China Surfactant Detergent & Cosmetics ›› 2026, Vol. 56 ›› Issue (8): 1062-1082.doi: 10.3969/j.issn.2097-2806.2026.08.011
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Kang Liu1,Jiuzheng Yu2,Guopeng Niu3,Chunsheng Wu2,Xiaochun Liu2,Yongli Yan1,*(
)
Received:2025-12-12
Revised:2026-07-30
Online:2026-08-22
Published:2026-09-02
Contact:
*E-mail: CLC Number:
Kang Liu, Jiuzheng Yu, Guopeng Niu, Chunsheng Wu, Xiaochun Liu, Yongli Yan. Blockage mechanisms and de-blockage technologies for the Lower Paleozoic carbonate gas reservoirs in the Ordos Basin[J].China Surfactant Detergent & Cosmetics, 2026, 56(8): 1062-1082.
Tab.1
Statistics of rock fabrics and lithologic types in the Ma-5 member, Jingbian field"
| Stratum | Micro-crystalline dolostone/% | Fine-crystalline dolostone/% | Calcareous mudstone/% | Dolomitic mudstone/% | Micro-crystalline limestone/% |
|---|---|---|---|---|---|
| Ma51+2 | 49.29 | 30.99 | 11.27 | 5.63 | 2.82 |
| Ma53+4 | 87.73 | 8.77 | 1.75 | 1.75 | 0 |
| Ma5 | 66.41 | 21.09 | 7.03 | 3.91 | 1.56 |
Tab.2
Pore-structure statistics for the Ma-5 member, Jingbian field"
| Sub-member | Inter-crystalline pores | Dissolution pores | Inter-crystalline- dissolution pores | Micro-fractures | Gypsum-mouldic pores | Intragranular pores | Mean areal porosity |
|---|---|---|---|---|---|---|---|
| Ma-51+2 | 39.06 | 27.1 | 19.71 | 7.26 | 5.47 | 1.4 | 5.7 |
| Ma-53+4 | 72.55 | 11.61 | 11.92 | 3.03 | 0.89 | 0.0 | 5.2 |
| Ma-5 | 33.48 | 29.68 | 21.01 | 7.97 | 6.23 | 1.63 | 5.9 |
| Mean pore diameter | 7.2 | 46.8 | 9.1 | 10.6 | 65 | 3.0 |
Tab.3
Equivalent pore-throat distribution statistics for core from well I, Yulin field"
| Equivalent pore-throat diameter/μm | Pore-volume proportions in core samples from well I, Yulin field/% | |||
|---|---|---|---|---|
| 1# | 2# | 3# | 4# | |
| 0-40 | 6.22 | 9.50 | 66.20 | 89.69 |
| 40-80 | 29.45 | 39.01 | 33.80 | 7.31 |
| 80-120 | 37.04 | 33.09 | 0 | 0 |
| 120-180 | 27.29 | 18.41 | 0 | 0 |
Tab.4
Petrophysical parameters of different reservoir types in the Ma-51+2 sub-member, southern Jingbian field"
| Reservoir class | Porosity/% | Permeability/×10-3 μm2 | ||||
|---|---|---|---|---|---|---|
| Max | Min | Mean | Max | Min | Mean | |
| Conventional | 8.97 | 0.23 | 2.61 | 3.442 | 0.004 | 0.184 |
| Fracture-dominated | 9.98 | 0.65 | 3.41 | 1 343.41 | 0.130 | 47.989 |
| Dissolution | 12.47 | 6.4 | 8.03 | 36.142 | 1.062 | 11.001 |
Tab.6
Elemental composition of blockage deposits from the well G50-6, Jingbian field"
| Parameter | Main component content/% | Fe3+/ % | Ca2+/ % | Mg2+/ % | SO42-/ % |
|---|---|---|---|---|---|
| Moisture | 0.37 | — | — | — | — |
| Oil | 0.84 | — | — | — | — |
| Organic matter (550 ℃) | 22.99 | — | — | — | — |
| Carbonate (950 ℃) | 3.44 | — | — | — | — |
| Acid-insoluble fraction | 15.22 | — | — | — | — |
| Acid-soluble fraction | 57.14 | 15.84 | 1.57 | 0.07 | 2.06 |
Fig.8
High-temperature, high-pressure relative-permeability curves for cores with permeabilities of 0.014×10-3 μm2 (a), 0.032×10-3 μm2 (b), 0.041×10-3 μm2 (c), 0.051×10-3 μm2 (d), 0.093×10-3 μm2 (e), and 0.150×10-3 μm2 (f) ;(g) relationship between core gas-phase permeability and water saturation[33]"
Tab.7
Characteristics and genesis of scaling in different gas fields of the Changqing area [35-38]"
| Gas field | Average salinity/ (mg/L) | Scale composition | Average content of acidic gas medium | Mechanisms of scale formation | |
|---|---|---|---|---|---|
