一种含酯基的酰胺型阳离子双子表面活性剂的合成及性能

doi:10.3969/j.issn.1001-1803.2021.07.003

Abstract

Abstract:

An amide cationic Gemini surfactant with ester groups （C₁₂- （BAE） -C₁₂） was synthesized in three steps with bromoacetic acid, ethylene glycol, lauric acid and N, N-dimethyl-1, 3-diaminopropane as raw materials. The structure of the product was characterized by FT-IR, ¹H NMR and mass spectrometry （MS）. The critical micelle concentration （cmc） of C₁₂- （BAE） -C₁₂ was determined by measurement of surface tension, conductivity and fluorescence. The thermodynamic parameters of C₁₂- （BAE） -C₁₂ were obtained from the results of conductivity at 25, 35 and 45 ℃. The emulsification and antistatic properties of C₁₂- （BAE） -C₁₂ were also measured. The results show that the cmc values of C₁₂- （BAE） -C₁₂ at 25 ℃ are 0.331 1, 0.532 8 and 0.316 2 mmol/L, respectively, as obtained by different methods. According to the results of conductivity, the thermodynamic parameters of micellization were calculated with the thermodynamic formulas. It is determined that the micellization process of C₁₂- （BAE） -C₁₂ is entropy-driven, and the increase of temperature will hinder the micellization of the surfactant. Furthermore, the results of application performance show that C₁₂- （BAE） -C₁₂ has better emulsification and antistatic effects than traditional single-chain cationic surfactant dodecyltrimethylammonium bromide （DTAB）.

Key words: Gemini surfactant, ester quaternary ammonium salt, micellization, emulsifying property, antistatic property

CLC Number:

TQ423

Lu Xiaohao,Xu Hujun,Lin Liangliang,Chang Kuan,Gao Haiyan. Synthesis and properties of an amide cationic Gemini surfactant with ester groups[J].China Surfactant Detergent & Cosmetics, 2021, 51(7): 598-605.

Figures/Tables 9

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References 20

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T/K	cmc/ （mmol·L^-1）	β	ΔG⁰_m/ （kJ·mol^-1）	ΔH⁰_m/ （kJ·mol^-1）	-TΔS⁰_m/ （kJ·mol^-1）
298.15	0.533	0.481	-36.66	-7.98	-28.68
308.15	0.562	0.369	-33.32	-7.55	-25.77
318.15	0.595	0.407	-35.64	-8.40	-27.24

Synthesis and properties of an amide cationic Gemini surfactant with ester groups

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