支链扩展表面活性剂与两性和阳离子表面活性剂复配性能

doi:10.3969/j.issn.2097-2806.2024.12.001

Abstract

Abstract:

2-Hexyl-1-decanol was used as the main material to prepare a block-polyether sulfonate extended surfactant （IC₁₆P₆E₆S）. The solubility and surface active properties of IC₁₆P₆E₆S were evaluated, and then the IC₁₆P₆E₆S was mixed with a cationic surfactant hexadecyl trimethyl ammonium bromide （CTAB） and a zwitterionic betaine surfactant （HAB）, respectively. The effects of mixing ratios of IC₁₆P₆E₆S∶HAB and IC₁₆P₆E₆S∶CTAB on the hydrodynamic diameter and interfacial properties were discussed. The emulsification, adsorption and laboratory core displacement experiments of the binary system were tested. The results showed that the critical micelle concentration （cmc） of IC₁₆P₆E₆S in distilled water was 0.1 mmol/L and the surface tension at cmc （γ_cmc） was 28.53 mN/m. IC₁₆P₆E₆S showed strong synergistic effects with HAB and CTAB, and the mixed systems could effectively reduce the interfacial tension compared with single surfactants. The mixed systems with n （IC₁₆P₆E₆S） ∶n （HAB） of 1∶1 and n （IC₁₆P₆E₆S） ∶n（CTAB） of 1∶3 could maintain ultra-low interfacial tension （in the order of magnitude of 10^-3 mN/m） in the salinity range of 1%-7% NaCl and low interfacial tension （in the order of magnitude of 10^-2 mN/m） in the salinity range of 3%-7% NaCl, respectively. With the increase of salinity, the emulsion formed by the mixed surfactant system underwent the phase transition process from Winsor Ⅰ to Winsor Ⅲ and then to Winsor Ⅱ. The emulsion of mixed IC₁₆P₆E₆S/HAB system had more middle-phase emulsion volume than that of the mixed IC₁₆P₆E₆S/CTAB system, and the former emulsion system was more stable. The mixed IC₁₆P₆E₆S/HAB system also had good solubilization effect, and the amount of oil solubilization was up to 43 mL/g. Meanwhile, it had good adsorption resistance. Compared with water flooding, the depressurization rate could reach 25.00% and the recovery could be enhanced by 11.75%, indicating that the IC₁₆P₆E₆S/HAB system was more conducive to the depressurization and injection enhancement for low-permeability reservoirs.

Key words: extended surfactant, interfacial tension, adsorption property, dynamic light scattering, depressurization and enhanced injection

CLC Number:

TQ423

Xiaoding Zeng, Yancheng Zheng, Guoqing Zhang, Lingchi Zeng, Jian Mu. Performance of branched-chain extended surfactant mixed with zwitterionic or cationic surfactant[J].China Surfactant Detergent & Cosmetics, 2024, 54(12): 1405-1413.

Figures/Tables 13

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References 31

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n（IC₁₆P₆E₆S） ∶n（HAB）	Diameter/nm	Polydispersity （PDI）
0∶1	157.1	0.139
1∶3	116.9	0.558
1∶1	97.68	0.205
3∶1	110.6	0.225
1∶0	157.2	0.177

n（IC₁₆P₆E₆S） ∶n（CTAB）	Diameter/nm	Polydispersity （PDI）
0∶1	224	0.241
1∶3	181	0.308
1∶1	206	0.124
3∶1	190	0.335
1∶0	157	0.177

Performance of branched-chain extended surfactant mixed with zwitterionic or cationic surfactant

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