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Table of Content

    22 March 2025, Volume 55 Issue 3 Previous Issue    Next Issue
    Invited paper
    Preparation of highly stable O/W Pickering emulsion based on amphiphilic Janus-SiO2 particles
    Keke Zhang, Huanjin Zou, Ye Fan, Yongmin Zhang, Xuefeng Liu, Yinjun Fang
    2025, 55 (3):  271-278.  doi: 10.3969/j.issn.2097-2806.2025.03.001
    Abstract ( 106 )   HTML ( 38 )   PDF (8248KB) ( 65 )  

    Janus-SiO2 nanoparticles were prepared by Pickering emulsion templating method by using 3-(2-aminoethylamino)propyltrimethoxysilane and n-octyl trimethoxysilane. The results of FT-IR, TG, contact angle and Zeta potential confirmed the successful grafting of amino groups and octyl groups onto the surface of SiO2 nanoparticles. Considering the emulsion droplet diameter and emulsification index, the optimal emulsification conditions were obtained at a homogenization intensity of 15 000 r/min, Janus-SiO2 nanoparticle mass fraction of 1.0%, and water-to-oil volume ratio of 5∶5. The average droplet diameter of the Pickering emulsion thus obtained was approximately 56.6 μm. The Janus-SiO2 nanoparticles exhibited good emulsification performance, which could stabilize high internal phase emulsion and have low-energy emulsification and broad oil phase universality. The results of stability test demonstrated that the Pickering emulsion prepared remained stable at room temperature for more than two months and maintained stability in the temperature range of 4 to 90 ℃. The Pickering emulsion could be formed even when the aqueous phase had low or high pH or high mass concentrations of NaCl, indicative of excellent resistance to acid, base and electrolyte. In addition, the viscosity of the emulsion increased with increasing electrolyte mass concentration. The O/W Pickering emulsion stabilized with Janus-SiO2 particles exhibited remarkable stability, which had potential for applications in cleaning of oil stains under high-temperature and high-electrolyte conditions.

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    Synthesis and crosslinking properties of W-SN crosslinking agent
    Haibing Cheng, Yong Zhang, Lei Sun, Weijia Li, Zhi Chen, Congming Tang, Li Chang
    2025, 55 (3):  279-285.  doi: 10.3969/j.issn.2097-2806.2025.03.002
    Abstract ( 76 )   HTML ( 9 )   PDF (1794KB) ( 22 )  

    Fracturing is an important stimulation means for low-permeability oil reservoirs to increase their productivity. The normal operation of hydraulic fracturing largely depends on whether the fracturing fluid has excellent heat and shear resistance which in turn depends on the crosslinking agent. In this work, melamine, sodium tetraborate, and zirconium oxychloride were used as raw materials to synthesize a new W-SN crosslinking agent through “one-step method”. Under laboratory conditions, the performance of the fracturing fluid used with this crosslinking agent was evaluated. By study of the preparation process of W-SN crosslinking agent, the optimized synthesis conditions were obtained as follows: 5wt% zirconium oxychloride, 1wt% melamine, 2.5wt% sodium tetraborate, pH of 0.5, temperature of 90 ℃, and reaction time of 4 hours. The optimized conditions for gelation with partially hydrolyzed polyacrylamide (HPAM) were as follows: crosslinking time, 25 minutes; mass ratio of HPAM to W-SN, 100∶2.5. Both W-SN crosslinker and the HPAM gel show improved salt tolerance and thermal stability, satisfying the practical requirements of hydraulic fracturing operation.

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    Basic research
    Preparation and sustained release performance of multi-core capsules based on fragrance-loaded Pickering emulsions
    Xinyi Liu, Juanbo Chen, Haoyue Hou, Jiawei Hou, Meiling Shi, Sa Zeng, Tao Meng
    2025, 55 (3):  286-294.  doi: 10.3969/j.issn.2097-2806.2025.03.003
    Abstract ( 59 )   HTML ( 8 )   PDF (3752KB) ( 43 )  

