复杂泡沫体系排液动力学研究进展

doi:10.3969/j.issn.1001-1803.2022.09.014

摘要/Abstract

摘要：

看似普通的小气泡,在人们的日常生活、工业生产和医药卫生等领域却发挥着极其重要的作用,而对于含有不同精细结构的复杂泡沫体系而言,其具有更加丰富的流动和稳定特性。本文针对这类复杂泡沫体系,包括表面活性剂聚集体稳定泡沫、纳米颗粒稳定泡沫和油水混相泡沫的排液动力学研究的发展现状做一总结评述。聚焦复杂泡沫体系中精细结构对其排液行为的影响机制,通过文献调研指明了该领域今后的研究方向与手段。

关键词: 复杂泡沫, 表面活性剂, 精细结构, 排液动力学, 稳定性

Abstract:

Bubbles play extremely important roles in our daily life and in the fields of industrial production, medicine, health care, etc. Concerning complex foam systems with different fine structures, they have a variety of flow and stability properties. However, the drainage behavior of complex foam systems has been far less studied compared with simple foams. Herein, the research status and development of dynamics of liquid drainage from complex foam systems are reviewed, including surfactant-aggregate-stabilized foams, nanoparticle-stabilized foams, and oil-water miscible foams. For the surfactant-aggregate-stabilized foam systems, two flow models such as Poiseuille flow and plug flow, and their kinetic equations are introduced. The drainage behaviors of nanoparticle-stabilized foam systems are emphasized in aspects of particle size effects and particle trapping and blocking effects. The two different forms of oil phase （dissolved oil/emulsified oil） have completely different effects on the drainage behavior of oil-water miscible foams. The drainage behaviors of complex foam systems with fine structures have not been well studied yet, and there are many theoretical disagreements and debates. It is necessary to carry out more in-depth research on basic theoretical issues. We believe that the research on the fluid drainage dynamics of complex foam systems will be a research hotspot at present and for a long time in the future.

Key words: complex foam, surfactant, fine structure, drainage dynamics, stability

中图分类号:

TQ423

燕永利,蔡雨秀,豆龙龙,曹玉霞. 复杂泡沫体系排液动力学研究进展[J]. 日用化学工业, 2022, 52(9): 1011-1015.

Yan Yongli,Cai Yuxiu,Dou Longlong,Cao Yuxia. Research progress in the dynamics of liquid drainage from complex foam system[J]. China Surfactant Detergent & Cosmetics, 2022, 52(9): 1011-1015.

