超两亲分子的研究进展

doi:10.3969/j.issn.1001-1803.2019.08.010

摘要/Abstract

摘要：

超两亲分子是近几年研究发现的新型两亲分子,具有可控性、高效性等优点。超两亲分子中含有两种双亲分子,通过非共价键或动态共价键连接。其中非共价键包括主客体相互作用、静电相互作用、π-π堆积相互作用和电荷转移相互作用等。根据超两亲分子的响应性也可分为pH响应性、光响应性、氧化还原响应性、酶响应性和多重响应性超两亲分子。超两亲分子是胶体化学和超分子化学联系的新纽带,对新型自组装功能材料的发展具有重要的研究意义。

关键词: 超两亲分子, 主客体相互作用, 响应性, 功能超分子材料

Abstract:

Supra-amphiphiles have been discovered for several years as a new type of amphiphiles,which have the advantages of controllability,high efficiency and so on. Supra-amphiphiles consist of two amphiphile molecules linked by non-covalent bonds or dynamic covalent bonds. The non-covalent bonds include host-guest interaction,electrostatic interaction,π-π stacking interaction and charge transfer interaction. According to the different responsive characteristics,the pH response,photoresponse,redox response,enzyme response and multiple response were also introduced. Supra-amphiphile is a new bond between colloid chemistry and supramolecular chemistry. It is very important for the development of novel self-assembly functional materials.

Key words: supra-amphiphile, host-guest interaction, responsive, functional supramolecular material

中图分类号:

TQ423

李双阳,叶宏. 超两亲分子的研究进展[J]. 日用化学工业, 2019, 49(8): 545-550.

LI Shuang-yang,YE Hong. Progress on the research of supra-amphiphiles[J]. China Surfactant Detergent & Cosmetics, 2019, 49(8): 545-550.

图/表 3

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