    Naturally degradable capsule provides a platform for sustained fragrance release. However, practical challenges such as low encapsulation efficiency and difficulty in sustained release are still limited in using fragrance-loaded capsules. In this work, the natural materials sodium alginate and gelatine are dissolved and act as the aqueous phase, lavender is dissolved in caprylic/capric triglyceride (GTCC) as the oil phase, and SiO2 nanoparticles with neutral-wettability as a solid emulsifier to form O/W Pickering emulsions simultaneously. Finally, multi-core capsules are prepared using the drop injection method with emulsions as templates. The results show that the capsules have been successfully prepared with a spherical morphology and multi-core structure, and the encapsulation rate of multi-core capsules can reach up to 99.6%. In addition, the multi-core capsules possess desirable sustained release performance, the cumulative sustained release rate of fragrance at 25 ℃ over 49 days is only 32.5%. It is attributed to the significant protection of multi-core structure, Pickering emulsion nanoparticle membranes, and hydrogel network shell for encapsulated fragrance. This study is designed to deliver a new strategy for using sustained-release technology with fragrance in food, cosmetics, textiles, and other fields.

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    Synergistic effect of triazine-based Gemini surfactant and 2-mercaptoethanol on corrosion inhibition of carbon steel in 3.5%NaCl solution
    Penghui Liang, Mengying Yuan, Yilei Ruan, Guofang Gao, Zhiyong Hu, Hailin Zhu
    2025, 55 (3):  295-304.  doi: 10.3969/j.issn.2097-2806.2025.03.004
    Abstract ( 52 )   HTML ( 3 )   PDF (3421KB) ( 24 )  

    The triazine-based Gemini surfactant C12-2-C12 was synthesized with cyanuric chloride, dodecylamine, ethylenediamine, N,N-dimethyl-1, 3-propanediamine and ethyl bromide as raw materials. The structure of the product was characterized by Fourier transform infrared spectroscopy, 1H NMR and high-resolution mass spectrometry. The synergistic effect of C12-2-C12 and 2-mercaptoethanol (TZ) on corrosion inhibition of carbon steel in 3.5% NaCl solution at 60 ℃ was investigated by static weight loss test, electrochemical impedance spectroscopy (EIS), and potentiodynamic polarization test. The results showed that, the corrosion inhibition rate could reach 95.47% when n(C12-2-C12) ∶n(TZ) = 7∶3, and the synergistic parameter of corrosion inhibition was 1.52. The potentiodynamic polarization curves indicated that the mixed corrosion inhibitors in 3.5% NaCl solution behaved like a hybrid corrosion inhibitor. The results of scanning electron microscopy and X-ray photoelectron spectroscopy showed that the presence of TZ could complement the adsorption sites of C12-2-C12 on the surface of carbon steel and enhance the denseness of the adsorption film, thus enhancing the corrosion inhibition performance. Molecular dynamics simulations were used to specifically elucidate the corrosion inhibition mechanism, which proved that there was good synergistic corrosion inhibition effect. This work would be expected to improve the ability of corrosion inhibitors to act in harsh environments and prolong the protective period.

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    Development and application
    Study on the adaptability of CO2 composite channeling plugging system in fractured ultra-low permeability reservoirs
    Hong Yang, Kang Yang, Ying Liu, Zhenzhen Shen, Kai Liu, Fangna Liu, Zhangchao Wang
    2025, 55 (3):  305-312.  doi: 10.3969/j.issn.2097-2806.2025.03.005
    Abstract ( 59 )   HTML ( 3 )   PDF (1548KB) ( 27 )  

    The Yanchang oilfield is characterized as a fractured, ultra-low permeability reservoir with low permeability, strong heterogeneity, and a complex network of natural micro-fractures and artificial fractures. It is also influenced by high salinity of formation water, high mass concentration of Ca2+, and weakly acidic formation water during the CO2 flooding process, making conventional plugging systems unsuitable. In this work, the performance of a composite plugging system was evaluated, the injection parameters were optimized, and the slug size and combination method were also optimized. The adaptability of the system was verified through radial flow simulation of injection and production. The results showed that the foam composed of 0.2% AOS+0.2% MX-20+0.4% HPAM exhibited the best comprehensive performance, with a foam volume of 510 mL and a half-life of 3 940 seconds. The optimal gas-liquid ratio, injection rate, and injection volume were 3∶1, 0.3 mL/min, and 0.4 PV, respectively. The gel was compatible with CO2, and its strength could meet the requirements for plugging fractures. The optimal slug size and combination method for the composite channeling plugging system were 0.1 PV gel+0.4 PV foam+0.1 PV gel. The validation experiment with radial flow model demonstrated that the composite system had good adaptability in fractured low-permeability oil reservoirs.