| H2S | CO2 | ||||
| Jingbian | 40 000 | FeS and FeCO3 corrosion products; CaCO3 and related scale minerals; residual corrosion-inhibitor films | 1 000 mg/m3 | 5.0% | Accumulation of CO2/H2S corrosion precipitates on the tubing wall, accompanied by organic deposits |
| Yulin | 20 000 | Crystalline CaCO3 and MgCO3 salts with minor FeCO3 corrosion scale and trace hydrocarbon residues | — | 2.5% | Scaling ions in formation water-particularly Ca2+-become thermodynamically unstable under temperature and pressure fluctuation, precipitating as scale |
| Sulige | 80 000 | Scale dominated by BaSO4, SrSO4 with minor CaCO3 and CaSO4, intergrown with FeS and FeCO3 corrosion products | 1 500 mg/m3 | 6.0% | CO2/H2S corrosion precipitates inside the tubing; destabilization of scaling ions in formation water due to T-P variations; incompatibility among waters from different stratigraphic horizons leading to enhanced scaling propensity |
Tab.8
Analysis of corrosion-scale formation and blockage mechanisms in gas wells [39-41]"
| Scaling cause | Scale-blockage mechanism | Gas fields affected by this scaling |
|---|---|---|
| Salt scaling triggered by elevated formation-water salinity | Thermodynamic instability and chemical incompatibility render inorganic salts in the reservoir fluid supersaturated; once their solubility is exceeded, Ca2+, Mg2+, and minor Ba2+/Sr2+ readily combine with CO32-/HCO3- and SO42- anions to precipitate near the wellbore. The higher the salinity, the more severe the scaling | Jingbian - Yulin |
| Scaling driven by acid-gas (CO2, H2S) corrosion | Corrosive gases dissolved in the produced fluid react with Fe2+ in formation water to form insoluble FeS and FeCO3; HCO3- can likewise react with Fe to produce FeCO3 corrosion scale | Jingbian - Sulige |
| Blockage caused by residual corrosion inhibitors | At elevated temperatures, the volatile fractions of corrosion inhibitors vaporize, leaving high-boiling residues that undergo amidation. These highly viscous, water-insoluble residues readily agglomerate, adhering to tubing walls or accumulating at the well bottom | Jingbian - Sulige |
| Blockage caused by degraded foaming agents | During prolonged foamer injection, high-temperature/pressure conditions promote reactions between the foamer and hydrophilic species (Ca2+, Mg2+) in formation water, generating water-insoluble calcium and magnesium soaps that precipitate and obstruct flow paths | Jingbian - Yulin - Sulige |
Tab.9
Unblocking measures and operational parameters for a single well in the Ma-5 sub-member"
| Well | Producing interval | Location of obstruction | Pumping rate/ (m3/min) | Unblocking fluid volume/m3 | Operation duration/days | Incremental gas output/m3 |
|---|---|---|---|---|---|---|
| G31-022C4 | Ma-5 | Matrix | 1.2 | 40 | 1 | 1.5 |
| G63-9 | Ma-5 | Matrix + fractures | 1.5 | 45 | 1.5 | 1.6 |
| Sunan 25-971 | Ma-5 | Matrix + fractures | 1.4 | 40 | 2 | 1.9 |
| G37-021C4 | Ma-5 | Matrix + fractures | 1.6 | 38 | 1 | 1.8 |
Tab.10
Dissolution efficiency of de-blockage formulations at different blend ratios in the Jingbian field"
| Sample | Reagent dosage/g | Weight before reaction/g | Weight after reaction/g | Material dissolved/g | Dissolution efficiency/% |
|---|---|---|---|---|---|
| XM-5+WPLJD-01 | 60 | 20 | 1.66 | 18.34 | 91.7 |
| XM-5 | 60 | 20 | 2.63 | 17.37 | 86.85 |
| WPLJD-01 | 60 | 20 | 5.68 | 14.32 | 71.6 |
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