新型清洁压裂液25-HP-21/NaSal胶束体系流变性研究

doi:10.3969/j.issn.1001-1803.2020.10.001

Abstract

Abstract:

Erucamidopropyl dimethylamine, oleamidopropyl dimethylamine and epichlorohydrin were used as the main raw materials to synthesize a novel asymmetric cationic Gemini surfactant, i.e. hydroxypropylene（erucamido-oleamido propyl dimethyl ammonium） chloride acetate （25-HP-21）. Then 25-HP-21 was mixed with sodium salicylate （NaSal） to obtain a viscoelastic micellar system. The rheological properties, microrheological properties, temperature-resistance and sand-carrying properties of the micellar system were studied. The effects of NaSal on the aggregate morphology of 25-HP-21 micelles was characterized by¹H NMR. The results showed that, when the content of 25-HP-21 in the mixed system was fixed to 2%, the optimized ratio of 25-HP-21/NaSal for this micellar system was 5∶1 （w/w）. In addition, when the mass ratio of 25-HP-21/NaSal was fixed to 5∶1, the micellar system of 3.6% 25-HP-21/NaSal showed better viscoelasticity, temperature-resistance and sand-carrying properties and more significant shear thinning and thixotropy. The¹H NMR spectrum of the system showed that the addition of NaSal was beneficial to the formation of worm-like micelles, and the arrangement of surfactant molecules were more compact. This micellar system had a simple formula and excellent properties, which was expected to enrich the family of novel clean fracturing fluids.

Key words: Gemini surfactant, clean fracturing fluid, micellar system, rheological property, microrheological property

CLC Number:

TQ423

CUI Xiu,FANG Bo,XU Hai-tao. Rheological properties of a novel clean fracturing fluid: the micellar system of 25-HP-21/NaSal[J].China Surfactant Detergent & Cosmetics, 2020, 50(10): 653-659.

