季铵盐型双子表面活性剂及其改性黏土的研究和应用进展

doi:10.3969/j.issn.1001-1803.2021.04.012

摘要/Abstract

摘要：

综述了季铵盐型双子表面活性剂的合成及其在改性黏土吸附水中有机污染物中的应用。从烷基季铵盐型双子表面活性剂的合成出发,重点从改变连接基结构、疏水基结构、阳离子连接点结构及反离子四个方面举例介绍了不同类型的季铵盐型双子表面活性剂的合成。同时概述了季铵盐型双子表面活性剂在改性不同种类的天然黏土中的应用。最后基于绿色化学的发展背景,阐述了未来双子表面活性剂的发展方向及其应用于治理水污染中的机遇与挑战。

关键词: 季铵盐型双子表面活性剂, 合成, 改性黏土, 有机污染物, 吸附

Abstract:

The synthesis of quaternary ammonium Gemini surfactants and their application in adsorption of organic pollutants in water by modified clay were reviewed. Starting from the synthesis of alkyl quaternary ammonium Gemini surfactants, emphasis was given on the introduction of different types of quaternary ammonium Gemini surfactants and their synthetic routes from four aspects, i.e. changing the structures of the spacer group, hydrophobic group, cationic connection point and counterion. The application of quaternary ammonium Gemini surfactants to modify different kinds of natural clay was also reviewed. Finally, based on the development background of green chemistry, the development direction of Gemini surfactants in the future and the opportunities and challenges of their application in water pollution control were discussed.

Key words: quaternary ammonium Gemini surfactant, synthesis, modified clay, organic pollutant, adsorption

中图分类号:

TQ423

富多娇,周银,陈晗宇,刘红芹,徐宝财. 季铵盐型双子表面活性剂及其改性黏土的研究和应用进展[J]. 日用化学工业, 2021, 51(4): 338-347.

FU Duo-jiao,ZHOU Yin,CHEN Han-yu,LIU Hong-qin,XU Bao-cai. Advances in research and application of quaternary ammonium Gemini surfactants and their modified clay[J]. China Surfactant Detergent & Cosmetics, 2021, 51(4): 338-347.

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