气相色谱质谱法测定日化用品中的卡拉花醛

doi:10.3969/j.issn.1001-1803.2020.08.011

Abstract

Abstract:

A method for the determination of karanal in daily chemicals by gas chromatography mass spectrometry （GC-MS） was established. It was ultrasonically extracted by methanol as extraction solvent. After membrane filtration, the filtrate was directly determined by GC-MS, and quantitative by external standard method. The results show that the limit of quantity is 0.5 μg/g. In the range of 0.05-10 mg/L, there is a good linear relationship between the peak area and the mass concentration of karanal. The average recoveries at three spiked levels of 0.5, 5 and 10 μg/g change from 70.1% to 96.9%, and the precisions （RSD, n=6） vary from 6.0% to 6.8%. The method has the advantages of wide application, strong operability, simplicity, rapidity, accuracy and reliability, and can meet the testing requirements of karanal in daily chemical products.

Key words: daily chemicals, karanal, gas chromatography mass spectrometry

CLC Number:

TQ658

LIU Ting,TANG Hang-yan,ZHU Li-ping,GUO Fang-long,LIU Hai-shan,YAN Ying-peng. Determination of karanal in daily chemicals by GC-MS[J].China Surfactant Detergent & Cosmetics, 2020, 50(8): 572-575.

Figures/Tables 6

Fig. 1

Fig. 2

Fig. 3

Fig. 4

Tab. 1

Tab. 2

References 8

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序号	温度/℃	t/min	峰面积	w/（μg·g^-1）
1	室温（25）	10	4 523 662	5.85
2	室温（25）	10	4 930 768	6.43
3	室温（25）	20	4 416 651	5.69
4	室温（25）	20	4 651 808	6.03
5	45	10	4 645 921	6.02
6	45	10	4 529 142	5.85
7	45	20	5 033 227	6.58
8	45	20	4 555 334	5.89

序号	添加水平/（μg·g^-1）	测试结果/（μg·g^-1）	回收率/ %	相对标准偏差/ %
1	0.5	0.43	85.5	6.6
2		0.40	79.6
3		0.43	85.9
4		0.45	90.3
5		0.48	96.9
6		0.44	87.0
7	5	4.63	92.6	6.0
8		4.03	80.5
9		4.10	82.0
10		4.08	81.7
11		4.49	89.8
12		4.48	89.6
13	10	8.25	82.5	6.8
14		8.20	82.0
15		7.01	70.1
16		7.51	75.1
17		7.13	71.3
18		7.77	77.7

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Determination of karanal in daily chemicals by GC-MS

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