图/表 5

参考文献 40

[1]	Stevenson P. Foam engineering, fundamentals and applications[M]. Pondicherry: Wiley-Blackwell, 2012: 227-509.
[2]	Hill C, Eastoe J. Foams: From nature to industry[J]. Advances in Colloid and Interface Science, 2017, 247: 496-513. doi: 10.1016/j.cis.2017.05.013
[3]	Rio E, Drenckhan W, Salonen A D, et al. Unusually stable liquid foams[J]. Advances in Colloid and Interface Science, 2014, 205: 74-86. doi: 10.1016/j.cis.2013.10.023
[4]	Lee M, Lee E Y, Lee D, et al. Stabilization and fabrication of microbubbles: Applications for medical purposes and functional materials[J]. Soft Matter, 2015, 11: 2067-2079. doi: 10.1039/C5SM00113G
[5]	Zhou J, Ranjith P G, Wanniarachchi W A M. Different strategies of foam stabilization in the use of foam as a fracturing fluid[J]. Advances in Colloid and Interface Science, 2020, 276: 102104. doi: 10.1016/j.cis.2020.102104
[6]	Friberg S E, Solans C. Surfactant association structures and the stability of emulsions and foams[J]. Langmuir, 1986, 2: 121-126. doi: 10.1021/la00068a001
[7]	Dickinson E. Structuring of colloidal particles at interfaces and the relationship to food emulsion and foam stability[J]. Journal of Colloid and Interface Science, 2015, 449: 38-45. doi: 10.1016/j.jcis.2014.09.080 pmid: 25446956
[8]	Zhang Yusong, Liu Qi, Ye Hang, et al. Nanoparticles as foam stabilizer: Mechanism, control parameters and application in foam flooding for enhanced oil recovery[J]. Journal of Petroleum Science and Engineering, 2021, 202: 108561. doi: 10.1016/j.petrol.2021.108561
[9]	Langevin D. Aqueous foams: A field of investigation at the frontier between chemistry and physics[J]. ChemPhysChem, 2008, 9: 510-522. doi: 10.1002/cphc.200700675
[10]	Wang J, Nguyen A V, Farrokhpay S. A critical review of the growth, drainage and collapse of foams[J]. Advances in Colloid and Interface Science, 2016, 228: 55-70. doi: 10.1016/j.cis.2015.11.009
[11]	Jalmes A S. Physical chemistry in foam drainage and coarsening[J]. Soft Matter, 2006, 2: 836-849. doi: 10.1039/b606780h
[12]	Addad S C, Höhler R, Pitois O. Flow in foams and flowing foams[J]. Annual Review of Fluid Mechanics, 2013, 45: 241-267. doi: 10.1146/annurev-fluid-011212-140634
[13]	Denkov N, Tcholakova S, Brinkova N P. Physicochemical control of foam properties[J]. Current Opinion in Colloid & Interface Science, 2020, 50: 101376. doi: 10.1016/j.cocis.2020.08.001
[14]	Sun Qicheng. Liquid foam drainage: an overview[J]. International Journal of Modern Physics B, 2008, 22: 2333-2354. doi: 10.1142/S0217979208039514
[15]	Giavazzi F, Trappe V, Erbino R. Multiple dynamic regimes in a coarsening foam[J]. Journal of Physics: Condensed Matter, 2021, 33: 24002. doi: 10.1088/1361-648X/abb684
[16]	Roberts K, Axberg C, Österlund R, et al. Liquid crystals as lamellar reservoirs reduce thinning by drainage[J]. Nature, 1975, 255: 53-54. doi: 10.1038/255053a0
[17]	Bergeron V. Forces and structure in thin liquid soap films[J]. Journal of Physics: Condensed Matter, 1999, 11: 215-238.
[18]	Karakashev S I. Hydrodynamics of foams[J]. Experiments in Fluids, 2017, 58: 91. doi: 10.1007/s00348-017-2332-z
[19]	Weaire D, Hutzler S. The physics of foams[M]. Oxford: Oxford University Press, 1999: 126-143.
[20]	Verbist G, Weaire D, Kraynik A M. The foam drainage equation[J]. Journal of Physics: Condensed Matter, 1996, 8: 3715-3731. doi: 10.1088/0953-8984/8/21/002
[21]	Hilgenfeldt S, Arif S, Tsai J C. Foam: A multiphase system with many facets[J]. Philosophical Transactions of the Royal Society A, 2008, 366: 2145-2159.
[22]	Koehler S A, Hilgenfeldt S, Stone H A. A generalized view of foam drainage: Experiment and theory[J]. Langmuir, 2000, 16: 6327-6341. doi: 10.1021/la9913147
[23]	Yan Yongli, Qu Chengtun, Zhang Ningsheng, et al. A study on the kinetics of liquid drainage from colloidal gas aphrons (CGAs)[J]. Colloidsand Surfaces A: Physicochemicaland Engineering Aspects, 2005, 259: 167-172.
[24]	Chen Zonglin, Yan Yongli, Huang Xuebin. Stabilization of foams solely with polyoxyethylene-type nonionic surfactant[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2008, 331: 239-244. doi: 10.1016/j.colsurfa.2008.08.011
[25]	Horozov T S. Foams and foam films stabilized by solid particles[J]. Current Opinion in Colloid & Interface Science, 2008, 13: 134-140. doi: 10.1016/j.cocis.2007.11.009
[26]	Narsimhan G. Drainage of particle stabilized foam film[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2016, 495: 20-29. doi: 10.1016/j.colsurfa.2016.01.044
[27]	Briceño-Ahumada Z, Soltero-Martínez J F A, Castillo R. Aqueous foams and emulsions stabilized by mixtures of silica nanoparticles and surfactants: A state-of-the-art review[J]. Chemical Engineering Journal Advances, 2021, 7: 100116. doi: 10.1016/j.ceja.2021.100116
[28]	Haffner B, Khidas Y, Pitois O. The drainage of foamy granular suspensions[J]. Journal of Colloid and Interface Science, 2015, 458: 200-208. doi: 10.1016/j.jcis.2015.07.051
[29]	Wang J, Nguyen A V. Foam drainage in the presence of solid particles[J]. Soft Matter, 2016, 12: 3004-3012. doi: 10.1039/c6sm00028b pmid: 26877265
[30]	Britan A, Liverts M, Ben-Dor G, et al. The effect of fine particles on the drainage and coarsening of foam[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2009, 344: 15-23. doi: 10.1016/j.colsurfa.2009.03.011
[31]	Denkov N D. Mechanisms of foam destruction by oil-based antifoams[J]. Langmuir, 2004, 20: 9463-9505. doi: 10.1021/la049676o
[32]	Lee J, Nikolov A, Wasan D. Stability of aqueous foams in the presence of oil: On the importance of dispersed vs solubilized oil[J]. Industrial & Engineering Chemistry Research, 2013, 52: 66-72. doi: 10.1021/ie301102m
[33]	Koursari N, Johnson P, Parsa M, et al. Modelling of foamed emulsion drainage[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2020, 600: 124915. doi: 10.1016/j.colsurfa.2020.124915
[34]	Salonen A, Lhermerout R, Rio E, et al. Dual gas and oil dispersions in water: production and stability of foamulsion[J]. Soft Matter, 2012, 8: 699-706. doi: 10.1039/C1SM06537H
[35]	Schneider M, Zou Z, Langevin D, et al. Foamed emulsion drainage: Flow and trapping of drops[J]. Soft Matter, 2017, 13: 4132-4141. doi: 10.1039/c7sm00506g pmid: 28555683
[36]	Mensire R, Lorenceau E. Stable oil-laden foams: Formation and evolution[J]. Advances in Colloid and Interface Science, 2017, 247: 465-476. doi: S0001-8686(17)30222-1 pmid: 28821347
[37]	Yan Yongli, Shan Cheng, Wang Yao, et al. Effects of oil on aqueous foams: Electrical conductivity of foamed emulsions[J]. ChemPhysChem, 2014, 15: 3110-3115. doi: 10.1002/cphc.201402219 pmid: 25056102
[38]	Stone H A, Koehler S A, Hilgenfeldt S, et al. Perspectives on foam drainage and the influence of interfacial rheology[J]. Journal of Physics: Condensed Matter, 2003, 15: 283-290.
[39]	Fameau A L, Salonen A. Effect of particles and aggregated structures on the foam stability and aging[J]. Comptes Rendus Physique, 2014, 15: 748-760. doi: 10.1016/j.crhy.2014.09.009
[40]	Behrens S H. Oil-coated bubbles in particle suspensions, capillary foams, and related opportunities in colloidal multiphase systems[J]. Current Opinion in Colloid & Interface Science, 2020, 50: 101384. doi: 10.1016/j.cocis.2020.08.009