联结基团对甜菜碱型双子表面活性剂清洁压裂液性能的影响

doi:10.3969/j.issn.2097-2806.2023.12.006

Abstract

Abstract:

Gemini betaine surfactants have the advantages of low pollution and low damage, which can be used in clean fracturing fluids for oilfield development. In this work, three Gemini betaine surfactants GAS-22-n （n=IPDI, HDI and TDI） with different spacers were synthesized by using erucic acid, N, N-dimethyl-1, 3-propanediamine and sodium 3-chloro-2-hydroxypropanesulfonate as raw materials, and hexamethylene diisocyanate, toluene diisocyanate and isophorone diisocyanate as spacers. The effects of spacers on the properties were studied. The experimental results showed that, the long carbon chain of the spacer in GAS-22-HDI structure was flexible and easy to bend, exhibiting strong intermolecular interactions and being less influenced by external forces, which made it easier to form micelles and have good salt resistance, low surface tension and low cmc. The rigid benzene ring in GAS-22-TDI structure had a larger volume, and the micelles fused to form wormlike aggregates, further forming a dense three-dimensional network structure, endowing it with good temperature resistance, shear resistance, sand suspension, and viscosity.

Key words: Gemini surfactant, betaine, spacer, clean fracturing fluid

CLC Number:

TQ423

Yongkang Zhang, Mengmeng Liu, Zhiwei Wan, Yaocong Wang, Mimi Tian, Liewei Qiu. Effect of spacer on the performance of Gemini betaine surfactant in clean fracturing fluid[J].China Surfactant Detergent & Cosmetics, 2023, 53(12): 1398-1404.

Figures/Tables 8

Fig. 1

Fig. 2

Fig. 3

Fig. 4

Fig. 5

Fig. 6

Fig. 7

Tab. 1

References 14

[1]	Wang C, Wan X. Research on performance evaluation of a clean fracturing fluid[J]. Liaoning Chemical Industry, 2021, 50 (12) : 1878-1880, 1918.
[2]	Li X. Research progress in clean fracturing fluids[J]. Energy and Chemical Engineering, 2018, 39 (2) : 55-59.
[3]	Zhang Y, Liu X, Li C, et al. Progress in the synthesis and research of Gemini surfactants[J]. Industrial Catalysis, 2020, 28 (5) : 1-7.
[4]	Fan Y, Han Y, Wang Y. Effect of molecular structure of Gemini surfactant on its aggregation behavior in aqueous solution[J]. Journal of Physical Chemistry, 2016, 32 (1) : 214-226.
[5]	Guo H, Zhuang Y, Chu Y, et al. Research progress on Gemini surfactant based clean fracturing fluids[J]. Chemical Progress, 2018, 37 (8) : 3155-3163.
[6]	Li C, Li N, Zhang J, et al. Research progress on highly active amphoteric Gemini surfactants[J]. Applied Chemistry, 2019, 48 (9) : 2235-2241.
[7]	Liao H, Tang S, Lei X, et al. Research progress on the influence of linking groups on the properties of Gemini surfactants[J]. Fine and Specialty Chemicals, 2013, 21 (8) : 39-42.
[8]	Zhao X, Ni J, Wang Y, et al. The effect of binding Groups on the interfacial tension and foaming performance of sulfonated Gemini surfactants[J]. Journal of Petroleum Processing, 2011, 27 (2) : 218-223.
[9]	Lai X, Liu P, Tian W, et al. The influence of linkers on the surface activity of betaine Gemini surfactants and the performance of foam[J]. China Surfactant Detergent & Cosmetics, 2018, 48 (10): 558-563.
[10]	Zhang W, Li P, Hou L. Preparation of Gemini surfactants containing rigid groups and their properties in combination with SDS[J]. China Surfactant Detergent & Cosmetics, 2019, 49 (5) : 298-303.
[11]	Wang L, Liu P, Lai X, et al. Effect of spacer on surface activity and foam properties of betaine Gemini surfactants[J]. Tenside Surfactants Detergents, 2019, 56 (3) : 558-563.
[12]	Liao H, Tang S, Lei X, et al. Research progress on the influence of linking groups on the properties of Gemini surfactants[J]. Fine and Specialty Chemicals, 2013, 21 (8) : 39-42.
[13]	Xue C. Study on the effect of binding groups on the behavior of amphoteric Gemini surfactant solutions[D]. Daqing: Northeast Petroleum University, 2017.
[14]	Tian M. The structural properties and application in oil displacement of Gemini betaine based surfactants[D]. Xi’an: Shaanxi University of Science and Technology, 2021.

