无规共聚物P（AA-co-BA）的制备及表面活性研究

doi:10.3969/j.issn.1001-1803.2020.06.005

日用化学工业 ›› 2020, Vol. 50 ›› Issue (6): 387-391.doi: 10.3969/j.issn.1001-1803.2020.06.005

无规共聚物P（AA-co-BA）的制备及表面活性研究

杨珊,徐洋,高云龙

渭南师范学院化学与材料学院陕西省煤基低碳醇转化工程研究中心,陕西渭南 714099

收稿日期:2019-10-29 修回日期:2020-06-01 出版日期:2020-06-22 发布日期:2020-06-22
作者简介:杨珊（1981-）,女,陕西长安人,博士,教授,电话：15191316581,E-mail：yss12041981@163.com。
基金资助:
陕西省自然科学基金项目资助(2017JM2012);2018陕西省大学生创新训练项目资助(2828);渭南师范学院自然科学类研究项目资助(18ZRRC12)

Preparation and surface activity of random copolymer P（AA-co-BA）

YANG Shan,XU Yang,GAO Yun-long

Shaanxi Province Engineering Research Center of Coal Conversion Alcohol, College of Chemistry and Materials, Weinan Normal University, Weinan, Shaanxi 714099, China

Received:2019-10-29 Revised:2020-06-01 Online:2020-06-22 Published:2020-06-22

摘要/Abstract

摘要：

研究无规共聚物P（AA-co-BA）作为高分子表面活性剂的可行性。以丙烯酸（AA）和丙烯酸丁酯（BA）为单体,采用自由基溶液聚合法成功制备了5种投料比的无规共聚物P（AA-co-BA）,其热稳定性良好。研究比较了表面张力法和电导法对该聚合物临界胶束浓度（cmc）的测试,结果表明,两种方法在测试聚合物cmc时结果一致,电导法虽简便,但表面张力法更适合进行物质的表面活性研究。当单体投料比m（BA）∶m（AA）=1∶10~1∶5时,聚合物的cmc为0.6~0.9 g/L,对应的表面张力为44.8~49.5 mN/m,这表明适当投料比的无规共聚物P（AA-co-BA）可以作为高分子表面活性剂。

关键词: 高分子表面活性剂, 无规共聚物, 表面活性, 表面张力法, 电导法

Abstract:

The feasibility of random copolymer P（AA-co-BA） as polymeric surfactant was studied. Five kinds of random copolymer P（AA-co-BA） were successfully synthesized by free radical solution polymerization with acrylic acid （AA） and butyl acrylate （BA） as monomers, and the products showed good thermal stability. The critical micelle concentration （cmc） of the polymers were tested and compared by surface tension method and conductivity method. The results showed that, the cmc values obtained by the two methods were consistent; while, although the conductivity method was more simple and convenient, the surface tension method was more suitable for studying the surface activity of substances. When the monomer m（BA）∶m（AA）=1∶10~1∶5, the cmc of the polymer was 0.6~0.9 g/L, and the corresponding surface tension was 44.8~49.5 mN/m, which showed that the random copolymer P（AA-co-BA） with appropriate feed ratio could be used as polymeric surfactant.

Key words: polymeric surfactant, random copolymer, surface activity, surface tension, conductivity

中图分类号:

TQ423

杨珊,徐洋,高云龙. 无规共聚物P（AA-co-BA）的制备及表面活性研究[J]. 日用化学工业, 2020, 50(6): 387-391.

YANG Shan,XU Yang,GAO Yun-long. Preparation and surface activity of random copolymer P（AA-co-BA）[J]. China Surfactant Detergent & Cosmetics, 2020, 50(6): 387-391.

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参考文献 17

[1]	Hao Shanshan, Zhao Li, Xu Baocai. Performance and applications of surfactants (XXVII)[J]. China Surfactant Detergent & Cosmetics, 2016,46(3) : 129-135.
[2]	Fudan University. Physical chemistry experiments [M]. 3rd edition. Beijing: Higher Education Press, 2004: 140-150.
[3]	Leng Xinjian, Zhao Fangjia, Wen Lefei, et al. Preparation of novel fluorocarbon quaternary ammonium salt surfactant and its application in emulsion polymerization[J]. Paint & Coatings Industry, 2016,46(9) : 33-38.
[4]	Yan Xuehai, Zhu Hong, Zhao Wei. Application of petroleum sulfonate surfactant in preparation of coal water slurry[J]. Fine Chemicals, 2004,21(1) : 19-22.
[5]	Cramail H, Cloutet E, Radhakrishnan K. Polymeric surfactants[M]. New Jersey: John Wiley & Sons Ltd., 2011: 2181-2223.
[6]	Raffa P, Wever D A Z, Picchioni F, et al. Polymeric surfactants: synjournal, properties, and links to applications[J]. Chemical Reviews, 2015,115(16) : 8504-8563.
[7]	Gu Xinna, Chen Hui, Li Shanshan, et al. Biosurfactant production and its application in the environmental pollution control[J]. Environmental Science & Technology, 2012,35(S1) : 155-162.
[8]	Torchilin V P. Structure and design of polymeric surfactant-based drug delivery systems[J]. Journal of Controlled Release, 2001,73(2) : 137-172.
[9]	Lv Bin, Liu Huihui, Li Pengfei, et al. Research progress on reactive polymeric surfactants[J]. China Surfactant Detergent & Cosmetics, 2019,49(9) : 601-608.
[10]	Schmolka I R. A review of block polymer surfactants[J]. Journal of the American Oil Chemists’ Society, 1977,54(3) : 110-116.
[11]	Liao Xueming. Synethesis, selt-aasembly and application of carboxylate Gemini and polymeric surfactants[D]. Wuhan: Wuhan Univeristy, 2018.
[12]	Wuhan University. Analytical Chemistry (volume II) [M]. 5th edition. Beijing: Higher Education Press, 2011: 211-286.
[13]	Deng Qinying, Liu Lan, Deng Huimin. Spectral analysis course [M]. 2nd edition. Beijing: Science Press, 2007: 46-61.
[14]	Yang Shan, Feng Yun, Gong Ming, et al. Effect of polyethylene glycol on pH sensitivity of polyacrylic acid hydrogels[J]. Engineering Plastics Application, 2018,46(6) : 14-19.
[15]	Jin Riguang, Hua Youqing. Polymer physics [M]. 3th Edition. Beijing: Chemical Industry Press, 2006: 138-140.
[16]	Yang Shan, Li Yali. Experiment design on determination of the liquid surface tension by Wilhelmy method[J]. Chinese Journal of Chemical Education, 2018,39(10) : 44-48.
[17]	Huang Xuezheng, Zhang Lei. The calculation and study of the model on the solution surface tension and its concentration[J]. Computers and Applied Chemistry, 2012,29(8) : 991-994.

无规共聚物P（AA-co-BA）的制备及表面活性研究

Preparation and surface activity of random copolymer P（AA-co-BA）

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