烯丙基二甲基烷基溴化铵的合成与性能研究

doi:10.13218/j.cnki.csdc.2015.11.004

Abstract

Abstract: Two kinds of allyldimethylalkylammonium bromide (C₁₆ and C₁₈) with different carbon chain length (n=16,18) were synthesized by using allyldimethylamine (ADMA) and 1-bromo linear alkanes as starting materials.The better synthetic conditions are as follows:acetone as the solvent;reaction temperature,65 ℃;reaction time,60 h;molar ratio of ADMA to 1-bromo alkane,1∶1.1~1.2.Yield of the product are 68.20% and 66.05% respectively.Their structures were characterized by IR,¹HNMR and elemental analysis.Their performance was measured,such as surface activity,water solubility and foaming,emulsifying and flocculating performance.Results showed that critical micelle concentration of the products (C₁₆ and C₁₈) is 5.5×10^-4 and 1.8×10^-4 mol/L respectively.Their corresponding surface tension is 33.5 and 32.4 mN/m respectively.The products display good surface properties.Krafft point is 8 and 21 ℃ respectively.The products display lower emulsifying power than that of sodium dodecyl sulfonate (SDS).The product C₁₆ displays significantly stronger foaming power and stronger flocculating capacity to kaolin than that of the product C₁₈.

Key words: quaternary ammonium salt, allyldimethylalkylammonium bromide, synthesis, performance

CLC Number:

TQ423.12

TAO Xian-ping, ZHANG Yue-jun. Synthesis and performance of allyldimethylalkylammonium bromide[J].China Surfactant Detergent & Cosmetics, 2015, 45(11): 616-620.

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Synthesis and performance of allyldimethylalkylammonium bromide

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