]	Zhang Jingli . Development of a highly efficient concentrated laundry liquid[J]. Detergent & Cosmetics, 2017,40(7) : 19-23.
[8]	Guo Junhua . Development of low foaming and highly efficient concentrated laundry liquid[J]. China Cleaning Industry, 2015 ( 2) : 47-50.
[9]	Zhong Zhensheng, Xue Wanbo, Li Wenbo . Design and application of high efficiency low foaming detergent formula[J]. Textile Auxiliaries, 2004,21(6) : 4-8.

复配产品	凝固点/℃
复配产品	9:1	8:2	7:3	6:4	5:5	4:6	3:7	2:8	1:9
SOE-N-60/平平加O-25	-9	-6	1	3	9	33	49	66	72
SOE-N-60/平平加O-20	-9	-7.5	-6	-2	3	20	36	44	54

复配产品	t/min
复配产品	9:1	8:2	7:3	6:4	5:5	0:10
SOE-N-60/平平加O-25	15.16	14.10	18.38	23.22	/	>180
SOE-N-60/平平加O-20	16.48	20.60	22.22	23.88	32.47	>180

[1]	张志升, 沈产量, 李建勋, 刘延强, 韩薇薇, 董三宝. 甜菜碱/AOS/Gemini季铵盐三元复合型泡排剂的研制与性能评价[J]. 日用化学工业（中英文）, 2024, 54(3): 239-249.
[2]	胡可云. Fe₃O₄基核壳纳米结构材料的制备及顺磁性研究[J]. 日用化学工业（中英文）, 2024, 54(3): 298-304.
[3]	侯仕达, 王志飞, 王亚魁, 李俊, 姜亚洁, 耿涛. 多阳离子位点季铵盐与AEC复配体系的应用性能研究[J]. 日用化学工业（中英文）, 2024, 54(2): 131-138.
[4]	张红梅, 张永民. [芥酰胺苯甲酸][胆碱]离子液体表面活性剂的合成及性能研究[J]. 日用化学工业（中英文）, 2024, 54(2): 149-155.
[5]	周康夫, 晏佳怡, 尚亚卓. 新型乳化体系及其在化妆品中的应用（I）——液晶乳化体系[J]. 日用化学工业（中英文）, 2023, 53(9): 1008-1017.
[6]	常香玲, 柴菲. 氧化锌纳米复合抗菌材料的制备及性能研究[J]. 日用化学工业（中英文）, 2023, 53(9): 1051-1056.
[7]	崔丛丛,张红丽,玄光善. 多头季铵盐表面活性剂的合成及性能评价[J]. 日用化学工业（中英文）, 2023, 53(8): 899-907.
[8]	牛奇奇,吕其超,董朝霞,张风帆,王洪勃. 含蠕虫胶束的泡沫体系的性能研究进展[J]. 日用化学工业（中英文）, 2023, 53(8): 915-924.
[9]	周媛, 杨秀全, 张军, 白亮, 吴志宇. 不同酯化度烷基糖苷磺基琥珀酸酯盐的合成与性能[J]. 日用化学工业（中英文）, 2023, 53(7): 765-772.
[10]	张佩亮, 燕永利, 吕博, 曹玉霞, 吴春生, 贺炳成. CaCO₃纳米晶体稳定非水相泡沫实验研究[J]. 日用化学工业（中英文）, 2023, 53(6): 642-648.
[11]	高党鸽, 李随荣, 王历历, 吕斌, 赵静. 基于水/辛酸异戊酯-白油反相乳液体系合成压裂液增稠剂及性能[J]. 日用化学工业（中英文）, 2023, 53(6): 625-633.
[12]	孔秋婵, 蒋佳欣, 夏高辉, 龚盛昭. 抗菌纤维的抑菌活性及其在面膜产品中的应用研究[J]. 日用化学工业（中英文）, 2023, 53(5): 538-543.
[13]	吴雨闻, 卞筱颖, 岳岭佳, 常宽, 王靖. 头发与头皮护理的科学基础（Ⅲ）——头发的力学性能[J]. 日用化学工业（中英文）, 2023, 53(3): 260-270.
[14]	斤朕, 张春生. 耐温缓交联有机锆冻胶压裂液的制备与性能评价[J]. 日用化学工业（中英文）, 2023, 53(3): 279-284.
[15]	韩亚楠, 台秀梅, 刘英, 耿涛, 白艳云, 郭凌霄. 改性油脂乙氧基化物单独稳定的水包油高内相乳液[J]. 日用化学工业（中英文）, 2023, 53(12): 1392-1397.

改性油脂乙氧基化物与平平加二元复配体系的性能研究

Study on performance of modified oil ethoxylates and peregal blend system

RichHTML

PDF (PC)

赞

可视化

摘要/Abstract

引用本文

使用本文

图/表 10

参考文献 9

相关文章 15

Metrics

本文评价

推荐阅读 10