岩芯序号	规格		渗透率/ （×10^-3μm²）		伤害率/ %
岩芯序号	岩芯长度/cm	岩芯直径/cm	伤害前	伤害后	伤害率/ %
GAS-22-IPDI	5.51	2.50	6.42	5.90	8.10
GAS-22-IPDI	5.48	2.52	6.38	5.82	8.78
GAS-22-HDI	5.55	2.48	6.03	5.61	6.97
GAS-22-HDI	5.50	2.52	6.05	5.63	6.94
GAS-22-TDI	5.54	2.52	4.58	4.25	7.21
GAS-22-TDI	5.50	2.53	4.63	4.28	7.56

[1]	Zhisheng Zhang, Chanliang Shen, Jianxun Li, Yanqiang Liu, Weiwei Han, Sanbao Dong. Preparation and performance of betaine/AOS/Gemini ternary surfactant foam for gas well deliquification [J]. China Surfactant Detergent & Cosmetics, 2024, 54(3): 239-249.
[2]	Xiaojie Zhang, Mingzhe Zhang, Zhicheng Xu, Qingtao Gong, Lei Zhang, Lu Zhang. Study on oil displacement mechanism of alkyl carboxyl betaine [J]. China Surfactant Detergent & Cosmetics, 2024, 54(2): 123-130.
[3]	Haokang Ai, Yajie Jiang, Yakui Wang, Lu Zhang, Tao Geng. Synthesis and properties of Gemini quaternary ammonium surfactant based on stearate [J]. China Surfactant Detergent & Cosmetics, 2024, 54(1): 16-23.
[4]	Chang Shiteng, Cai Xiaojun, Zheng Yancheng, Liu Xuejin, Yi Xiao, Jiang Zhuyang. Physicochemical properties of ethoxylated sulfosuccinate surfactants and their interfacial properties when mixed with a betaine surfactant [J]. China Surfactant Detergent & Cosmetics, 2023, 53(9): 989-998.
[5]	Ting Pan, Junhui Wu, Xiaomei Pei, Zhenggang Cui. Temperature and pH responsive behavior of wormlike micelles formed by novel pseudo-gemini surfactant [J]. China Surfactant Detergent & Cosmetics, 2023, 53(12): 1361-1368.
[6]	Zhao Shufen,Zheng Danmiao,Liu Huaxi,Song Songlin,Chen Zhan,Yang Ningyuan,Wei Xingchuan. Progress in synthesis and application of rosin based gemini surfactants [J]. China Surfactant Detergent & Cosmetics, 2022, 52(8): 892-903.
[7]	Lu Xiaohao,Xu Hujun,Lin Liangliang,Chang Kuan,Gao Haiyan. Synthesis and properties of an amide cationic Gemini surfactant with ester groups [J]. China Surfactant Detergent & Cosmetics, 2021, 51(7): 598-605.
[8]	Li Yongbin,Wang Wendong,Chen Jian,Shen Jiaxun,Liu Yi,Sun Shuangqing. Molecular simulation study on the micellization behavior of betaine-type zwitterionic surfactants [J]. China Surfactant Detergent & Cosmetics, 2021, 51(7): 583-589.
[9]	FU Duo-jiao,ZHOU Yin,CHEN Han-yu,LIU Hong-qin,XU Bao-cai. Advances in research and application of quaternary ammonium Gemini surfactants and their modified clay [J]. China Surfactant Detergent & Cosmetics, 2021, 51(4): 338-347.
[10]	LIU Jia-jia,XU Hu-jun. Study on the synthesis and properties of fatty amido propyl phosphobetaine [J]. China Surfactant Detergent & Cosmetics, 2020, 50(7): 446-451.
[11]	Ze-yu YANG,Wan-xu WANG,Guo-yong WANG,Xiu-mei TAI. Preparation of modified montmorillonite by BS-12 and application in Pickering emulsion [J]. China Surfactant Detergent & Cosmetics, 2020, 50(3): 177-181.
[12]	Yong-chen CAI,Hua-sheng ZHENG,Hu-jun XU. Synthesis and properties of an amide Gemini surfactant [J]. China Surfactant Detergent & Cosmetics, 2020, 50(3): 143-148.
[13]	CUI Xiu,FANG Bo,XU Hai-tao. Rheological properties of a novel clean fracturing fluid: the micellar system of 25-HP-21/NaSal [J]. China Surfactant Detergent & Cosmetics, 2020, 50(10): 653-659.
[14]	KANG Wan-li,LI Xin-xin,ZHAO Yi-lu,WANG Peng-xiang,HOU Xiao-yu,YANG Hong-bin. Construction of N-erucamido-N, N-dimethylamine and benzoic acid fracturing fluid system [J]. China Surfactant Detergent & Cosmetics, 2019, 49(9): 555-560.
[15]	CAI Kun-liang,CHENG Rong,GAN Chang-sheng. Synthesis and properties of sugar-based cationic gemini surfactants [J]. China Surfactant Detergent & Cosmetics, 2019, 49(6): 351-357.

Effect of spacer on the performance of Gemini betaine surfactant in clean fracturing fluid

RichHTML

PDF (PC)

Like

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 8

References 14

Related Articles 15

Metrics

Comments

Recommended 10