丙烯酸树脂类水性颜料型记号墨水的制备与稳定性研究

doi:10.3969/j.issn.1001-1803.2019.03.006

日用化学工业 ›› 2019, Vol. 49 ›› Issue (3): 167-173.doi: 10.3969/j.issn.1001-1803.2019.03.006

丙烯酸树脂类水性颜料型记号墨水的制备与稳定性研究

温鲜妮^1,²,王立伟²,邓维¹,姜飞¹,郭亨长²()

^1. 上海应用技术大学化学与环境工程学院,上海 201418
^2. 上海晨光文具股份有限公司,上海 201406

收稿日期:2018-06-07 修回日期:2019-01-20 出版日期:2019-03-22 发布日期:2019-04-04
通讯作者: 郭亨长
作者简介:温鲜妮（1991-）,女,陕西人,硕士研究生,电话：15102131795,E-mail： 525844799@qq.com。
基金资助:
“十三五”国家重点研发计划项目(2016YFB0302605);上海市科委工程中心能力提升项目(17DZ2283600)

Study on preparation and stability of acrylic resin based waterborne pigment marker ink

Xian-ni WEN^1,²,Li-wei WANG²,Wei DENG¹,Fei JIANG¹,Heng-chang GUO²()

^1. School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, China
^2. Shanghai M&G Stationery Inc, Shanghai 201406, China;

Received:2018-06-07 Revised:2019-01-20 Online:2019-03-22 Published:2019-04-04
Contact: Heng-chang GUO

摘要/Abstract

摘要：

通过测试接触角和表面张力优选了表面活性剂和助溶剂,测试墨水附着性优选了附着力促进剂。配制由色浆、丙烯酸树脂、表面活性剂、附着力促进剂等助剂组成的水性墨水,用红外光谱和热重分析对树脂和树脂-附着力促进剂进行表征,测试墨水经高温和低温存放前后的黏度、微观、pH、粒径D50、表面张力等性能变化,最后测试了优选墨水的书写效果。结果表明,表面活性剂OP-10在该墨水体系中降低表面张力的效果最明显,乙醇润湿性最好;附着力促进剂的效果与其分子结构和添加量有关,过量的附着力促进剂易导致墨水稳定性下降,主要体现在微观、黏度、粒径的变化;优选墨水书写效果良好。

关键词: 表面活性剂, 水性记号墨水, 树脂, 附着力促进剂, 稳定性

Abstract:

Surfactants and co-solvents were optimized by testing contact angle and surface tension, and adhesion promoters were selected by testing ink adhesion. The aqueous ink composed of additives such as pigment paste, acrylic resin, surfactant, and adhesion promoter. The resin and the resin-adhesion promoter were characterized by Fourier transform infrared spectroscopy （FTIR） and thermogravimetric analysis （TG）. The changes of viscosity, microscopic property, pH, particle size of D50, surface tension and other properties of the ink before and after storage at high and low temperatures were tested. Finally, the writing effect of the optimized ink was tested. The results show that the surfactant OP-10 has the most obvious effect on reducing the surface tension in the ink system, and ethanol has the best wettability. The effect of the adhesion promoter is related to its molecular structure and addition amount. However, excessive adhesion promoters could easily lead to the decline of ink stability, which is mainly manifested in the changes of microscopic property, viscosity and particle size. Here we develop a waterborne marker ink which is stable and has excellent adhesion and good writing effect after optimizing the formula.

Key words: surfactant, waterborne marker ink, acrylic resin, adhesion promoter, stability

中图分类号:

TQ423

温鲜妮,王立伟,邓维,姜飞,郭亨长. 丙烯酸树脂类水性颜料型记号墨水的制备与稳定性研究[J]. 日用化学工业, 2019, 49(3): 167-173.

Xian-ni WEN,Li-wei WANG,Wei DENG,Fei JIANG,Heng-chang GUO. Study on preparation and stability of acrylic resin based waterborne pigment marker ink[J]. China Surfactant Detergent & Cosmetics, 2019, 49(3): 167-173.

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附着力促进剂	附着性强度
附着力促进剂	0.1%	0.3%	0.5%	0.7%
A	4	4	4	3
B	4	3	3	3
C	3	2	1	1
D	2	1	1	1

丙烯酸树脂类水性颜料型记号墨水的制备与稳定性研究

Study on preparation and stability of acrylic resin based waterborne pigment marker ink

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	原料
	色浆	树脂	保湿剂	杀菌剂	消泡剂	表面活性剂	去离子水
w/%	20	20	0.3	0.1	0.1	0.2	59.3

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