一种聚羧酸盐共聚物的合成及其助洗性能研究

doi:10.3969/j.issn.1001-1803.2023.03.004

日用化学工业（中英文） ›› 2023, Vol. 53 ›› Issue (3): 271-278.doi: 10.3969/j.issn.1001-1803.2023.03.004

一种聚羧酸盐共聚物的合成及其助洗性能研究

高党鸽^1,^2,^3,^*(),李鹏宇^1,^2,³,于淑珍^4,⁵,刘伟^4,⁵,吕斌^1,^2,³

1.陕西科技大学轻工科学与工程学院，陕西西安 710021
2.西安市绿色化学品与功能材料重点实验室，陕西西安 710021
3.陕西科技大学轻化工程国家级实验教学示范中心，陕西西安 710021
4.长庆油田油气工艺研究院，陕西西安 710021
5.低渗透油气田勘探开发国家工程实验室，陕西西安 710021

收稿日期:2022-04-18 修回日期:2023-02-26 出版日期:2023-03-22 发布日期:2023-03-22
基金资助:
陕西省杰出青年科学基金项目(2020JC-47);陕西省“高层次人才特殊支持计划”青年拔尖人才项目;陕西省创新能力支撑计划(2021TD-16);轻化工助剂化学与技术教育部重点实验室开放基金(KFKT2019-01)

Synthesis and washing aid properties of a polycarboxylate copolymer

Gao Dangge^1,^2,^3,^*(),Li Pengyu^1,^2,³,Yu Shuzhen^4,⁵,Liu Wei^4,⁵,Lv Bin^1,^2,³

1. College of Bioresources Chemical & Materials Engineering, Shaanxi University of Science & Technology, Xi’an, Shaanxi 710021, China
2. Xi’an Key Laboratory of Green Chemicals and Functional Materials, Xi’an, Shaanxi 710021, China
3. National Demonstration Center for Experimental Light Chemistry Engineering Education, Shaanxi University of Science & Technology, Xi’an, Shaanxi 710021, China
4. Oil & Gas Tech Research Institute of Changqing Oilfield Company, Xi’an, Shaanxi 710021, China
5. National Engineering Lab for Exploration and Development of Low Permeability Oil-gas Field, Xi’an, Shaanxi 710021, China

Received:2022-04-18 Revised:2023-02-26 Online:2023-03-22 Published:2023-03-22
Contact: * Tel.: +86-13649255565, E-mail: dangge2000@126.com.

摘要/Abstract

摘要：

以环氧琥珀酸（ESA）、丙烯酸（AA）、烯丙基磺酸钠（SAS）和丙烯酸羟丙酯（HPA）为原料，通过溶液聚合法合成了聚羧酸盐共聚物Poly（ESA-AA-SAS-HPA）。采用FT-IR，¹H NMR，TG，DLS对其结构进行了表征。考察了螯合pH、温度及助剂质量分数等因素对Poly（ESA-AA-SAS-HPA）助洗性能的影响。结果表明：与三聚磷酸钠相比，其具有良好的助洗性能，鳌合量为308.7 mg/g、钙分散力为101.5 mg/g。同时，Poly（ESA-AA-SAS-HPA）与十二烷基苯磺酸钠（LAS）有良好的协同作用，可将体系表面张力降至45 mN/m。

关键词: 溶液聚合, 助洗, 聚羧酸盐

Abstract:

Poly（ESA-AA-SAS-HPA） was synthesized by solution polymerization from epoxy succinic acid （ESA）, acrylic acid （AA）, sodium allyl sulfonate （SAS） and hydroxypropyl acrylate （HPA）. It was characterized by FT-IR,¹H NMR, TG and DLS. The effects of chelating pH, temperature and additive mass fraction on the washing aid performance of Poly（ESA-AA-SAS-HPA） were investigated. The results show that, compared with sodium tripolyphosphate, it has good washing aid performance, with the chelating amount of 308.7 mg/g and the calcium dispersing power of 101.5 mg/g. Poly（ESA-AA-SAS-HPA） has good synergism with sodium dodecylbenzene sulfonate （LAS）, which can reduce the surface tension of the system to 45 mN/m.

Key words: solution polymerization, washing aid, polycarboxylate

中图分类号:

TQ423

高党鸽, 李鹏宇, 于淑珍, 刘伟, 吕斌. 一种聚羧酸盐共聚物的合成及其助洗性能研究[J]. 日用化学工业（中英文）, 2023, 53(3): 271-278.

Gao Dangge, Li Pengyu, Yu Shuzhen, Liu Wei, Lv Bin. Synthesis and washing aid properties of a polycarboxylate copolymer[J]. China Surfactant Detergent & Cosmetics, 2023, 53(3): 271-278.

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一种聚羧酸盐共聚物的合成及其助洗性能研究

Synthesis and washing aid properties of a polycarboxylate copolymer

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