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    Adsorption of toluene by acid-modified NaY molecular sieve at high humidity
    Sheng Li, Jie Meng, Jingwei Liu, Bingying Gao, Chao Yao
    2025, 55 (3):  313-321.  doi: 10.3969/j.issn.2097-2806.2025.03.006
    Abstract ( 59 )   HTML ( 2 )   PDF (2003KB) ( 17 )  

    To solve the problem that the adsorption performance of molecular sieve on VOCs decreased sharply under humid conditions, in this work, hydrochloric acid and citric acid were respectively used to dealuminate NaY molecular sieve to prepare high-performance water-resistant NaY molecular sieve. X-ray diffraction (XRD), N2 adsorption-desorption, scanning electron microscopy (SEM) and X-ray fluorescence spectroscopy(XRF) were used to investigate the changes in the skeleton structure, specific surface area and element content of the NaY molecular sieve before and after modification. The adsorption of toluene was tested under static water vapor and humid conditions. The results showed that the adsorption capacity for static water vapor gradually decreased after modification. When the relative humidity (RH) was 80%, the most successful modification effect was indicated by 0.5M-CA-NaY molecular sieve whose breakthrough time and saturated adsorption capacity of toluene were 6 times and 4.3 times higher than that before modification, respectively. The adsorption kinetic model showed that the adsorption process of NaY molecular sieve before and after modification was mainly monolayer adsorption. After 5 cycles of adsorption-desorption, 0.5M-CA-NaY molecular sieve showed excellent regeneration performance and still had a recycling rate of more than 95%.

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    Preparation and performance evaluation of polymers and polymer blend as high-efficiency pour point depressant for high-wax crude oil
    Jing Song
    2025, 55 (3):  322-327.  doi: 10.3969/j.issn.2097-2806.2025.03.007
    Abstract ( 54 )   HTML ( 4 )   PDF (1071KB) ( 28 )  

    High-wax crude oil often has the features of high density, high viscosity, and high pour point, which leads to high costs during exploitation, transportation, and storage. To overcome the above problems, in this work, two polymers were synthesized via free radical polymerization. The two polymers and their blends were used as viscosity reducers to improve the flowability of high-wax crude oil. The copolymer P1 was synthesized by using nonyl acrylate and vinyl acetate as monomers, while the copolymer P2 was synthesized by using dodecyl acrylate and methyl methacrylate as monomers. The effects of polymer amount on the viscosity parameters, pour point and shear stability index of high-wax crude oil were studied, in which the two copolymers and their blend P3 acted as pour point depressants. The experimental results showed that P1, P2, and P3 all had significant pour point depression and drag reduction performance, among which P3 was the best. At a dosage of 4%, P3 could reduce the pour point of the crude oil sample from 28.3 ℃ to 4.4 ℃ and the viscosity could be maximally reduced by 75.293%. The results of shear stability analysis showed that, the adverse effects of high-speed shear on freezing point and viscosity reduction were not very significant in presence of P3 (The freezing point was merely raised by 2.1 ℃ after high-speed shear and the viscosity reduction rate was merely decreased by 5.76% after high-speed shear), and the PVL and PSSI values were small at all concentrations, indicative of good shear stability. Therefore, P3 was expected as an efficient pour point depressant and drag reducing agent which could effectively reduce the viscosity of high-wax crude oil and reduce the drag during transportation, and thus reduce the energy consumption during pipeline transportation.

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    Synthesis and properties of tall oil aminoxyethyl imidazoline
    Gaofei Zhang, Wei Zhang, Bing Liu
    2025, 55 (3):  328-332.  doi: 10.3969/j.issn.2097-2806.2025.03.008
    Abstract ( 62 )   HTML ( 11 )   PDF (1157KB) ( 26 )  

