pH响应黏弹性油酰胺丙基二甲胺/邻苯二甲酸氢钾胶束体系流变性研究

doi:10.3969/j.issn.1001-1803.2020.07.001

Abstract

Abstract:

The pH responsiveness of the viscoelastic micellar system of oleylamidopropyl dimethyl amine （PKO-O）/potassium hydrogen phthalate （PHP） was studied by investigating the rheological properties such as steady-state shear viscosity, flow curve, shear thixotropy, viscoelasticity and thermal thixotropy of the fluid. The steady-state shear viscosity of the micellar system （pH=7.47） was high, which was 122.3 mPa·s at 200 s^-1. And the steady-state shear viscosity could be switched cyclically between the status at pH 7.61, 7.47 and 6.40, indicating that this micellar system had good pH responsiveness. In addition, the PKO-O/PHP micellar system was shear-thinning and positive thixotropic fluid. The flow curve could be characterized by the Cross constitutive equation. The micellar system （pH=7.47） was a typical viscoelastic fluid with high complex modulus and significant thermal thixotropy.

Key words: oleylamidopropyl dimethyl amine, potassium hydrogen phthalate, pH-responsive micellar system, rheological property

CLC Number:

TQ423

CUI Xiu,FANG Bo,XU Hai-tao. Rheological properties of pH-responsive viscoelastic micellar system of oleylamidopropyl dimethyl amine/potassium hydrogen phthalate[J].China Surfactant Detergent & Cosmetics, 2020, 50(7): 433-438.

Figures/Tables 9

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References 25

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pH	η₀/(mPa·s)	η_∞/(mPa·s)	λ/s	n	R
7.61	2.92×10⁵	2.59	150.15	0.91	0.999
7.47	2.68×10⁶	88.90	215.05	1.10	0.996
6.40	3.35×10⁵	2.30	80.26	1.00	0.999

Rheological properties of pH-responsive viscoelastic micellar system of oleylamidopropyl dimethyl amine/potassium hydrogen phthalate

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