Gemini表面活性剂与疏水缔合水溶性聚合物的相互作用研究进展

doi:10.13218/j.cnki.csdc.2016.10.010

摘要/Abstract

摘要： 简述了Gemini表面活性剂的分类和特性,疏水缔合水溶性聚合物的结构、合成方法和特性;重点综述了Gemini表面活性剂和疏水缔合水溶性聚合物相互作用的研究进展,包括复配体系的表面活性、油/水界面性能、界面膜流变性能、流变性能、微观聚集体和相互作用的热力学等;同时对复配体系在一些领域的应用和研究趋势进行了展望。

关键词: Gemini表面活性剂, 疏水缔合水溶性聚合物, 相互作用, 流变性能, 热力学

Abstract: Classification and features of Gemini surfactants,as well as the structure,synthesis and characteristics of hydrophobic associated water soluble polymer (HAWSP) were briefed.Progress in research work field with respect to interaction between Gemini surfactants and HAWSP were reviewed emphatically,including the surface activity,oil-water interface performance,rheological performance of interfacial layer,rheological performance,micro aggregates and their thermodynamics,etc.of the blend systems.Moreover,the applications of such blends in some fields and the trend of research work were prospected.

Key words: Gemini surfactants, HAWSP, interaction, rheological performance, thermodynamics

中图分类号:

TQ423

梅平,郑慧玲,陈武,杨宇雷,程立,张鹏. Gemini表面活性剂与疏水缔合水溶性聚合物的相互作用研究进展[J]. 日用化学工业, 2016, 46(10): 596-604.

MEI Ping,ZHENG Hui-ling,CHEN Wu,YANG Yu-lei,CHENG Li,ZHANG Peng. Progress in research work field with respect to interaction between Gemini surfactants and hydrophobic associated water soluble polymers[J]. China Surfactant Detergent & Cosmetics, 2016, 46(10): 596-604.

