流变调节剂对W/O型乳液稳定性和流变性的影响

doi:10.3969/j.issn.1001-1803.2022.05.001

Abstract

Abstract:

W/O emulsions were prepared by homogeneous emulsification method. The effects of water-soluble polymers （xanthan gum and sodium hyaluronate）and oil-phase thickeners （glyceryl behenate and dimethyl distearyl ammonium lithium-montmorillonite） on the stability and rheological properties of W/O emulsions were studied. The experimental results showed that the stability of W/O emulsions was decreased under different stability testing conditions after the addition of xanthan gum. When sodium hyaluronate was added, the storage stability of the emulsion was decreased at room temperature, but the storage stability at high temperature was improved. The storage stabilities at room temperature and high temperature were both increased when glyceryl behenate was added to the W/Oemulsions. With the addition of dimethyl distearyl ammonium lithium-montmorillonite, the stability of the emulsion was enhanced under different conditions. After the addition of water-soluble polymers, the water-phase viscosity was increased, but the apparent viscosity of W/O emulsions was significantly decreased and the range of linear viscoelastic region became narrow. This might be due to the increased viscosity of the inner water phase which prevented the adsorption of emulsifier molecules at the oil/water interface. The apparent viscosity and linear viscoelastic region of W/Oemulsions were both increased with the addition of oil-phase thickeners, which might be related to the decrease of emulsion droplet size and the change of oil-water interface energy. In addition, the hysteresis loop area of emulsions was decreased to different extent with the addition of rheological modifiers.

Key words: rheological modifier, W/O emulsion, stability, rheology

CLC Number:

O648.23

Dong Leilei,Huang Tianyi,Duan Guolan,Chen Hanjun,Zhang Wanping,Zhang Qianjie. Effects of rheological modifiers on the rheological properties and stability of W/O emulsions[J].China Surfactant Detergent & Cosmetics, 2022, 52(5): 457-467.

Figures/Tables 13

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References 23

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配方编号	组分名称	w/%
A相	角鲨烷	4
	辛酸/癸酸甘油三酯	15
	霍霍巴籽油	3
	乳木果油	4
	聚甘油-2二聚羟基硬脂酸酯	4
B相	水	至100
B相	甘油	6
C相	防腐剂	0.2

储存条件		稳定性
储存条件		0	0.05%	0.10%	0.15%	0.20%
室温	1天	+++++	+++++	+++++	+++++	+++++
室温	7天	++++	+++	+++	+++	+++
低温	1次循环	++++	++++	++++	++++	++++
	2次循环	+++	++	++	++	++
	3次循环	+++	++	++	++	++
高温	1天	++++	++++	++++	++++	++++
	3天	+++	+++	+++	++	++
	7天	++	++	+	+	+

储存条件		稳定性
储存条件		0	0.05%	0.10%	0.15%	0.20%
室温	1天	+++++	+++++	+++++	+++++	+++++
室温	7天	++++	++++	+++	+++	+++
低温	1次循环	++++	++++	++++	++++	++++
	2次循环	+++	++	++	++	++
	3次循环	++	+	++	++	++
高温	1天	++++	+++++	+++++	+++++	+++++
	3天	+++	+++	+++	+++	+++
	7天	++	+++	+++	+++	+++

储存条件		稳定性
储存条件		0	0.50%	1.00%	1.50%
室温	1天	+++++	+++++	+++++	+++++
室温	7天	++++	++++	++++	++++
低温	1次循环	++++	++++	+++	+++
	2次循环	+++	+++	++	++
	3次循环	+++	++	+	+
高温	1天	++++	++++	++++	++++
	3天	+++	+++	+++	+++
	7天	++	++	+++	+++

储存条件		稳定性
储存条件		0	0.30%	0.60%	0.90%
室温	1天	+++++	+++++	+++++	+++++
室温	7天	++++	+++++	+++++	+++++
低温	1次循环	++++	++++	++++	++++
	2次循环	+++	+++	+++	+++
	3次循环	+++	+++	+++	+++
高温	1天	++++	+++++	+++++	+++++
	3天	+++	+++++	+++++	+++++
	7天	++	+++++	++++	++++

Effects of rheological modifiers on the rheological properties and stability of W/O emulsions

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流变调节剂类型	滞后环面积/（Pa/s）
未加流变调节剂	267.56
黄原胶	165.00
透明质酸钠	48.95
山嵛酸甘油酯	121.50
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