亚微米二氧化钛基功效性紫外屏蔽复合材料的制备及性能研究

doi:10.3969/j.issn.2097-2806.2024.11.007

摘要/Abstract

摘要：

首先制备了一种亚微米花状二氧化钛，依次对其进行无机和有机表面处理后制得TiO₂/Al（OH） ₃/SS复合材料（TAS），最后在TAS表面包覆一种天然防晒剂姜黄素（Cur），得到最终产物TASC复合材料。通过XRD、UV-Vis、TEM、FT-IR、水接触角等技术手段对所得样品进行表征，结果表明：Al（OH） ₃、SS、Cur均以非晶态和物理吸附的形式包覆于TiO₂表面，三者的适宜包覆量分别为8%，8%和6%；防晒指数分析表明：TASC的紫外屏蔽能力远强于市售亚微米TiO₂（CR-50），接近市售纳米TiO₂（626B）。此外，与TAS相比，TASC复合材料还具有较强的抗氧化性。

关键词: 亚微米TiO₂, 姜黄素, 紫外屏蔽, 功效

Abstract:

In this study, a sub-micron flower-like titanium dioxide was first prepared, followed by inorganic and organic surface treatment to prepare TiO₂/Al（OH） ₃/SS composite （TAS）. Finally, the surface of TAS was coated with curcumin （Cur）, a natural sunscreen, to obtain the final product-TASC composite. The samples were characterized by XRD, UV-Vis, TEM, FT-IR and water contact angle. The results show that Al（OH） ₃, SS and Cur are all coated on the TiO₂ surface in the form of amorphous state and physical adsorption, and the suitable coating amounts of the three are 8%, 8% and 6%, respectively. The UV shielding ability of TASC is much stronger than that of the commercial submicron TiO₂ （CR-50） and close to the level of the commercial nano TiO₂ （626B）. In addition, compared with TAS, TASC composite also has strong oxidation resistance.

Key words: submicron TiO₂, curcumin, ultraviolet shielding, efficacy

中图分类号:

TQ658

吴鑫, 左士祥, 余瑶瑶, 孙晓敏, 蔡悦, 姚超. 亚微米二氧化钛基功效性紫外屏蔽复合材料的制备及性能研究[J]. 日用化学工业（中英文）, 2024, 54(11): 1339-1346.

Xin Wu, Shixiang Zuo, Yaoyao Yu, Xiaomin Sun, Yue Cai, Chao Yao. Preparation and properties of submicron titanium dioxide based efficient UV shielding composites[J]. China Surfactant Detergent & Cosmetics, 2024, 54(11): 1339-1346.

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材料名称	SPF	PFA	临界波长/nm
TAS	12	6	378
TASC	14	9	386
626B	18	3	366
CR-50	3	4	383