参考文献

[1] 李海普,陆文霞,秦春阳,等.分子与表面活性剂在水相中的相互作用[J] .高分子通报,2013(3):18-23.
[2] 苑再武,苑敬,吕鑫,等.多糖类大分子与表面活性剂相互作用的研究进展[J] .物理化学学报,2013,29(3):449-459.
[3] 高南,李国荣,陈旭东.双子表面活性剂的合成及应用研究进展[J] .日用化学工业,2014,44(11):644-651.
[4] ZANA R.Dimeric and oligomeric surfactants.Behavior at interfaces and in aqueous solution:a review [J] .Adv Colloid Interface Sci,2002,97:205-253.
[5] ZANA R,XIA J.Gemini surfactants [M] .New York:Maree1 Deker,2003:3-7,125-126,186-187.
[6] 陈晓阁.Gemini表面活性剂的合成和理化性质的研究[D] .贵州:贵州大学,2010.
[7] 张青山,郭炳南,张辉淼,等.Gemini表面活性剂研究进展和应用[J] .化学进展,2004,16(3):343-347.
[8] 曹云丽,徐伏,王莉,等.双子表面活性剂的应用研究进展[J] .日用化学工业,2011,41(1):46-49.
[9] KIRBY A J,CAMILLERI P,ENGBERTS J,et al.Gemini surfactants:New synthetic vectors for gene transfection [J] .Angewandte Chemic(International Edition),2003,42(13):1448-1457.
[10] YAMAMOTO H,TOMATSU I,HASHIDZUME A,et al.Associative properties in water of copolymers of sodium 2-(acrylamido)-2-methylpropane and methacrylamides substituted with alkyl groups of varying lengths [J] .Macromolecules,2000,33(21):7852-7861.
[11] 樊明红.表面活性剂与聚合物相互作用的研究[D] .哈尔滨:哈尔滨工程大学,2004.
[12] 姜峰,蒲万芬,杜代军,等.双尾型丙烯酰胺类疏水缔合共聚物的合成与表征[J] .化工学报,2015,66(3):1215-1220.
[13] 韩婷婷.疏水改性聚丙烯酸胺(HMPAM)与嵌段聚醚的复合作用[D] .济南:山东大学,2011.
[14] DEGUCHI S,LINDMAN B.Novel approach for the synthesis of hydrophobe modified polyacrylamide.Direct N-alkylation of polyacrylamide in dimethyl sulfoxide [J] .Polymer,1999,40(25):7163-7165.
[15] 苑敬.咪唑类表面活性剂与疏水改性聚丙烯酰胺的相互作用[D] .济南:山东大学,2014.
[16] 何珩.疏水缔合水溶性聚合物与表面活性剂的相互作用[D] .成都:西南石油学院,2002.
[17] 袁瑞.新型化学驱油剂的分子行为与性能研究[D] .济南:山东大学,2013.
[18] MESZAROS R,VARGA I,GILANYI T.Effect of polymer molecular weight on the polymer/surfactant interaction [J] .The Journal of Physical Chemistry B,2005,109(28):13538-13544.
[19] 牛菲,秦旺盛,高志农.含阴离子Gemini表面活性剂复配体系的性能研究[J] .武汉大学学报(理学版),2013,59(6):589-593.
[20] 冯先华,董爱娥.表面活性剂与聚合物的相互作用[J] .日用化学工业,2002,32(3):43-45.
[21] 敬加强,孙娜娜,安云朋,等.两性表面活性剂与阴离子聚丙烯酰胺复配体系的抗盐性[J] .高分子学报,2014(1):88-96.
[22] 柳建新,郭拥军,孙怀宇,等.双子表面活性剂/疏水缔合水溶性聚合物复配体系的研究及三次采油中的应用潜力[J] .精细石油化工进展,2009,10(6):11-15.
[23] LI X,WETTING S D,VERRALL R E.Isothermal titration calorimetry and dynamic light scattering studies of interactions between Gemini surfactants of different structure and pluronic block copolymers [J] .Journal of Colloid and Interface Science,2005,282(2):466-477.
[24] 董宏伟,孙玉海,陈志,等.疏水缔合聚丙烯酰胺与阳离子双子表面活性剂的相互作用[J] .合成化学,2007,15(2):165-168.
[25] 郭拥军.水溶性聚合物/表面活性剂相互作用研究:从溶液到固/液界面[D] .成都:西南石油学院,1999.
[26] 王新平,唐季安,江龙,等.聚丙烯酰胺和表面活性剂相互作用的研究[J] .科学通报,1997,42(7):30-31.
[27] 蔡琨,方云,吴云兰.聚合物/表面活性剂溶液相互作用的研究进展[J] .日用化学工业,2001,31(4):26-31.
[28] 尉云平.疏水改性羟乙基纤维素与表面活性剂的相互作用及其共同稳定的乳状液[D] .济南:山东大学,2009.
[29] 赵丹.表面活性剂/疏水缔合聚合物二元体系流变性研究[D] .成都:西南石油大学,2010.
[30] 吴小梅,梅平,赖璐,等.含Gemini成分的正/负离子表面活性剂复配体系性质研究进展[J] .精细石油化工进展,2014,15(2):8-16.
[31] KASTUER U,ZANA R.Interactions between quatemary ammomum surfactant oligomers and water-soluble modified guars [J] .Journal of Colloid and Interface Science,1999,218(2):468-479.
[32] WANG X Y,LI Y J,WANG J B,et al.Interactions of cationic Gemini surfactants with hydrophobically modified polyacrylamides studied by fluorescence and microcalorimetry [J] .Journal of Physical Chemistry B,2005,109:12850-12855.
[33] 王瑞娟,王毅琳.阴离子磺酸盐型Gemini表面活性剂与PEO-PPO-PEO嵌段共聚物相互作用的研究[J] .化学学报,2014,72(1):41-50.
[34] 董国君,樊明红,陈雨.表面活性剂与聚合物相互作用的研究[J] .化学工程师,2004(3):64-65.
[35] 韩利娟,叶仲斌,陈洪,等.疏水缔合聚丙烯酰胺与双子表面活性剂的自组装[J] .物理化学学报,2012,28(6):1405-1410.
