一种阳离子型氟表面活性剂的合成及性能研究

doi:10.13218/j.cnki.csdc.2015.11.003

Abstract

Abstract: A cationic fluorinated surfactant,C₈F₁₇(CH₂)₂CONH(CH₂)₃N⁺(CH₃)₃I^- (FTAI),was synthesized with perfluorooctyliodoethane (C₈F₁₇CH₂CH₂I) as starting material through a series of reactions,including Grignard reaction,acylchlorination,amidation and quaterization.Structure of the FTAI was characterized by IR,¹HNMR and ¹⁹FNMR.The surface tension,the contact angle on paraffin wax surface and the foaming power of FTAI aqueous solution and FTAI aqueous solution with 0.1 mol/L NaCl were measured.The results showed that this fluorinated surfactant exhibits excellent surface activity at room temperature.Its foaming power and wetting power were much higher than that of conventional cationic surfactant C₁₂H₂₅N⁺(CH₃)₃Cl^-.

Key words: fluorocarbon surfactant, quaternary ammonium salt, cationic surfactant, salt effect, foam

CLC Number:

TQ423.4

XIAO Zi-bing, XING Hang, XIAO Jin-xin. Synthesis and performance of a cationic fluorinated surfactant[J].China Surfactant Detergent & Cosmetics, 2015, 45(11): 611-615.

References

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Synthesis and performance of a cationic fluorinated surfactant

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