    Tall oil acid is a renewable biomass material. In this work, the effects of different types of catalysts such as 3, 4, 5-trifluorophenylboronic acid, phosphoric acid, and potassium hydroxide on the conversion rate to tall oil aminoxyethyl imidazoline (TON100) were investigated, in which diethylenetriamine and tall oil acid were used as raw materials. The structure of TON100 was characterized by FT-IR and ES-MS. Its corrosion inhibition performance to A3 steel sheets in hydrochloric acid solution and sulfuric acid solution was investigated by static weight loss method. The results showed that when the reaction temperature was 230 ℃, 3,4,5-trifluorophenylboronic acid was used as a catalyst and its amount was 0.3 wt% of the total amount, the conversion rate of tall oil acid was 99.4%. In a 4 wt% hydrochloric acid solution, the best dosage of TON100 for corrosion inhibition was 25 mg/L at 30 ℃ and 60 ℃. In contrast, at the experimental temperature of 90 ℃, the best dosage of TON100 was 50 mg/L and the highest corrosion inhibition rate was obtained as 95.1%; at 30 ℃, in a 4 wt% sulfuric acid solution, when the amount of TON100 added was 100 mg/L, the corrosion inhibition rate was 85.1%. Therefore, TON100 had good corrosion inhibition effects against both hydrochloric acid and sulfuric acid.

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    Research on the forming process and antibacterial activity of the facial mask combined Scutellaria baicalensis Georgi with Salvia miltiorrhiza Bge.
    Weiqiang Song, Yali Chen, Hongyan Yang, Fan Zhang
    2025, 55 (3):  333-340.  doi: 10.3969/j.issn.2097-2806.2025.03.009
    Abstract ( 95 )   HTML ( 7 )   PDF (1434KB) ( 33 )  

    Acne is a common skin disease, and the occurrence of acne is closely related to Propionibacterium acnes. Research shows that Scutellaria baicalensis Georgi and Salvia miltiorrhiza Bge. have good antibacterial activities, especially to Propionibacterium acnes. The facial mask combined S. baicalensis Georgi with S. miltiorrhiza Bge. was prepared, and its forming process was optimized through response surface test. A rapid analysis technology for active ingredients was established using high performance liquid chromatography (HPLC), and the experiments were held to investigate the antibacterial activities of Propionibacterium acnes and Staphylococcus aureus in vitro. The results show that three main factors affecting the forming process are glycerol, 1, 3-butanediol and hydroxyethyl cellulose identified by single factor test. Box-Behnken test and response surface method are used to optimize the variation parameters of the three significant factors, and its optimal process conditions. The twelve indicative activities in the facial mask are identified by HPLC, and the rapid quality analysis method and its chromatographic conditions are established. Also, the bacteriostatic test in vitro of the facial mask confirms that it shows certain bacteriostatic effects on Propionibacterium acens and Staphylococcus aureus, and can exert effectively and continuously within ten hours. When it is combined with positive drug DP-300, it shows better synergistic or additive bacteriostatic effects, which are considered as the mild bacteriostatic effects due to facial mask.

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    Study on the influencing factors for the droplet size and stability of crude oil emulsions
    Li He, Huabin Li, Gang He, Lei Luo
    2025, 55 (3):  341-348.  doi: 10.3969/j.issn.2097-2806.2025.03.010
    Abstract ( 59 )   HTML ( 14 )   PDF (9161KB) ( 22 )  

    The properties of an emulsion are affected by several factors including emulsifier type, emulsifier concentration, water content (oil-water volume ratio) and stirring speed (shear rate). In this work, the effects of stirring speed, water content and their combined action on the droplet size and stability of the emulsion were investigated by using the water separation percent and the Sauter mean diameter of the emulsion as the evaluation indexes. The results showed that, for the YMX-1 emulsion system of a water content of 50% at 50 ℃, when the stirring speed was increased from 7 000 r/min to 15 000 r/min, the Sauter mean diameter would decrease from 18.83 μm to 14.54 μm, and the water separation percent decreased from 72.00% to 50.80%. It suggested that with the increase of stirring speed, the droplet size of emulsion decreased and the stability increased. In the case of a stirring speed at 7 000 r/min, when the water content was increased from 40% to 70%, the Sauter mean diameter would increase from 17.11 μm to 27.65 μm, and the water separation percent increased from 58.50% to 86.29%. It suggested that with the increase of water content, the droplet size of the emulsion increased and the stability decreased. The results of variance analysis and regression analysis showed that, the water content had greater influence on the droplet size and stability of the emulsion than the stirring speed did. The prediction equations of Sauter mean diameter (D) and stability score (VF) for water content (X) and stirring speed (Y) were obtained: D = 16.55+2.85X-2.94Y -1.5XY+1.35X2+1.73Y2 and VF = 9.0-3.54X+1.55Y, and the fitting degree reached 0.837 1 and 0.947 9, respectively, which could provide a theoretical basis for subsequent emulsion flooding to improve oil recovery in Y oilfield.

