碳氢/碳氟混杂型表面活性剂的研究进展

doi:10.13218/j.cnki.csdc.2014.11.143

日用化学工业 ›› 2014, Vol. 44 ›› Issue (11): 638-643.doi: 10.13218/j.cnki.csdc.2014.11.143

碳氢/碳氟混杂型表面活性剂的研究进展

杨美^1,4, 郝京诚^1,3, 李洪光²

1.中国科学院兰州化学物理研究所固体润滑国家重点实验室,甘肃兰州 730000;
2.中国科学院兰州化学物理研究所清洁能源化学与材料实验室,甘肃兰州 730000;
3.山东大学胶体与界面化学教育部重点实验室,山东济南 250100;
4.中国科学院大学,北京 100049

收稿日期:2014-05-09 发布日期:2019-04-08
通讯作者: 李洪光,研究员,E-mail:hgli@licp.cas.cn。
作者简介:杨美(1984-),女,博士研究生,安徽安庆人,E-mail:yangmei@licp.cas.cn。
基金资助:
国家自然科学基金资助项目(21033005);国家重点基础研究发展计划(973计划)资助项目(2009CB930103);中科院百人计划资助项目(Y20245YBR1)

Progress in research work with respect to hydrocarbon/fluorocarbon hybrid surfactants

YANG Mei^1,4, HAO Jing-cheng^1,3, LI Hong-guang²

1.State Key Laboratory of Solid Lubrication,Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences,Lanzhou, Gansu 730000,China;
2.Laboratory of Clean Energy Chemistry and Materials,Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences,Lanzhou,Gansu 730000,China;
3.Key Laboratory of Colloid and Interface Chemistry, Ministry of Education,Shandong University,Jinan,Shandong 250100,China;
4.University of Chinese Academy of Sciences,Beijing 100049,China

Received:2014-05-09 Published:2019-04-08

摘要/Abstract

摘要： 阐述了分子中同时含有一条碳氢链和一条碳氟链的碳氢/碳氟混杂型表面活性剂的基本概念,介绍了该类表面活性剂的发展历史、研究现状及典型分子的合成方法,归纳了其流变特性、聚集行为及其在乳化、生物医药等领域的实际应用,提出应从分子结构设计入手,有针对性地研发新一代碳氢/碳氟混杂型表面活性剂。

关键词: 碳氢/碳氟混杂型表面活性剂, 流变特性, 聚集行为, 应用

Abstract: Basic conception for hydrocarbon/fluorocarbon hybrid surfactants where both a hydrocarbon chain and a fluorocarbon chain are integrated into the same surfactant molecule was introduced.Their development history,research work status and synthesis method for typical molecules were described.Their rheological characteristics,aggregation behavior and practical applications in fields of emulsification and biomedicine were summarized.It was put forward that the development of new generation of hydrocarbon/fluorocarbon hybrid surfactants should be orientatively proceeded from molecular structure design.

Key words: hydrocarbon/fluorocarbon hybrid surfactants, rheological characteristics, aggregation behavior, application

中图分类号:

TQ423

杨美, 郝京诚, 李洪光. 碳氢/碳氟混杂型表面活性剂的研究进展[J]. 日用化学工业, 2014, 44(11): 638-643.

YANG Mei, HAO Jing-cheng, LI Hong-guang. Progress in research work with respect to hydrocarbon/fluorocarbon hybrid surfactants[J]. China Surfactant Detergent & Cosmetics, 2014, 44(11): 638-643.

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碳氢/碳氟混杂型表面活性剂的研究进展

Progress in research work with respect to hydrocarbon/fluorocarbon hybrid surfactants

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