含推进剂防晒喷雾化妆品取样方式研究

doi:10.3969/j.issn.1001-1803.2019.05.011

Abstract

Abstract:

The contents of the sunscreen agents in the sunscreen spray cosmetic samples containing propellant were determined respectively by propellant-containing and propellant-free sampling method, and the results of the two methods were compared to provide a reference for standardizing the sampling method for this kind of cosmetic. Results show that the determination of sunscreen contents by sampling after propellant removal are more accurate than those without propellant removal, and the propellant-free sampling method is more reproducible with RSD less than 10%. The content of sunscreen agents in the sunscreen spray cosmetics containing propellant can be accurately determined by sampling after excluding the propellant. The measurement results of parallel samples have good reproducibility.

Key words: sunscreen spray, cosmetic, propellant, sampling method

CLC Number:

TQ658

Cite this article

GAO Jia-min,CAO Jin,WANG Gang-li. Study on sampling methods of sunscreen spray cosmetics with propellant[J].China Surfactant Detergent & Cosmetics, 2019, 49(5): 341-345.

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URL: https://www.ryhxgy.cn/EN/10.3969/j.issn.1001-1803.2019.05.011

https://www.ryhxgy.cn/EN/Y2019/V49/I5/341

Figures/Tables 5

Tab.1

Preparation of the standard stock solutions"

防晒剂	ρ/（mg·L^–1）	溶剂
苯基苯并咪唑磺酸	30	先加入少量氢氧化钠溶液使溶解,再用混合溶液定容
二苯酮-4/二苯酮-5	100	混合溶液
对氨基苯甲酸	30
二苯酮-3	100
对甲氧基肉桂酸异戊酯	100
4-甲基苄亚基樟脑	60
PABA乙基己酯	100
丁基甲氧基二苯甲酰基甲烷	300	四氢呋喃
奥克立林	100
甲氧基肉桂酸乙基己酯	100
水杨酸乙基己酯	500
胡莫柳酯	500
乙基己基三嗪酮	50
亚甲基双-苯并三唑基四甲基丁基酚	100
双-乙基己氧苯酚甲氧苯基三嗪	100

Tab.1

Tab.2

Gradient elution program"

t/min	V（甲醇）/ %	V（四氢呋喃）/ %	V（0.067%高氯酸）/ %
0	25	45	30
13	25	45	30
14	45	50	5
20	45	50	5
22	25	45	30

Tab.2

Tab.3

The content of sunscreen ingredients in formula of sunscreen"

防晒剂配方中防晒剂组分的含量	w/%
防晒剂配方中防晒剂组分的含量	甲氧基肉桂酸乙基己酯	水杨酸乙基己酯	胡莫柳酯
配方中防晒剂组分的含量（含推进剂）	2.023	1.35	1.71
配方中防晒剂组分的含量±20%（含推进剂）	1.618 4~2.427 6	1.08~1.62	1.368~2.052
配方中防晒剂组分的含量（按不含推进剂折算）	6.74	4.50	5.70
配方中防晒剂组分的含量±20%（按不含推进剂折算）	5.39~8.09	3.60~5.40	4.56~6.84

Tab.3

Tab.4

The results of sunscreen agents determined by the sampling methods with propellant"

取样方式		样品编号	w/%
取样方式		样品编号	甲氧基肉桂酸乙基己酯	水杨酸乙基己酯	胡莫柳酯
直接喷出样品取样	以样品瓶减重为取样量	1-1	1.92	1.28	1.51
		1-2	1.72	1.14	1.36
		1-3	1.64	1.09	1.28
		1-4	1.61	1.07	1.27
		1-5	1.38	0.92	1.09
		1-6	1.66	1.12	1.33
		RSD/%	10.5	10.5	10.5
	以取样瓶增重为取样量	1-1	7.27	4.86	5.74
		1-2	6.37	4.23	5.01
		1-3	4.68	3.09	3.66
		1-4	4.11	2.73	3.25
		1-5	3.58	2.40	2.85
		1-6	5.14	3.47	4.12
		RSD/%	26.9	26.9	26.7
同一样品喷出数段分别取样	第一段	2-1	4.47	3.53	4.19
	第一段	2-2	4.39	3.56	4.20
	第二段	2-3	5.18	3.98	4.77
	第二段	2-4	5.30	4.09	4.91
	第三段	2-5	4.78	3.65	4.38
	第三段	2-6	4.87	3.68	4.43
		RSD/%	12.1	10.5	10.9

Tab.4

Tab.5

The results of sunscreen agents determined by the sampling methods without propellant"

取样方式	样品编号	w/%
取样方式	样品编号	甲氧基肉桂酸乙基己酯	水杨酸乙基己酯	胡莫柳酯
全喷入接收瓶超声后取样	1-1	6.64	4.72	5.76
全喷入接收瓶超声后取样	1-2	6.83	4.85	5.92
导管全导出超声后取样	2-1	7.10	4.98	6.10
导管全导出超声后取样	2-2	6.89	4.86	5.93
打孔排气后超声倒出再取样	3-1	7.15	5.05	6.17
打孔排气后超声倒出再取样	3-2	7.14	5.06	6.18
打孔排气后超声直接瓶中取样	4-1	6.12	4.40	5.37
打孔排气后超声直接瓶中取样	4-2	5.89	4.16	5.09
RSD/%		7.1	6.8	6.8

Tab.5

References 5

[1]	Ministry of Health of the People’s Republic of China. Regulations on the supervision of cosmetics hygiene (order No. third of ministry of health) [EB/OL]. ( 1989- 09- 26) [2018-08-18]. http://www.sda.gov.cn/WS01/CL0053/110567.html.
[2]	Wang Feifei, Ma Xiao, Mo Junying , et al. Research on characteristics of three different types of sunscreen by sensory analysis and consumer investigation[J]. Flavour Fragrance Cosmetics, 2018,4(2) : 69-75.
[3]	Ma Xiao, Wang Feifei, Mo Junying , et al. Prediction of overall preferences of sunscreen products by multiple linear regression analysis[J]. Detergent & Cosmetics, 2017,40(9) : 18-24.
[4]	Wang Xiuping, Niu Wenxia, Bai Xiaoyun , et al. Evaluation of eleven commercial sun-protection cosmetics with SPF-290S analyzer system[J]. Flavour Fragrance Cosmetics, 2014,8(4) : 32-34, 37.
[5]	Zhou Xiaoping . Perspective of European sun care market[J]. Detergent & Cosmetics, 2006,29(9) : 14-17.

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