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日用化学工业(中英文) ›› 2023, Vol. 53 ›› Issue (11): 1299-1304.doi: 10.3969/j.issn.2097-2806.2023.11.009

• 开发与应用 • 上一篇    下一篇

不同制膏法对牙膏流变性的影响研究

高艳*(),陈杰文,肖蕾   

  1. 无限极(中国)有限公司,广东 江门 529100
  • 收稿日期:2022-10-15 修回日期:2023-11-02 出版日期:2023-11-22 发布日期:2023-11-21

Study on the rheological properties of toothpastes from different production processes

Gao Yan*(),Chen Jiewen,Xiao Lei   

  1. Research and Development Sector, Infinitus (China) Company Ltd, Jiangmen, Guangdong 529100, China
  • Received:2022-10-15 Revised:2023-11-02 Online:2023-11-22 Published:2023-11-21
  • Contact: *Tel.: +86-20-88750000, E-mail: 553045829@qq.com.

摘要:

研究了一步和两步制膏法制备的牙膏的流变性能。发现两种制膏法得到的牙膏的流变性相近,均属假塑性流体,具有剪切稀化特性及触变性。两步制膏法牙膏的黏度更高、屈服力大、结构偏刚性;一步制膏法牙膏更具有弹性,经高速剪切后结构恢复快。温度对一步制膏法牙膏影响大,经高温处理后其黏度会增大。经分析,两步制膏法有独立的增稠剂水合溶胀工序,一步制膏法中增稠剂水合溶胀与粉料吸附液料、发泡剂溶解乳化等工序同时进行。在两步制膏法中,增稠剂水合溶胀工序的温度和液相比例更高,其分子链舒展更开,亲水基团结合的水更多,分子链缠绕更剧烈,牙膏内聚力更大,结构刚性大。

关键词: 牙膏, 一步制膏法, 两步制膏法, 流变性

Abstract:

The rheological properties of the one-step producing toothpaste and the two-step producing toothpaste were researched by Anton Paar MCR 302 Rheometer in this paper. Results show that the two toothpastes are the pseudoplastic fluids with shear thinning behavior and the thixotropy. The two-step producing toothpaste has higher viscosity, greater yield strength and rigid structure. The one-step producing toothpaste is more elastic, and its structure recovers quickly after high-speed shearing. The temperature has more influence on the one-step producing toothpaste, and its viscosity can increase after high temperature treatment. The two-step paste production process includes the thickeners hydration and swelling procedure. In the one-step paste production process, the thickeners hydration and swelling procedure is carried out simultaneously with the abrasive adsorbing liquid material procedure, the foaming agent dissolution and emulsification procedures. Comparing with the one-step paste production process, the temperature and liquid concentration are higher during the thickener’s hydration and swelling procedure in the two-step paste production process. So, by the two-step paste production process, the molecular chain of the thickeners combines more water, unfolds more and twines more. The toothpaste has a greater cohesive force and the structure is more rigid.

Key words: toothpaste, one-step paste production process, two-step paste production process, rheological properties

中图分类号: 

  • TQ658