非碱性条件下磷酸镍钴分子筛对甘油催化氧化反应研究

doi:10.13218/j.cnki.csdc.2015.07.005

日用化学工业 ›› 2015, Vol. 45 ›› Issue (7): 381-384.doi: 10.13218/j.cnki.csdc.2015.07.005

非碱性条件下磷酸镍钴分子筛对甘油催化氧化反应研究

王增龙, 王超, 刘雷

太原理工大学精细化工研究所,山西太原 030024

收稿日期:2015-04-09 修回日期:2015-06-29 发布日期:2019-04-10
通讯作者: 刘雷,教授,博士生导师,电话:13934227874,E-mail:liulei@tyut.edu.cn。
作者简介:王增龙(1988-),男,内蒙古人,硕士研究生,电话:18334706213,E-mail:951031343@qq.com。
基金资助:
国家优秀青年科学基金资助项目(21322608); 全国优秀博士学位论文作者专项资金资助项目(201350); 山西省青年拔尖人才支持项目

Study of catalytic oxidation of glycerol on cobalt-nickel phosphate molecular sieve under non-alkaline condition

WANG Zeng-long, WANG Chao, LIU Lei

Research Institute of Special Chemicals,Taiyuan University of Technology,Taiyuan,Shanxi 030024,China

Received:2015-04-09 Revised:2015-06-29 Published:2019-04-10

摘要/Abstract

摘要： 采用水热合成法制备了磷酸镍钴分子筛(Co-VSB-1),将焙烧后的样品作为催化剂,在非碱性条件下以H₂O₂作为氧化剂用于甘油的催化氧化反应,考察了反应时间、温度以及H₂O₂和甘油摩尔比对甘油催化活性和选择性的影响。结果表明:Co-VSB-1作为催化剂对甘油酸和甲酸具有较高的选择性,当n(H₂O₂)∶n(甘油)=2∶1,反应时间为4 h,反应温度为70 ℃时,甘油的转化率为8.2%,甘油酸、甲酸和乙醇酸的选择性分别为45.1%,49.9%和5.0%。同时,通过催化性能实验,发现Co-VSB-1骨架中的钴离子作为催化活性中心对甘油的氧化起到了催化作用。

关键词: 甘油, 磷酸镍钴, 催化氧化, 非碱性

Abstract: Cobalt-nickel phosphate molecular sieve (Co-VSB-1) was prepared adopting hydrothermal method.The calcined Co-VSB-1 was used as catalyst for the oxidation of glycerol with H₂O₂ as oxidant under non-alkaline condition.The effect of reaction conditions,such as the reaction time,temperature,H₂O₂/glycerol molar ratio,on the conversion and selectivity of glycerol oxidation were investigated in detail.The results showed that the Co-VSB-1 displays rather high selectivity with main oxidation products of glyceric acid and formic acid.Under the reaction conditions as:H₂O₂/glycerol molar ratio of 2,reaction time of 4 h and reaction temperature of 70 ℃,the conversion ratio of glycerol was 8.2% and the selectivity of glyceric acid,formic acid and glycolic acid was 45.1%,49.9% and 5.0%,respectively.Meanwhile,catalyst performance test result showed that the cobalt ions in the framework of Co-VSB-1 are responsible for the catalytic oxidation of glycerol.

Key words: glycerol, cobalt-nickel phosphate, catalytic oxidation, non-alkaline

中图分类号:

TQ645.5

王增龙, 王超, 刘雷. 非碱性条件下磷酸镍钴分子筛对甘油催化氧化反应研究[J]. 日用化学工业, 2015, 45(7): 381-384.

WANG Zeng-long, WANG Chao, LIU Lei. Study of catalytic oxidation of glycerol on cobalt-nickel phosphate molecular sieve under non-alkaline condition[J]. China Surfactant Detergent & Cosmetics, 2015, 45(7): 381-384.