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    Modeling of post-sunburn skin condition assessment based on KNN algorithm
    Yihong Li, Xu Mengran, Pan Yao, Wu Jinhao, Liu Qi, Chang Sisi, Zhao Hua
    2025, 55 (3):  349-357.  doi: 10.3969/j.issn.2097-2806.2025.03.011
    Abstract ( 50 )   HTML ( 2 )   PDF (1895KB) ( 19 )  

    This study established a model for assessing post-sunburn skin condition by exploring the trends of skin indexes after different doses of UV irradiation. First, we screened out the indicators with regular and sensitive changes, optimized the tanning model to further expand the sample library, used the clinical experts’ grading of post-tanning skin status as the learning standard, and trained the identification of the indicator data based on the K Neighborhood Classification Algorithm (KNN) to establish the post-tanning skin status grading assessment model. After 10-fold cross validation, when the hyperparameter K=3, the mmce mean value of the model is 0.015, and the mean value of the prediction accuracy acc is 0.985, with a prediction accuracy of 98.5%. The results show that the model is able to objectively quantify the subjective ratings of post-tanning skin condition and recognize post-tanning skin condition with high efficiency and accuracy. The results can provide technical support for the assessment of post-sunburn skin condition and the evaluation system of post-sunburn repair efficacy.

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    Reviews
    Progress in the preparation and application of magnetic fluorescent nanoparticles
    Zihan Yang, Xin Liu, Xinru Li, Miao Li
    2025, 55 (3):  358-366.  doi: 10.3969/j.issn.2097-2806.2025.03.012
    Abstract ( 49 )   HTML ( 2 )   PDF (1617KB) ( 18 )  

    With the development of science and technology, nanoparticles with a single performance can no longer meet the needs of human beings. The research and development of multifunctional nanoparticles are of great significance to the development of society. Bifunctional magnetic fluorescent nanoparticles have been developed to combine magnetic and fluorescent properties and can be manipulated by an external magnetic field while realizing fluorescence labeling, which meets the needs of high sensitivity and multi-selectivity. Therefore, magnetic fluorescent bifunctional nanoparticles have broad application prospects in biomedicine, environmental protection, new energy, and other fields. In this paper, the encapsulation method, coupling method, pyrolysis method, and other preparation methods are introduced, and their advantages and limitations are discussed. In addition, magnetic fluorescent nanoparticles are classified into three types according to their structures. The latest research progress of magnetic fluorescent nanoparticles in nano-drug delivery, biological detection and separation, biological imaging, food safety detection, and fingerprint detection are summarized. Finally, the synthesis and application of bifunctional magnetic fluorescent nanoparticles are prospected.

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    The research progress and regulation of cosmetic ingredients produced by synthetic biology at home and abroad
    Yunping Lan, Zhijie Xie, Chujie Zhao, Xiaochun Liu, Shiqiong Wang, Qiuxing He
    2025, 55 (3):  367-380.  doi: 10.3969/j.issn.2097-2806.2025.03.013
    Abstract ( 100 )   HTML ( 13 )   PDF (1257KB) ( 34 )  

    The use of synthetic biology technology to develop cosmetic ingredients is attracting widespread attention due to its effectiveness, safety, and environmental friendliness. This article explains the concept of synthetic biology and its key technologies and current status in the production of cosmetic ingredients. It also briefly analyzes the regulatory approaches to synthetic biology-based cosmetic ingredients in different countries and regions, providing guidance for the management of this field in China. The goal is to ensure product safety, enhance consumer trust, and promote the healthy development of the industry.

