弱相互作用调控表面活性剂自组装(Ⅰ)——弱相互作用的分类

doi:10.13218/j.cnki.csdc.2018.11.002

摘要/Abstract

摘要： 表面活性剂是依靠分子间的弱相互作用实现自组装的,包括疏水相互作用、氢键作用力、主客体相互作用、静电相互作用、π-π堆积相互作用、金属配位相互作用和电荷转移相互作用等。通过调节分子间的相互作用可以实现对两亲分子自组装的调控,本文介绍了弱相互作用对两亲分子自组装形成有序分子聚集体结构和功能的影响。

关键词: 表面活性剂, 弱相互作用, 自组装, 聚集行为, 有序分子聚集体

Abstract: The self-assembly of surfactants relies on the weak interactions between molecules,including hydrophobic interaction,hydrogen bond interaction,host-guest interaction,electrostatic interaction,π-π stacking interaction,metal coordination interaction and charge transfer interaction.The self-assembly of amphiphilic molecules can be controlled by regulating the interaction between molecules.This paper introduces the influence of weak interactions on the structure and function of ordered molecular aggregates formed by self-assembly of amphiphilic molecules.

Key words: surfactants, weak interactions, self-assembly, aggregation behavior, ordered molecular aggregates

中图分类号:

TQ658

任姝静, 郑利强, 孙继超. 弱相互作用调控表面活性剂自组装(Ⅰ)——弱相互作用的分类[J]. 日用化学工业, 2018, 48(11): 611-616.

REN Shu-jing, ZHENG Li-qiang, SUN Ji-chao. Self-assembly of surfactants regulated by weak interaction (Ⅰ)The classification of weak interactions[J]. China Surfactant Detergent & Cosmetics, 2018, 48(11): 611-616.

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