纤维型黏土在日化领域的应用研究进展

doi:10.3969/j.issn.1001-1803.2022.03.011

Abstract

Abstract:

Fiber-type clays, including sepiolite and palygorskite （also wknown as attapulgite）, are a type of natural one-dimensional clay mineral with fibrous crystal structure and water-rich magnesium aluminosilicate. China has the largest mineral reserves of attapulgite in the world, about 460 million tons of proven reserves, accounting for more than 70% of the world’s total reserves. Special crystal structures （rods, fibers or fiber assemblies） and neatly arranged nano-pores endow fiber-type clays with excellent ion exchange capacity, adsorption properties, rheological regulation and carrier functions, which hold enormous potential to be exploited for application in the field of daily chemistry. In recent years, the application of fiber clay in personal care products, detergents and other daily chemical consumer products is growing rapidly. Attapulgite has been used as a natural mineral ingredient in toothpaste, facial mask, face cream, shampoo and facial cleanser for oil controlling, skin cleansing and anti-microbial functionalities. In this paper, the application characteristics and related mechanisms of fiber-type clay minerals in daily chemical industry are reviewed from the aspects of rheological modification, UV protection, coloration, bacteriostasis, anti-inflammation, controlled adsorption and release as well as the related toxicological issues. The current problems and challenges of fiber-type clays in daily chemical industry are summarized, which provide important references for Chinese researchers to make full use of this type of characteristic clay minerals and to further develop high-tech and high-value daily chemical products.

Key words: fiber-type clay, sepiolite, palygorskite, attapulgite, daily chemical products

CLC Number:

TQ658

Tang Ying,Zhang Zhaolun,Cao Lihua,Xiong Ziyi,Zhang Xi,Feng Yongjun. Research progress on application of fiber-type clays in daily chemical industrial products[J].China Surfactant Detergent & Cosmetics, 2022, 52(3): 302-308.

Figures/Tables 2

References 45

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名称	结构式	颜色	比表面积/（m²/g）	纤维长度/μm	成矿及形貌特点	国内分布
海泡石	Si₂O₃₀Mg₈（OH） ₄（OH₂） ₄·8H₂O	白色、浅灰色	300	长1~10,宽约0.01	沉积-风化产物,外观光滑,长径比较大,结晶度高,多呈纤维状或纤维集合体	湖南、河南、河北、江西
坡缕石/凹凸棒石	Si₈Mg₅O₂₀（OH） ₂（OH₂） ₄·4H₂O	白色、浅褐色	150~210	坡缕石：长0.5~5,宽0.05~0.15; 凹凸棒石：长1~2,宽0.1~0.5	坡缕石：水热蚀变反应产物,外观柔软,结晶度好,纤维较长,多呈纤维状或纤维集合体; 凹凸棒石：沉积产物,外观致密如黏土,结晶度差,纤维较短,多呈棒状	甘肃、贵州、江苏、安徽

Research progress on application of fiber-type clays in daily chemical industrial products

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