参考文献

[1] QUISPE C A G,CORONADO C J R,CARVALHO JR J A.Glycerol:production,consumption,prices,characterization and new trends in combustion[J].Renewable Sustainable Energy Rev,2013,27:475-493.
[2] ZHOU C H,BELTRAMINI J N,FAN Y X,et al.Chemoselective catalytic conversion of glycerol as a biorenewable source to valuable commodity chemicals[J].Chem Soc Rev,2008,37(3):527-549.
[3] PAGLIARO M,CIRIMINNA R,KIMURA H,et al.From glycerol to value-added products[J].Angewandte Chemie,2007,46(24):4434-4440.
[4] KATRYNIOK B,KIMURA H,SKRZYNSKA E,et al.Selective catalytic oxidation of glycerol:perspectives for high value chemicals[J].Green Chem,2011,13(8):1960-1979.
[5] BELTRAN-PRIETO J C,KOLOMAZNIK K,PECHA J.A review of catalytic systems for glycerol oxidation:Alternatives for waste valorization[J].Aust J Chem,2013,66(5):511-521.
[6] HABE H,FUKUOKA T,KITAMOTO D,et al.Biotechnological production of D-glyceric acid and its application[J].Applied Microbiology and Biotechnology,2009,84(3):445-452.
[7] FUKUZUMI S,KOBAYASHI T,SUENOBU T.Unusually large tunneling effect on highly efficient generation of hydrogen and hydrogen isotopes in pH-selective decomposition of formic acid catalyzed by a heterodinuclear iridium-ruthenium complex in water[J].Journal of the American Chemical Society,2010,132(5):1496-1497.
[8] CARRETTIN S,MCMORN P,JOHNSTON P,et al.Oxidation of glycerol using supported Pt,Pd and Au catalysts[J].Phys Chem Chem Phys,2003,5(6):1329-1336.
[9] GARCIA R,BESSON M,GALLEZOT P.Chemoselective catalytic oxidation of glycerol with air on platinum metals[J].Applied Catalysis A:General,1995,127(1/2):165-176.
[10] PORTA F,PRATI L.Selective oxidation of glycerol to sodium glycerate with gold-on-carbon catalyst:an insight into reaction selectivity[J].J Catal,2004,224(2):397-403.
[11] LARI G M,MONDELLI C,PEÉREZ-RAMÍREZ J.Gas-phase oxidation of glycerol to dihydroxyacetone over tailored iron zeolites[J].ACS Catalysis,2015,5(3):1453-1461.
[12] GUILLOU N,GAO Q,NOGUES M,et al.Zeolitic and magnetic properties of a 24-membered ring porous nickel (II) phosphate,VSB-1[J].Comptes Rendus de I?Académie des Sciences-Series IIC-Chemistry,1999,2(7):387-392.
[13] XIE L L,GAO Q M,LI Q H.Nanoporous metal phosphate Co-VSB-1 catalyst for oxidation of styrene with H₂O₂[J].Stud Surf Sci Catal,2007,170B:1338-1343.
[14] TIMOFEEVA M N,PANCHENKO V N,HASAN Z,et al.Catalytic potential of the wonderful chameleons:Nickel phosphate molecular sieves[J].Appl Catal,A,2013,455:71-85.
[15] CHANG J S,HWANG J S,JHUNG S H,et al.Nanoporous metal-containing nickel phosphates:A class of shape-selective catalyst[J].Angew Chem,Int Ed,2004,43(21):2819-2822.
[16] CHANG J S,GAO Q,CHEETHAM A K,et al.Catalytic conversion of butadiene to ethylbenzene over the nanoporous nickel(II) phosphate,VSB-1[J].Chem Commun,2001(9):859-860.
[17] XIE L,GAO Q,SU X,et al.Synthesis and characterization of nanoporous nickel phosphates VSB-1 with systematic doping of cobalts in the frameworks[J].Microporous Mesoporous Mater,2004,75(1/2):135-141.
[18] KWON Y,RAAIJMAN SJ,KOPER MTM.Role of peroxide in the catalytic activity of gold for oxidation reactions in aqueous media:An electrochemical study[J].Chem Cat Chem,2014,6(1):79-81.
[19] WANG X,GAO Q,WU C,et al.Preparation,channel surface hydroxyl characterization and photoluminescence properties of nanoporous nickel phosphate VSB-1[J].Microporous Mesoporous Mater,2005,85(3):355-364.

非碱性条件下磷酸镍钴分子筛对甘油催化氧化反应研究

Study of catalytic oxidation of glycerol on cobalt-nickel phosphate molecular sieve under non-alkaline condition

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