一种含羟丙基的阳离子表面活性剂的流变性能

doi:10.13218/j.cnki.csdc.2015.01.001

Abstract

Abstract: Rheological performance of aqueous solution of a cationic surfactant (3-tetradecyloxy-2-hydroxypropyltrimethylammonium bromide,R₁₄HTAB) was studied with steady and dynamic shear rheological method.Results showed that structure of the self-asembly of the R₁₄HTAB undergoes three transitions in the shape within the investigated concentration range,from spherical to rodlike micelles,then to viscoelastic wormlike micelles,and finally to hexagonal lytropic liquid crystal.The transition from spherical micelles into rodlike micelles takes place as the concentration of R₁₄HTAB higher than 360 mmol/kg.The overlapped threshold micelle concentration is about 500 mmol/kg.The viscosity at zero shear (η₀) and R₁₄HTAB concentration (C) displays exponential relationship,i.e.,η₀∝C^5.7.The microstructure of the formed micelles was further ascertained by FF-transmission electronic microscopy.The deviations from Cox-Merz rule in the steady and dynamic viscosity experiment is mainly due to formation of hydrogen bond.

Key words: 3-tetradecyloxy-2-hydroxypropyltrimethylammonium bromide, rheological property, self-asembly, network structure

CLC Number:

TQ423.12

ZHANG Xu-dong, GE Qing, LI Qing-xia, YANG Min, HAN Chuan-hong, WEI Xi-lian. Rheological performance of aqueous solution of a cationic surfactant containing hydroxypropyl group[J].China Surfactant Detergent & Cosmetics, 2015, 45(1): 1-6.

References

[1] LEE H Y,DIEHN K K,RAGHAVAN S R,et al.Reversible photorheological fluids based on spiropyran-doped reverse micelles [J].J Am Chem Soc,2011,133:8461-8463.
[2] LEHN J M.Toward self-organization and complex matter [J].Science,2002,295:2400-2403.
[3] WANG C,WANG Z Q,ZHANG X.Amphiphilic building blocks for self-assembly:from amphiphiles to supra-amphiphiles [J].Acc Chem Res,2012,45:608-618.
[4] DREISS C A.Wormlike micelles:where do we stand? Recent developments,linearrheology and scattering techniques [J].Soft Matter,2007,3:956-970.
[5] WANG XIAOQING,WANG RUITAO,ZHENG YAN,et al.Interaction between zwitterionic surface activity ionic liquid and anionic surfactant:Na⁺-driven wormlike micelles [J].J Phys Chem B,2013,117:1886-1895.
[6] NARAYANNAN R O J,HASSAN P A,MANOHAR C R,et al.Effect of the lipophilicity of the counterion on the viscoelasticity of micellar solutions of cationic surfactants [J].Langmuir,1998,14:4364-4372.
[7] KHATORY A,KERN F,LEQUEUX F,et al.Entangled versus multiconnected network of wormlike micelles [J].Langmuir,1993,9:933-939.
[8] HELGESON M E,HODGDON T K,KALER E W,et al.Formation and rheology of viscoelastic “double networks” in wormlike micelle-nanoparticle mixtures [J].Langmuir,2010,26:8049-8060.
[9] LIN YIYANG,QIAO YAN,HUANG JIABIN,et al.Thermo-responsive viscoelastic wormlike micelle to elastic hydrogel transition in dual-component systems [J].Soft Matter,2009,5:3047-3053.
[10] WEI XILIAN,LIU JIE,YIN BAOLIN,et al.Studies on lyotropic liquid crystal formation in the ternary systems of a type of new cationic surfactant/n-butanol/water by means of phase diagram,2H quadrupolar splitting and X-ray diffraction [J].J Disper Sci Technol,2005,26:779-783.
[11] WEI XILIAN,WANG XIUHONG,LIU JIE,et al.Adsorption kinetics of 3-alkoxy-2-hydroxypropyl trimethyl ammonium chloride at oil-water interface [J].Appl Surf Sci,2012,261:237-241.
[12] SUN DEZUI,WANG SHIBING,WEI XILIAN,et al.A microcalorimetric study of β-cyclodextrin with 3-alkoxyl-2-hydroxypropyl trimethyl ammonium bromides in aqueous solutions [J].J Chem Therm,2005,37:431-436.
[13] WEI ZENGBIN,WEI XILIAN,WANGH XIUHONG,et al.Ionic liquid crystals of quaternary ammonium salts with a 2-hydroxypropoxy insertion group [J].J Mater Chem,2011,21:6875-6882.
[14] REHAGE H,HOFFMANN H.Viscoelastic surfactant solutions:model systems for rheological research [J].Mol Phys,1991,74:933-973.
[15] GRANEK R,CATES M E.Stress relaxation in living polymers:Results from a poisson renewal model [J].J Chem Phys,1992,96:4758-4767.
[16] MONTALVO G,VALIENTE M,RODENAS E.Rheological properties of the L phase and the hexagonal,lamellar,and cubic liquid crystals of the CTAB/benzyl alcohol/water system [J].Langmuir,1996,12:5202-5208.
[17] MIYOSHI E,NISHINARI K.Non-Newtonian flow behavior of gellan gum aqueous solutions [J].Colloid Polym Sci,1999,277:727-734.
[18] OHSHIMA A,KUDO H,SATO T,et al.Entanglement effects in semiflexible polymer solutions.1.Zero-shear viscosity of poly(n-hexyl isocyanate) solutions [J].Macromolecules,1995,28:6095-6099.
[19] ENOMOTO H,EINAGA Y,TERAMOTO A.Viscosity of concentrated solutions of rodlike polymers [J].Macromolecules,1985,18:2695-2702.
[20] WEI XILIAN,PING ALI,DU PANPAN,et al.Formation and properties of wormlike micelles in solutions of a cationic surfactant with a 2-hydroxypropoxy insertion group [J].Soft Matter,2013,9:8454-8463.
[21] CAPPELAERE E,RESSELY R,DECRUPPE J P.Linear and non-linear rheological behaviour of salt-free aqueous CTAB solutions [J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,1995,104:353-374.
[22] DOI M,EDWARDS S F.The theory of polymer dynamic [M].Oxford,UK:Clarendon,1986.
[23] 范海明,吴晓燕,黄经纬,等.两性/阴离子表面活性剂形成具有耐盐性能的蠕虫状胶束[J].化学学报,2011,69(17):1997-2002.
[24] WINTER H H.Three views of viscoelasticity for Cox-Merz materials [J].Rheol Acta,2009,48:241-243.
[25] KULICKE W M,PORTER R S.Relation between steady shear flow and dynamic rheology [J].Rheol Acta,1980,19:601-605.
[26] MEZZENGA R,MEYER C,SERVAIS C,et al.Shear rheology of lyotropic liquid crystals:A case study [J].Langmuir,2005,21:3322-3333.

