特殊烫发类产品中的巯基乙酸含量检测分析

doi:10.3969/j.issn.1001-1803.2019.07.010

Abstract

Abstract:

Thioglycolic acid contents in 48 batches of special hair perm products were detected by HPLC, ion chromatography-conductivity detector and ion chromatography-UV detector. The differences and applicability of the three detection methods were studied. The overall adding data of thioglycolic acid in 48 batches of hair perm products was obtained, and the adding trend was analyzed. The results show that the ion chromatography-UV detector method can effectively eliminate the interference of impurities, and it is similar as the detection method of thioglycolic acid in the current “Safety and Technical Standards for Cosmetics”（2015 edition）. It is recommended as a supplementary method. The contents of thioglycolic acid in all special hair perm products meet the upper limit standard established by the industry.

Key words: special hair perm products, thioglycolic acid, high performance liquid chromatography, ion chromatography

CLC Number:

TQ658.3

LIU Qi,YANG Ling,LIU Cheng-hao,HAN Xiao-qian,ZHANG Hua-jun. Detection and analysis of thioglycolic acid contents in special hair perm products[J].China Surfactant Detergent & Cosmetics, 2019, 49(7): 476-479.

Figures/Tables 7

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Tab. 1

Tab. 2

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Tab. 3

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References 10

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方法	线性方程	线性范围/（mg·L^-1）	相关系数	检出限/（mg·L^-1）	定量限/（mg·L^-1）
高效液相色谱法	y=4.970×10³x-7.980×10²	1~200	0.999 9	0.3	1
离子色谱-电导检测器法	y=4.763×10^-2x+0.186 4	1~200	0.999 8	0.3	1
离子色谱-紫外检测器法	y=2.987×10^-1x-0.373 4	1~200	0.999 8	0.5	1

方法	添加浓度/（μg·g^-1）	平均回收率/%	RSD/%	日内精密度/%	日间精密度/%
高效液相色谱法	5	92.9	3.1	1.2	3.2
	50	95.0	1.9	0.7	2.0
	200	93.3	0.8	1.3	1.9
离子色谱-电导检测器法	5	94.6	1.3	1.5	2.9
	50	98.5	0.7	0.9	2.1
	200	102.0	2.4	1.0	0.8
离子色谱-紫外检测器法	5	97.2	1.2	1.6	2.7
	50	96.7	0.8	1.1	2.6
	200	99.6	2.3	1.7	1.7

样品编号	w（巯基乙酸）/%			样品编号	w（巯基乙酸）/%
样品编号	高效液相色谱法	离子色谱- 电导检测器法	离子色谱- 紫外检测器法	样品编号	高效液相色谱法	离子色谱- 电导检测器法	离子色谱- 紫外检测器法
1	6.3	6.0	6.0	25	5.6	5.2	5.2
2	7.7	7.6	7.6	26	1.7	1.6	1.6
3	<0.1	<0.1	<0.1	27	1.4	1.2	1.2
4	0.70	0.65	0.69	28	5.0	4.6	4.6
5	2.1	1.9	1.9	29	<0.1	<0.1	<0.1
6	5.4	5.2	5.1	30	6.1	5.9	5.9
7	5.4	5.1	5.1	31	5.3	5.3	5.3
8	4.7	4.3	4.3	32	1.2	0.93	0.90
9	8.9	8.6	8.4	33	0.7	0.42	0.41
10	6.7	6.6	6.6	34	0.95	0.61	0.58
11	5.5	5.2	5.2	35	7.0	6.4	6.4
12	10.4	9.7	9.8	36	<0.1	<0.1	<0.1
13	10.0	9.1	9.1	37	<0.1	<0.1	<0.1
14	9.5	8.8	8.8	38	4.4	4.2	4.2
15	10.0	9.4	9.4	39	6.9	6.6	6.6
16	10.8	10.5	10.2	40	5.4	5.4	5.4
17	7.2	6.8	6.6	41	3.3	3.2	3.5
18	4.9	4.7	4.7	42	<0.1	<0.1	<0.1
19	9.0	8.3	8.3	43	<0.1	<0.1	<0.1
20	9.2	8.8	8.8	44	6.9	6.4	6.6
21	10.2	9.9	9.7	45	<0.1	<0.1	<0.1
22	10.2	10.2	10.2	46	2.9	2.8	2.8
23	9.3	8.9	8.9	47	10.7	10.6	10.6
24	9.8	9.2	9.2	48	8.3	8.1	8.1

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Detection and analysis of thioglycolic acid contents in special hair perm products

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