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    Analysis of product packaging design from the perspective of low carbon concept: Taking daily toiletries as an example
    Niannian Zhao, Aizhen Li
    2025, 55 (3):  381-389.  doi: 10.3969/j.issn.2097-2806.2025.03.014
    Abstract ( 86 )   HTML ( 5 )   PDF (2206KB) ( 19 )  

    With the increasingly severe global environmental problems, low-carbon concepts have gradually become the core principle of social development. The packaging design of daily care products also needs to follow the trend of the times and develop towards a more environmentally friendly and low-carbon direction. This article takes daily toiletries as the research object and uses case analysis method to explore product packaging design from the perspective of low-carbon concept. Firstly, the development status of packaging design for daily care products at home and abroad is analyzed, and problems such as excessive packaging and the use of materials that are difficult to degrade are pointed out. Then, based on the theoretical foundation of the low-carbon concept and its correlation with the packaging design of daily care products, the principles of packaging design for daily care products under the low-carbon concept are summarized. Finally, a packaging design strategy for daily toiletries from the perspective of low-carbon concept is proposed, including selecting and applying environmentally friendly materials, optimizing and innovating packaging structures, and exploring green printing and decoration technologies. It aims to promote the development of the packaging design industry towards a more green and sustainable direction through the application of low-carbon concepts in product packaging design.

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    Skin microecology and microecological skincare products
    Huabing Zhao, Yingtian Li, Xihan Wang, Zhengmei Huang, Fuping Lu
    2025, 55 (3):  390-398.  doi: 10.3969/j.issn.2097-2806.2025.03.015
    Abstract ( 90 )   HTML ( 15 )   PDF (1358KB) ( 78 )  

    The skin microecosystem is comprised of the components including: the microbiome, encompassing bacteria, fungi, archaea, viruses, protozoa, and other microorganisms; host cells, including epithelial cells, immune cells, and various glands; chemical constituents, such as sebum, sweat, skin care products, environmental molecules, and their metabolic products; and the physical microenvironment, which includes factors such as oxygen, ultraviolet light, and temperature. The microbiome serves as the central component of the skin microecosystem, playing a crucial role in the maintenance of skin homeostasis through its mediation of the interactions among the physical barrier, chemical barrier, and immune barrier. Understanding the skin microecosystem, and how to maintain its delicate balance is an essential way to gain insight into the mechanisms responsible for healthy skin. The daily use of skin care products has become a modern living habit, and its impacts on skin microecosystem cannot be ignored. Therefore, this article aims to summarize the various factors that may affect the skin microecosystem in skin care products, and systematically analyze the common effects, harmful effects, beneficial effects and uncertainty effects. Based on this premise, the following development directions are proposed: further elucidation of the skin microecology mechanism with multi-omics technology, the creation of in vitro skin microecology models, the establishment of evaluation systems and regulations for assessing the effects of skincare products on skin microecology, and the exploration of beneficial skin bacteria and substitutes for potentially harmful ingredients.

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    Analytical methods and testing
    Determination of 21 nonsteroidal anti-inflammatory drugs in cosmetics by high performance liquid chromatography-tandem mass spectrometry
    Keran Feng, Xiaoming Wu, Liangbo Ma, Yu Sun
    2025, 55 (3):  399-406.  doi: 10.3969/j.issn.2097-2806.2025.03.016
    Abstract ( 52 )   HTML ( 3 )   PDF (1198KB) ( 26 )  

    A method was developed for the determination of 21 nonsteroidal anti-inflammatory drugs (NSAIDs) in cosmetics by ultra-high performance liquid chromatography-tandem mass spectrometry (UHPLC-MS/MS). Four kinds of cosmetics such as cream, facial mask, gel and toner were selected as representative matrix. The sample pretreatment conditions, chromatography and mass spectrometry conditions were systematically investigated. At first, the cosmetic samples were extracted by methanol for cream, gel, toner matrix, and methanol containing 0.3% (V/V) formic acid for facial mask matrix by ultrasonic-assisted liquid-liquid extraction. Then they were separated on an ACQUITY UPLC BEH C18 column (1.7 μm, 2.1 mm×150 mm) by gradient elution. Aqueous containing 0.1% (V/V) formic acid and acetonitrile were used as mobile phases. The flow rate was 0.3 mL/min and injection volume was 5 μL. Finally, samples were detected with multiple reaction monitoring (MRM) scanning mode. The results show a good linearity in the concentration range of 10-100 μg/L for rofecoxib and 5-50 μg/L for other NSAIDs. The spiked recoveries at the low, medium, and high levels range from 72.1% to 117.3%, with the RSD ranging from 0.6% to 9.7% (n=6). This method has the characteristics of simple operation, high accuracy, and good sensitivity. It is suitable for the detection of NSAIDs in cosmetics, and provides a technical support for the supervision in cosmetics.

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