Figures/Tables 13

Fig. 1

Fig. 2

Tab. 1

Fig. 3

Fig. 4

Tab. 2

Fig. 5

Fig. 6

Tab. 3

Fig. 7

Fig. 8

Fig. 9

Fig. 10

References 22

[1]	Yin Haiqing, Lin Yiyang, Huang Jianbin. Microstructures and rheological dynamics of viscoelastic solutions in a catanionic surfactant system[J]. Journal of Colloid and Interface Science, 2009,338(1) : 177-183. doi: 10.1016/j.jcis.2009.05.076 pmid: 19560154
[2]	Chu Zonglin, Dreiss C A, Feng Yujun. Smart wormlike micelles[J]. Chemical Society Reviews, 2013,42(17) : 7174-7203. doi: 10.1039/c3cs35490c
[3]	Liu Rui, Wang Xiangmei, Hu Yapeng. Progress in field of research work with respect to vesicles of bola-form surfactant self-assembly[J]. China Surfactant Detergent & Cosmetics, 2014,44(10) : 584-589.
[4]	Zhang Xudong, Ge Qing, Li Qingxia, et al. Rheological performance of aqueous solution of a cationic surfactant containing hydroxypropyl group[J]. China Surfactant Detergent & Cosmetics, 2015,45(1) : 1-6.
[5]	Wang Jinyu, Liao Geqi, He Zhiming, et al. Viscoelastic surfactant worm micelles and its application[J]. Guangdong Chemical Industry, 2017,44(22) : 85-86.
[6]	Liu Mingshu, Tang Shanfa, Fang Feifei, et al. Progress of research on ionic surfactant system for use in clean fracturing fluids[J]. Advances in Fine Petrochemicals, 2012,13(6) : 38-41.
[7]	Yu Defeng, Wang Yilin. Effect of sodium benzoate on the aggregation behavior of cationic Gemini surfactant solution [G]//Abstract of the 15^th National Conference on Chemical Thermodynamics and Thermal Analysis of the Chinese Chemical Society . Xian, 2010: 221.
[8]	Calabrese M A, Rogers S A, Murphy R P, et al. The rheology and microstructure of branched micelles under shear[J]. J. Rheol., 2015,59(5):1299-1328. doi: 10.1122/1.4929486
[9]	Chu Zonglin, Feng Yujun. pH-switchable wormlike micelles[J]. Chemical Communications, 2010,46:9028-9030. doi: 10.1039/c0cc02415e pmid: 21052582
[10]	Cao Xuejun, He Xinggui. Research progress and application prospect of foreign viscoelastic surfactant fracturing fluid[J]. Natural Gas Exploration and Development, 2014,37(2) : 76-80.
[11]	Yan Zhihu, Dai Caili, Zhao Mingwei, et al. Development, formation mechanism and performance evaluation of a reusable viscoelastic surfactant fracturing fluid[J]. Journal of Industrial and Engineering Chemistry, 2016,37:115-122. doi: 10.1016/j.jiec.2016.03.012
[12]	Zhang Lei. Status quo of research and application of clean fracturing fluids[J]. Advances in Fine Petrochemicals, 2012,13(8) : 12-15.
[13]	Wang Tongyu, Yang Shuangchun, Pan Yi, et al. Research progress on temperature resistance of cationic surfactant cleaning fracturing fluid[J]. Chemical Industry and Engineering Progress, 2017,36(12) : 4607-4612.
[14]	Liu Yong, Chen Jinhu, Wang Chenglong, et al. Preparation and evaluation of viscoelastic surfactant fracturing fluid[J]. Natural Gas Exploration and Development, 2013,14(5) : 4-7.
[15]	Baruah A, Pathak A K, Ojha K. Study on the thermal stability of viscoelastic surfactant-based fluids bearing lamellar structures[J]. Ind. Eng. Chem. Res., 2015,54:7640-7649. doi: 10.1021/acs.iecr.5b01612
[16]	Jin Leiping, Lu Yongjun, Qiu Xiaohui, et al. Viscoelastic surfactant fracturing fluids based on long chain amine oxide and their rheological properties[J]. Oilfield Chemistry, 2015,32(4) : 499-502, 506.
[17]	Jiang Guancheng, Zhang Qiang, Zhang Zhihang. Application of viscoelastic surfactant CTAB in drilling fluid[J]. Oilfield Chemistry, 2014,31(3) : 317-321.
[18]	Pei Xiaomei, Zhao Jianxi, Wei Xilian. Effect of sodium salicylate on the formation and properties of wormlike micelles in aqueous cationic Gemini surfactant solutions[J]. Acta Physico-Chimica Sinica, 2011,27(4) : 913-917. doi: 10.3866/PKU.WHXB20110420
[19]	Fang Bo, Zou Chunyu, He Lianghao, et al. Rheologic and drag-reduction properties of cationic Gemini surfactant/sodium salicylate micelle systems[J]. Journal of Chemical Engineering of Chinese Universities, 2013,27(1) : 18-23.
[20]	Lan Chengcheng, Fang Bo, Lu Yongjun, et al. Rheology of triisopropanolamine modified xanthan water solution[J]. Drilling Fluid & Completion Fluid, 2019,36(3) : 371-377.
[21]	Zhang Weican, Li Ganzuo, Mu Jianhai, et al. Effect of KBr on the micellar properties of CTAB[J]. Chinese Science Bulletin, 2000,45(20) : 1854-1856. doi: 10.1007/BF02886293
[22]	Wang Liangyuan. Study on the rheology of photosensitive Gemini cationic surfactant micelle[D]. Shanghai: East China University of Science and Technology, 2018.

w（NaSal）/%	η₀/（mPa·s）	η_∞/（mPa·s）	λ/s	n	R
0	17.85	1.42	1.51	1.687	0.993
0.2	238.35	3.80	9.22	0.575	0.991
0.3	9.67×10⁴	12.15	110.13	0.903	0.999
0.4	9.25×10⁷	130.97	6 398.77	1.108	0.997
0.55	4.21×10³	15.91	1.022	1.154	0.995

w（NaSal）/%	面积/（Pa·s^-1）
0	0.04
0.2	1.00
0.3	1.65
0.4	188.83
0.55	49.41

w/%	面积/（Pa·s^-1）
1.2	1.40
2.4	188.83
3.6	552.87
4.8	78.26

Rheological properties of a novel clean fracturing fluid: the micellar system of 25-HP-21/NaSal

RichHTML

PDF (PC)

