无机盐对窄分布醇醚羧酸盐性能影响

doi:10.3969/j.issn.1001-1803.2020.02.004

Abstract

Abstract:

The effect of inorganic salt （NaCl, CaCl₂, MgCl₂, KCl, NH₄Cl, ZnCl₂） on the surface tension, wettability, foam, emulsification, decontamination and corrosion inhibition performance of narrow distribution alcohol ether carboxylate sodium （NAEC, EO number 3/5/7/9） aqueous solution were investigated. The results show that the inorganic salts have a significant influence on NAEC property. Inorganic salts significantly reduced the surface tension, and divalent salt had a better reduction effect than monovalent salt. The addition of inorganic salt could enhance the wetting effect on canvas, and the enhancement effect of CaCl₂and ZnCl₂was the strongest. In particular, ZnCl₂shortened the wetting time of NAEC9 from non-wetting to 173 s. Except for CaCl₂, which significantly enhanced foaming and foam stability, other chloride salts accelerated the collapse of the foam. NH₄Cl had the most significant effect on the emulsification of soybean oil. Inorganic salts were not good for the removal of black carbon and sebum stains, but good for the removal of protein stains. For NAEC5 with different EO numbers, the addition of 0.2% CaCl₂ reduced the wetting time from 27 s to 5 s.

Key words: NAEC, inorganic salt, performance, synergy effect

CLC Number:

TQ423.99

XU Fu-li,ZHANG Wei,WANG Feng-shou. Effect of inorganic salt on the properties of narrow distribution alcohol ether carboxylate[J].China Surfactant Detergent & Cosmetics, 2020, 50(2): 92-97.

Figures/Tables 8

Tab. 1

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Fig. 1

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Fig. 2

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Tab. 5

References 30

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无机盐	γ/（mN·m^-1）	t（润湿）/s	V（泡沫）/mL
无机盐	γ/（mN·m^-1）	t（润湿）/s	30 s	3 min	5 min
空白	44.7	10 min不润湿	300	210	150
NH₄Cl	39.7	10 min不润湿	350	80	50
NaCl	40.8	10 min不润湿	270	40	5
KCl	41.1	10 min不润湿	250	40	5
MgCl₂	37.8	10 min不润湿	350	100	50
CaCl₂	35.8	10 min不润湿	400	230	150
ZnCl₂	34.5	173	30	0	0

无机盐	R
无机盐	JB-01	JB-02	JB-03
空白	14.06	4.97	15.12
NH₄Cl	12.69	6.25	14.10
NaCl	8.98	5.49	13.90
KCl	12.62	5.46	13.73
CaCl₂	12.18	4.48	9.91
ZnCl₂	11.54	4.06	8.03

无机盐	m（失重量）/g	f_i /%
空白	0.156 2	/
无盐	0.045 2	71.1
NH₄Cl	0.043 0	72.5
NaCl	0.045 9	70.6
KCl	0.041 0	73.8
MgCl₂	0.039 3	74.8
CaCl₂	0.048 8	68.8
ZnCl₂	0.044 0	71.6

样品	t（空白）/s	w（CaCl₂）/%	t（润湿）/s
NAEC9	10 min未润湿	1	10 min未润湿
NAEC7	10 min未润湿	1	42
NAEC5	27	1	4
NAEC5	27	0.2	5

Effect of inorganic salt on the properties of narrow distribution alcohol ether carboxylate

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