Rheological performance of aqueous solution of a cationic surfactant containing hydroxypropyl group

PDF (PC)

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 9

Metrics

Comments

Recommended 10

[1]	Yang Bin. Study on rheological and interfacial properties of a synergistic mixture of hydrophobically associating polymer HAWP and erucamidopropyl allyl ammonium bromide [J]. China Surfactant Detergent & Cosmetics, 2023, 53(4): 365-372.
[2]	Tang Yayuan,He Xuemei,Sun Jian,Wei Zhen,Li Changbao,Liu Guoming. Application and properties of the polysaccharide from red pulp pitaya stem in hand creams [J]. China Surfactant Detergent & Cosmetics, 2022, 52(4): 410-417.
[3]	ZHANG Yan-wei,CHAI Guang-qing,WANG Yan-fei,YANG Li-guo,ZHENG Yong-jun. Preparation of emulsified wax resistant to agitation for wood-based panels [J]. China Surfactant Detergent & Cosmetics, 2021, 51(1): 32-37.
[4]	CUI Xiu,FANG Bo,XU Hai-tao. Rheological properties of pH-responsive viscoelastic micellar system of oleylamidopropyl dimethyl amine/potassium hydrogen phthalate [J]. China Surfactant Detergent & Cosmetics, 2020, 50(7): 433-438.
[5]	JIANG Tong,ZHANG Chen,ZHANG Zhi-wei,SHEN Ling-hua,ZHANG Wan-ping,FANG Bo. Study on the relationship between rheological properties and the thickness of O/W creams [J]. China Surfactant Detergent & Cosmetics, 2020, 50(4): 227-232.
[6]	CUI Xiu,FANG Bo,XU Hai-tao. Rheological properties of a novel clean fracturing fluid: the micellar system of 25-HP-21/NaSal [J]. China Surfactant Detergent & Cosmetics, 2020, 50(10): 653-659.
[7]	JIANG Tong,ZHANG Chen,ZHANG Zhi-wei,ZHANG Wan-ping,FANG Bo. Study on rheological properties and melting sensation of O/W cream [J]. China Surfactant Detergent & Cosmetics, 2019, 49(11): 705-710.
[8]	ZENG Hai-yan, CAO Guang-qun, YANG Cheng, DONG Wei. Study on Pickering emulsions stabilized by gel nanoparticles composed of chitosan and sodium tripolyphosphate [J]. China Surfactant Detergent & Cosmetics, 2015, 45(6): 306-310.
[9]	QIU Zhao-min, PING A-li, WEI Xi-lian. Study of conductivity and rheological behaviors of cetyltrimethylammonium salicylate in aqueous solution [J]. China Surfactant Detergent & Cosmetics, 2014, 44(1): 1-5.