高悬浮能力清洁剂的制备与性能研究

doi:10.3969/j.issn.1001-1803.2022.03.004

Abstract

Abstract:

In order to prepare detergents with high suspension ability, low viscosity, high transparency and low film-forming ability, two monomers of ethyl acrylate and methacrylic acid were used to prepare the polymer as the suspending agent in detergent （experimental group A）. The influence of different monomer ratios on the suspension ability of the suspension agent was investigated. The viscosity and turbidity, suspension ability, film-forming ability and shear thinning ability in detergent of the experimental group A was compared with two commonly used acrylic suspension agents, namely Carbopol® Aqua SF-1 Polymer （control group B） and Carbopol® Aqua SF-2CN Polymer （control group C）. The results show that the ductility in application of the experimental group A is the best due to the smallest viscosity in the same experimental conditions. When the mass fraction of the suspending agent is ≥1.8%, all three suspending agents have good transparency and suspending ability. The film forming ability of the experimental group A is the worst, therefore it is not easy to block the pump head. The spray extrusion strength and spray uniformity of the experimental group A are better than those of the control group B and the control group C. Overall, the performances of the experimental group A are the best.

Key words: suspending agent, detergent, viscosity, turbidity, film-forming ability

CLC Number:

TQ423

Cite this article

Zhang Yun,Li Chen,Yu Sihan,Liu Dong. Study on preparation and performances of high suspension ability detergent[J].China Surfactant Detergent & Cosmetics, 2022, 52(3): 253-257.

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URL: https://www.ryhxgy.cn/EN/10.3969/j.issn.1001-1803.2022.03.004

https://www.ryhxgy.cn/EN/Y2022/V52/I3/253

Figures/Tables 6

Fig. 1

Suspension ability of the polymers that prepared with different monomer ratios"

Fig. 1

Tab. 1

The viscosity and turbidity of the detergents that prepared by different suspending agents at different mass fractions and pH values"

悬浮剂种类	质量分数/%	体系黏度/（mPa·s）			体系浊度/NTU
悬浮剂种类	质量分数/%	pH=4.0	pH=7.0	pH=10.0	pH=4.0	pH=7.0	pH=10.0
实验组A	0.6	16.5	6.3	8.4	380	294	295
	0.9	99.3	29.4	28.8	321	218	210
	1.2	145	112.8	100.2	296	154	143
	1.8	1 452	372	367	147	79.6	77.4
	3.0	3 323	1 386	1 218	81	56.3	50.2
对照组B（Carbopol® Aqua SF-1 Polymer）	0.6	32.7	10.2	9.3	563	40.8	152
	0.9	197.1	67.8	50.4	313	23	100
	1.2	646.4	260.9	183	203	10.9	60.4
	1.8	2 220	1 176	721	145	5.56	26.8
	3.0	7 332	5 153	3 263	183	5.14	14
对照组C（Carbopol® Aqua SF-2 Polymer）	0.6	23.2	9.2	8.1	432	92	192
	0.9	145.2	47.2	45.9	322	46	82
	1.2	292.1	172.4	161	265	38	71
	1.8	1 720	721	670	148	12	32
	3.0	5 210	2 432	2 152	142	9.2	12

Tab. 1

Tab. 2

The suspending ability of the detergents that prepared by different suspending agents at different mass fractions and pH values"

悬浮剂种类	质量分数/%	悬浮能力评分
悬浮剂种类	质量分数/%	pH=4.0	pH=7.0	pH=10.0
实验组A	0.6	1	0	0
	0.9	3	1	0
	1.2	6	3	0
	1.8	10	7	5
	3.0	10	10	10
对照组B	0.6	3	0	0
	0.9	4	1	0
	1.2	6	4	0
	1.8	10	10	10
	3.0	10	10	10
对照组C	0.6	0	0	0
	0.9	3	0	0
	1.2	6	5	0
	1.8	10	10	5
	3.0	10	10	10

Tab. 2

Fig. 2

The photos of the experimental group A for （A） 0 d and （B） 28 d with suspension mass fraction of 3.0% at 50 ℃"

Fig. 2

Fig. 3

The film formation puncture results of the （A） experimental group A, （B） control group B and （C） control group C"

Fig. 3

Tab. 3

The spray test of the detergents that prepared with different suspension agents"

悬浮剂种类	喷雾测试
悬浮剂种类	喷雾挤压力度	喷雾均匀度
实验组A	5	5
对照组B	4	3
对照组C	4	4

Tab. 3

References 5

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[3]	Zhao Shikuang, Cheng Juhua, Zhang Yucang, et al. Preliminary study on the viscosity and suspension ability of composite xanthan gum[J]. Food Science, 1998, 19(4) : 12-15.
[4]	Jeffery M. Yield stress measurements for personal care, part 1: definitions and basics[J]. Cosmetics & Toiletries, 2015, 130(8) : 44-56.
[5]	Jaromír Š, Otakar Q, Jiří H. Effect of styrene and methyl methacrylate comonomers in ethyl acrylate/methacrylic acid latex on particle alkali-swellability, film formation and thickening with associative thickeners[J]. Progress in Organic Coatings, 2005, 54(2) : 99-103. doi: 10.1016/j.porgcoat.2005.04.003

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