脂肪酰胺丙基磷酸酯甜菜碱的合成和性能研究

doi:10.3969/j.issn.1001-1803.2020.07.003

Abstract

Abstract:

Three fatty amide propyl phosphobetaines （abbreviated as C_n-APA, where n=12, 14 or 16） were synthesized with three fatty acid amidopropyl tertiary amines and sodium 2-hydroxy-3-chloropropyl phosphate by different experimental methods. The results show that the yield of the pressurized reaction is as high as 95%. Compared with the atmospheric pressure reaction, the pressurized reaction can greatly shorten the reaction time and increase the reaction yield. The structure of the products was characterized by infrared spectroscopy and mass spectroscopy. The surface activity, detergency performance, foam properties, emulsifying properties and antistatic performance of the three products were investigated. The results show that the cmc of C₁₂-APA, C₁₄-APA and C₁₆-APA are 5.1×10^-4, 3.4×10^-4 and 8.2×10^-5 mol/L, respectively, and all products possess good foam stability, good emulsifying properties, good detergency to sebum, and excellent antistatic properties.

Key words: phosphobetaine, surface activity, detergency performance, foam property, emulsifying property, antistatic performance

CLC Number:

TQ423

LIU Jia-jia,XU Hu-jun. Study on the synthesis and properties of fatty amido propyl phosphobetaine[J].China Surfactant Detergent & Cosmetics, 2020, 50(7): 446-451.

Figures/Tables 11

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References 21

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产物	cmc/（mol·L^-1）	γ_cmc/（mN·m^-1）	pc₂₀	cmc/c₂₀	10¹⁰Γ_max/（mol·cm^-2）	A_min/nm²
C₁₂-APA	5.1×10^-4	40.4	3.80	3.20	4.06	0.41
C₁₄-APA	3.4×10^-4	37.3	4.02	3.62	4.45	0.37
C₁₆-APA	8.2×10^-5	41.4	4.40	2.03	5.80	0.29

产物	碳黑污布去污值	蛋白污布去污值	皮脂污布去污值
C₁₂-APA	0.18	0.18	7.72
C₁₄-APA	0.92	0.93	10.34
C₁₆-APA	1.67	1.64	9.42

产物	泡沫高度/mm		稳泡率/%
产物	0 min	5 min	稳泡率/%
C₁₂-APA	155	152	98.1
C₁₄-APA	179	177	98.9
C₁₆-APA	166	165	99.4

产物	乳化分水时间/s
C₁₂-APA	354
C₁₄-APA	327
C₁₆-APA	291

等级	静电半衰期/s
A	≤2.0
B	≤5.0
C	≤15.0

Study on the synthesis and properties of fatty amido propyl phosphobetaine

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