Like

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 13

References 22

Related Articles 15

Metrics

Comments

Recommended 10

[1]	Zhisheng Zhang, Chanliang Shen, Jianxun Li, Yanqiang Liu, Weiwei Han, Sanbao Dong. Preparation and performance of betaine/AOS/Gemini ternary surfactant foam for gas well deliquification [J]. China Surfactant Detergent & Cosmetics, 2024, 54(3): 239-249.
[2]	Haokang Ai, Yajie Jiang, Yakui Wang, Lu Zhang, Tao Geng. Synthesis and properties of Gemini quaternary ammonium surfactant based on stearate [J]. China Surfactant Detergent & Cosmetics, 2024, 54(1): 16-23.
[3]	Yang Bin. Study on rheological and interfacial properties of a synergistic mixture of hydrophobically associating polymer HAWP and erucamidopropyl allyl ammonium bromide [J]. China Surfactant Detergent & Cosmetics, 2023, 53(4): 365-372.
[4]	Yongkang Zhang, Mengmeng Liu, Zhiwei Wan, Yaocong Wang, Mimi Tian, Liewei Qiu. Effect of spacer on the performance of Gemini betaine surfactant in clean fracturing fluid [J]. China Surfactant Detergent & Cosmetics, 2023, 53(12): 1398-1404.
[5]	Ting Pan, Junhui Wu, Xiaomei Pei, Zhenggang Cui. Temperature and pH responsive behavior of wormlike micelles formed by novel pseudo-gemini surfactant [J]. China Surfactant Detergent & Cosmetics, 2023, 53(12): 1361-1368.
[6]	Zhao Shufen,Zheng Danmiao,Liu Huaxi,Song Songlin,Chen Zhan,Yang Ningyuan,Wei Xingchuan. Progress in synthesis and application of rosin based gemini surfactants [J]. China Surfactant Detergent & Cosmetics, 2022, 52(8): 892-903.
[7]	Tang Yayuan,He Xuemei,Sun Jian,Wei Zhen,Li Changbao,Liu Guoming. Application and properties of the polysaccharide from red pulp pitaya stem in hand creams [J]. China Surfactant Detergent & Cosmetics, 2022, 52(4): 410-417.
[8]	Lu Xiaohao,Xu Hujun,Lin Liangliang,Chang Kuan,Gao Haiyan. Synthesis and properties of an amide cationic Gemini surfactant with ester groups [J]. China Surfactant Detergent & Cosmetics, 2021, 51(7): 598-605.
[9]	FU Duo-jiao,ZHOU Yin,CHEN Han-yu,LIU Hong-qin,XU Bao-cai. Advances in research and application of quaternary ammonium Gemini surfactants and their modified clay [J]. China Surfactant Detergent & Cosmetics, 2021, 51(4): 338-347.
[10]	ZHANG Yan-wei,CHAI Guang-qing,WANG Yan-fei,YANG Li-guo,ZHENG Yong-jun. Preparation of emulsified wax resistant to agitation for wood-based panels [J]. China Surfactant Detergent & Cosmetics, 2021, 51(1): 32-37.
[11]	CUI Xiu,FANG Bo,XU Hai-tao. Rheological properties of pH-responsive viscoelastic micellar system of oleylamidopropyl dimethyl amine/potassium hydrogen phthalate [J]. China Surfactant Detergent & Cosmetics, 2020, 50(7): 433-438.
[12]	JIANG Tong,ZHANG Chen,ZHANG Zhi-wei,SHEN Ling-hua,ZHANG Wan-ping,FANG Bo. Study on the relationship between rheological properties and the thickness of O/W creams [J]. China Surfactant Detergent & Cosmetics, 2020, 50(4): 227-232.
[13]	Yong-chen CAI,Hua-sheng ZHENG,Hu-jun XU. Synthesis and properties of an amide Gemini surfactant [J]. China Surfactant Detergent & Cosmetics, 2020, 50(3): 143-148.
[14]	KANG Wan-li,LI Xin-xin,ZHAO Yi-lu,WANG Peng-xiang,HOU Xiao-yu,YANG Hong-bin. Construction of N-erucamido-N, N-dimethylamine and benzoic acid fracturing fluid system [J]. China Surfactant Detergent & Cosmetics, 2019, 49(9): 555-560.
[15]	CAI Kun-liang,CHENG Rong,GAN Chang-sheng. Synthesis and properties of sugar-based cationic gemini surfactants [J]. China Surfactant Detergent & Cosmetics, 2019, 49(6): 351-357.