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日用化学工业（中英文）

日用化学工业 ›› 2014, Vol. 44 ›› Issue (3): 121-125.doi: 10.13218/j.cnki.csdc.2014.03.028

• 基础研究 •    下一篇

含羟基-磺酸基不对称表面活性剂的合成及表面活性

侯璐, 胡志勇, 姜欣欣, 菅丰田   

  1. 中北大学 化工与环境学院,山西 太原 030051
  • 收稿日期:2013-11-28 发布日期:2019-04-09
  • 作者简介:侯 璐(1988-),女,山西人,硕士研究生,电话:18234138634。

Synthesis and surface activity of dissymmetric surfactants containing a sulfonic and a hydroxyl group

HOU Lu, HU Zhi-yong, JIANG Xin-xin, JIAN Feng-tian   

  1. School of Chemical Engineering and Environment,North University of China,Taiyuan,Shanxi 030051,China
  • Received:2013-11-28 Published:2019-04-09

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摘要： 以三聚氯氰、氨基乙磺酸、乙醇胺和二正己胺、二正辛胺以及二异辛胺为原料合成出3种疏水结构不同的含羟基-磺酸基不对称表面活性剂(XSOHC6,XSOHC8和XSOHEC8),并用1HNMR,ESI-MS和元素分析对终产品进行了结构表征,结果与目标结构一致。采用吊片法测定目标产物的表面活性,运用稳态荧光探针法测定3种表面活性剂的临界胶束聚集数(Nm)。30 ℃下,XSOHC6,XSOHC8和XSOHEC8的cmc依次为8.1×10-4,2.1×10-6和8.5×10-5 mol·L-1,γcmc分别为33.0,27.6和28.2 mN·m-1,Nm分别为18,11和18。结果表明此类表面活性剂均具有较好的表面活性。

关键词: 不对称阴离子表面活性剂, 表面活性, 胶束聚集数

Abstract: Three dissymmetric surfactants containing a sulfonic and a hydroxyl group with different length of carbon chain (XSOHC6,XSOHC8 and XSOHEC8) were synthesized with cyanuric chloride,three different kinds of fatty amine,taurine and ethanolamine as starting materials.Structure of the targeted products was characterized by 1HNMR,ESI-MS and elemental analysis.Surface activity of the surfactants was measured by Wilhelmy plate method.The critical aggregation number of micelle (Nm) was determined by steady-state fluorescence probe method.The cmc of XSOHC6,XSOHC8 and XSOHEC8 is 8.1×10-4,2.1×10-6 and 8.5×10-5 mol·L-1,γcmc of them is 33.0,27.6 and 28.2 mN·m-1,and Nm of them is 18,11 and 18 respectively.The results of the study showed that such dissymmetric surfactants have rather good surface activity.

Key words: dissymmetric anionic surfactant, surface activity, aggregation number of micelle

中图分类号: 

  • TQ423.11