[36] 张憬瑛.两亲高分子与阳离子表面活性剂的相互作用研究[D] .哈尔滨:哈尔滨工程大学,2008.
[37] 吕文杰,胡耀峰,詹必才,等.表面活性剂对污泥脱水性能影响的机理研究:Gemini表面活性剂与聚电解质相互作用的分子动力学模拟[J] .物理化学学报,2014,30(5):811-820.
[38] BAI GUANGYUE,WANG YUJIE,YAN HAIKE,et al.Thermodyna-mics of interaction between cationic gemini surfactants and hydrophobically modified polymers in aqueous solutions [J] .The Journal of Physical Chemistry B,2002,106:2153-2159.
[39] MUZZALUPO R,INFANTE M R,PEREZ L,et al.Interactions between Gemini surfactants and polymers:Thermodynamic studies[J] .Langmuir,2007,23(11):5963-5970.
[40] 陈明贵,叶仲斌.磺酸盐阴离子双子表面活性剂与疏水缔合聚合物的相互作用[J] .油气地质与采收率,2009,16(5):60-62.
[41] 陈明贵,姚启庆,叶仲斌,等.双子表面活性剂囊泡与疏水缔合聚合物溶液间协同效应实验研究[J] .中国海上油气,2009,21(4):246-248.
[42] 毕春霞.HAWSP/表面活性剂分子结构对界面张力的影响[D] .成都:西南石油大学,2010.
[43] 冯玉军,孙玉海,陈志等.双子表面活性剂结构对性能的影响[J] .日用化学工业,2007,37(2):107-111.
[44] 马晓晶.表面活性剂与聚合物之间的相互作用及其对中相微乳液影响的研究[D] .哈尔滨:哈尔滨工程大学,2004.
[45] BABAK V G,LUKINA I G,VIKHOREVA G A,et al.Interfacial pro-perties of dynamic association between chitin derivatives and surfactants [J] .Colloids Surf A:Physicochem Eng Asp,1999,147(1):139.
[46] 尉云平,孙文彬.HMHEC/Gemini混合水溶液的性质及其稳定的乳状液[J] .广州化工,2011,39(12):70-72.
[47] QIAO Y,XIN X,WANG L,et al.Modification of the stability of oil-in-water nano-emulsions by polymers with different structures [J] .Colloid and Polymer Science,2014,292(6):1297-1306.
[48] 张红星.不同类型表面活性剂和聚合物对O/W乳状液稳定性的调控作用[D] .济南:山东大学,2008.
[49] LIU J X,GUO Y J,HU J,et al.Displacement characters of combination flooding systems consisting of Gemini-nonionic mixed surfactant and hydrophobically associating polyacrylamide for Bohai offshoreoilfield [J] .Energy & Fuels,2012,26(5):2858-2864.
[50] 陈洪,李二晓,叶仲斌,等.疏水缔合聚丙烯酰胺与双子表面活性剂的相互作用[J] .物理化学学报,2011,27(3):671-676.
[51] 曹绪龙,张磊,程建波.Gemini表面活性剂对疏水缔合聚丙烯酰胺界面吸附膜扩张流变性质的影响[J] .高等学校化学学报,2010,31(5):998-1002.
[52] 张磊.驱油表面活性剂分子结构与界面扩张流变性能关系研究[D] .北京:中国科学院研究生院(理化技术研究所),2008.
[53] 徐鹏.疏水缔合水溶性聚合物溶液微观结构研究及表面活性剂对其流变性的影响[D] .成都:西南石油学院,2001.
[54] BIGGS S,SELB J,CANDAU F.Effect of surfactant on the solution properties of hydrophobically modified polyacrylamide [J] .Langmuir,1992,8(3):838-847.
[55] 黄光稳.疏水缔合型聚丙烯酰胺与Gemini活性剂的合成及复配研究[D] .长沙:湖南大学,2013.
[56] 江立鼎,高保娇,李刚.新一族疏水缔合聚丙烯酰胺NaAMC₁₄S/AM与Gemini表面活性剂之间的相互作用[J] .物理化学学报,2007,23(3):337-342.
[57] ZHOU T,AO M Q,XU G Y,et al.Interactions of bovine serum albumin with cationic imidazolium and quaternary ammonium Gemini surfactants:Effects of surfactant architecture [J] .Journal of Colloid and Interface Science,2013,389(1):175-181.
[58] XIN X,WANG L,SHEN J L,et al.Rheological properties of hydrolyzed polyacrylamide/sodium oleate mixed system in the presence of different inorganic salts[J] .Journal of Petroleum Science and Engineering,2014,114:15-21.
[59] GONG H J,XU L,XU G Y,et al.Effect of PEO-PPO-ph-PPO-PEO and PPO-PEO-ph-PEO-PPO on the rheological and EOR properties of polymer solutions [J] .Industrial & Engineering Chemistry Research,2014,53(12):4544-4553.
[60] GUO Y J,LIU J X,ZHANG X M,et al.Solution property investigation of combination flooding systems consisting of Gemini-non-ionic mixed surfactant and hydrophobically associating polyacrylamide for enhanced oil recovery [J] .Energy & Fuels,2012,26(4):2116-2123.
[61] XU Y,FENG J,SHANG Y Z,et al.Molecular dynamics simulation for the effect of chain length of spacer and tail of cationic Gemini surfactant on the complex with anionic polyelectrolyte [J] .Chin J Chem Eng,2007,15(4):560-565.