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日用化学工业（中英文）

日用化学工业 ›› 2015, Vol. 45 ›› Issue (4): 233-240.doi: 10.13218/j.cnki.csdc.2015.04.013

• 分析与检测 • 上一篇    

离子排斥色谱法测定化妆品中硼酸(盐)含量

李铭1, 凌小芳1, 郑洪国2, 郭桦1   

  1. 1.成都产品质量检验研究院有限责任公司,四川 成都 610100;
    2.赛默飞世尔科技有限公司,四川 成都 610011
  • 出版日期:2015-04-22 发布日期:2019-04-02
  • 通讯作者: 凌小芳,硕士,E-mail:984957545@qq.com。
  • 作者简介:李铭(1981-),男,河北衡水人,硕士,E-mail:85321941@qq.com。
       

Determination of boric acid salt in cosmetics by ion exclusion chromatography

LI Ming1, LING Xiao-fang1, ZHENG Hong-guo2, GUO Hua1   

  1. 1.Chengdu Institute of Product Quality Inspection Co.Ltd.,Chengdu,Sichuan 610100,China;
    2.Thermo Fisher Scientific Corporation,Chengdu,Sichuan 610011,China
  • Online:2015-04-22 Published:2019-04-02

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摘要： 建立了离子排斥色谱法对化妆品中硼酸及硼酸盐类进行检测。在对试样进行前处理后,采用ICS1100离子色谱仪对硼酸及其盐类进行测定,配置对硼酸根具有良好选择性的IonPac ICE-borate离子排斥色谱柱为分析柱,以甲磺酸-甘露醇为淋洗液,利用抑制电导检测器对化妆品中硼酸盐进行检测。结果表明,硼酸盐的检出限为0.57 mg/kg,定量下限为1.9 mg/kg,回收率在87%~108%之间,具有良好的回收率和重现性。

关键词: 化妆品, 硼酸盐, 离子排斥色谱

Abstract: The method of ion exclusion chromatography to detect boric acid and salt in cosmetics was established.After pretreatment of the samples,the boric acid and salt in samples was separated on ICS1100 ion chromatography system using IonPac ICE-borate ion exclusion column which has a good selectivity for borate radicals as analysis column,with methane sulfonic acid-mannitol as eluent,and suppressed conductivity detector to detect boric acid salts in cosmetics.Results showed that boric acid salt detection limit of this method is 0.57 mg/kg;the limit of quantification is 1.9 mg/kg;the recovery is in the range of 87%-108%,with good recovery and reproducibility.

Key words: cosmetics, borate, ion exclusion chromatography

中图分类号: 

  • TQ658