日用化学工业 ›› 2021, Vol. 51 ›› Issue (6): 546-553.doi: 10.3969/j.issn.1001-1803.2021.06.012
收稿日期:
2020-09-19
修回日期:
2021-05-21
出版日期:
2021-06-22
发布日期:
2021-06-22
作者简介:
王军(1961-),男,陕西人,教授,电话:(0371)63556922,E-mail: 基金资助:
WANG Jun(),ZHANG Chen-long,YANG Xu-zhao,BAI Ya-rong
Received:
2020-09-19
Revised:
2021-05-21
Online:
2021-06-22
Published:
2021-06-22
摘要:
磁性表面活性剂是一类同时具有表面活性和对磁响应双重功能的表面活性剂,允许表面活性剂的性质可以简单的由磁场的“开”和“关”来控制。本文综述了磁性表面活性剂的结构、合成、性能和应用研究进展。具有磁响应的反离子与表面活性基团可通过正负离子静电吸引或金属离子与表面活性基团形成络合物相结合,磁性表面活性剂比非磁性母体表面活性剂具有优异的表面性能,如低的表面张力和小的临界胶束浓度(cmc)。外加磁场能够进一步降低磁性表面活性剂水溶液的表面张力。磁性表面活性剂的磁矩主要由金属离子所决定,烷基三甲基铵类磁性表面活性剂的磁矩大于烷基咪唑类磁性表面活性剂的磁矩。磁性表面活性剂在药物输送、微乳液、纳米材料、杀菌等方面表现出了独特的性能,预示这类表面活性剂具有良好的发展前景。
中图分类号:
王军,张晨龙,杨许召,白亚榕. 磁性表面活性剂的研究进展[J]. 日用化学工业, 2021, 51(6): 546-553.
WANG Jun,ZHANG Chen-long,YANG Xu-zhao,BAI Ya-rong. Research progress of magnetic surfactants[J]. China Surfactant Detergent & Cosmetics, 2021, 51(6): 546-553.
表 1
磁性表面活性剂的表面活性参数"
表面活性剂 | cmc/(mmol·L-1) | γcmc/(mN·m-1) | 文献 |
---|---|---|---|
[C10TA][GdCl3Br] | 48 | / | [22] |
[C10MIM][FeCl4] | 40.6 | / | [4] |
[C12TA][FeCl3Br] | 13.6 | / | [4] |
[2C12DA][FeCl3Br] | 0.06 | / | [4] |
[ProC10][FeCl3Br] | 0.02 | 33.9 | [16] |
[C14TA][FeCl3Br] | 2.46 | 39.57 | [17] |
[C14TA][CeCl3Br] | 2.52 | 40.67 | [17] |
[C14TA][GdCl3Br] | 3.27 | 40.48 | [17] |
[C16TA][FeCl3Br] | 0.713 | 39.89 | [17] |
[C16TA][CeCl3Br] | 0.797 | 39.69 | [17] |
[C16TA][GdCl3Br] | 0.698 | 39.11 | [22] |
[C18TA][FeCl3Br] | 0.188 | 38.97 | [17] |
[C18TA][CeCl3Br] | 0.231 | 38.62 | [17] |
[C18TA][GdCl3Br] | 0.240 | 39.79 | [17] |
[14-2-14][Br]2 | 0.140 | 31.42 | [17] |
[14-2-14][FeCl3Br]2 | 0.106 | 31.14 | [17] |
[14-2-14][CeCl3Br]2 | 0.109 | 31.58 | [17] |
[14-2-14][GdCl3Br]2 | 0.146 | 30.65 | [17] |
[16-2-16][Br]2 | 0.020 9 | 38.26 | [17] |
[16-2-16][FeCl3Br]2 | 0.019 4 | 34.95 | [17] |
[16-2-16][CeCl3Br]2 | 0.014 9 | 33.77 | [17] |
[16-2-16][GdCl3Br]2 | 0.015 4 | 31.07 | [17] |
表 2
磁场对表面活性剂水溶液表面张力的影响"
表面活性剂 | 无磁场时γcmc/(mN·m-1) | 有磁场时γcmc/(mN·m-1) | 表面张力变化率/% | 文献 |
---|---|---|---|---|
[C12TA][Br] | 37.3 | 38.6 | +3.5 | [14] |
[C12TA][HoCl3Br] | 32.6 | 31.3 | -4.0 | [14] |
[C12TA][GdCl3Br] | 33.2 | 29.9 | -9.4 | [14] |
[C12TA][CeCl3Br] | 28.8 | 29.3 | +1.7 | [14] |
[C10MIM][Cl] | 39.8 | 41.0 | +3.0 | [14] |
[C10MIM][FeCl4] | 38.4 | 34.8 | -9.4 | [4] |
[C10MIM][HoCl4] | 33.1 | 29.1 | -12.1 | [14] |
[C10MIM][GdCl4] | 37.8 | 35.1 | -7.1 | [14] |
[C10MIM][CeCl4] | 39.1 | 40.3 | +3.1 | [14] |
表 3
磁性表面活性剂的磁性参数"
表面活性剂阳离子 | 表面活性剂阴离子 | χmT/(emu·K·mol-1·Oe-1) | μeff/μB | θcw/K | Tc/K | TN/K | 文献 |
---|---|---|---|---|---|---|---|
[C12TA]+ | [HoCl3Br]- | 10.15 | 9.05 | 4.09 | 5.1 | [14] | |
[C12TA]+ | [GdCl3Br]- | 6.89 | 7.45 | 0.06 | [14] | ||
[C12TA]+ | [CeCl3Br]- | 0.43 | 1.86 | -60 | 12.2 | [14] | |
[C10MIM]+ | [HoCl4]- | 8.55 | 8.41 | 2.78 | [14] | ||
[C10MIM]+ | [GdCl4]- | 6.41 | 7.19 | -0.78 | [14] | ||
[C10MIM]+ | [CeCl4]- | 0.32 | 1.61 | -72 | 12.2 | [14] | |
[C10MIM]+ | [FeCl4]- | 4.01 | -3.3 | [15] | |||
[C14PC63]+ | [FeCl4]- | 4.34 | -0.8 | [15] | |||
[C14PC63]+ | [CoCl4]2- | 2.48 | -3.7 | [15] | |||
[C14PC63]+ | [MnCl4]2- | 4.22 | -0.1 | [15] | |||
[C14PC63]+ | [Co(NCS)4]2 - | 2.06 | -0.2 | [15] | |||
[C14PC63]+ | [GdCl6]3- | 7.72 | -0.2 | [15] |
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