9, 10-二羟基硬脂酸钠的性能研究

doi:10.3969/j.issn.1001-1803.2022.01.001

Abstract

Abstract:

Sodium 9,10-dihydroxystearate （SDHS） was synthesized from oleic acid and hydrogen peroxide. Compared with the traditional method for preparing SDHS, this synthetic method had the advantages of short reaction time, high efficiency, no waste water, and low environmental pollution. The product was characterized by ¹H-NMR, mass spectroscopy, GC and HPLC. The surface tension, detergency and the emulsifying, foaming and wetting properties of SDHS were studied. The results show that the SDHS synthesized by this method has higher purity; SDHS has good surface-active performance; the emulsifying ability of SDHS is better than those of sodium stearate and sodium oleate; it can stabilize O/W emulsions at low concentrations. Compared with traditional anionic surfactants, SDHS has poor foaming performance. SDHS is a kind of low-foaming surfactant and has poor foam stability. SDHS has good wetting performance, and its wetting power is better than sodium oleate and sodium stearate. The detergency experiment shows that SDHS has better cleaning performance, especially for sebum stained cloth. SDHS is suitable to be used in various detergent formulations.

Key words: oleic acid, hydroxystearic acid, wetting, detergency

CLC Number:

TQ423

Huang Siyu,Jiang Jianzhong,Cui Zhenggang. Study on the performance of sodium 9, 10-dihydroxystearate[J].China Surfactant Detergent & Cosmetics, 2022, 52(1): 1-6.

Figures/Tables 11

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References 15

[1]	Zhang H. The development of detergents and the demand for grease-based surfactants[J]. Beijing Daily Chemical, 2013, 2:31-37.
[2]	Ren X R, Niu J P, Han Y M. Oil based surfactants in the application of mineral flotation[J]. China Detergent Industry, 2009, 5:49-50.
[3]	Zhang G Y, Li Q X. The research and development of Chinese surfactants based on oil and fat[J]. Detergent & Cosmetics, 2001, 24(1) : 1-5.
[4]	Plietker B, Niggemann M. An improved protocol for the RuO₄-catalyzed dihydroxylation of olefins[J]. Organic Letters, 2003, 5(18) : 3353-3356. pmid: 12943425
[5]	Zhang M, Selvakumar, Zhang X, et al. Structural and solubility parameter correlations of gelation abilities for dihydroxylated derivatives of long-chain, naturally occurring fatty acids[J]. Chemistry-A European Journal, 2015, 21(23) : 8530-8543. doi: 10.1002/chem.v21.23
[6]	Amatjang S, Xiamusikamar, Ayiaxiamu, et al. Synjournal of trans-9,10-dihydroxystearic acid[J]. Fine Chemicals, 2009, 26(7) : 724-728.
[7]	Chen A M, Cheng Q L, Ji F, et al. Preparation of methyl-9 (10) -hydroxy-10 (9) -methoxystearate from methyl-9,10-epoxystearate[J]. Applied Chemical Industry, 2016, 45(4) : 649-656.
[8]	Zhang L. Preparation and properties of oleic acid derived multifunctional surfactants[D]. Taiyuan: China Daily Chemical Industry Research Institute, 2009.
[9]	Yu X M, Zhang Y H, Liu Y H, et al. Effects of 9,10-dihydroxysteatic acid on gulcose metabolism in KKAy mice[J]. Health Research, 2010, 39(4) : 423-425.
[10]	Cheng S Y, Guo X C, He Y, et al. Preparation and rheological properties of lithium grease based on 9,10-dihydroxysteatic acid[J]. Journal of Chongqing University of Technology, 2018, 32(10) : 121-126.
[11]	Yan S X, Tan L L, Tong M W, et al. Synjournal and application of zinc dihydroxystearate[J]. Plastic Additives, 2017, 6:22-24.
[12]	Zhang L, Sun Y Q, Di S M. Synjournal and properties of 9,10-dihydroxystearic acid ethoxylate[J]. Tenside Surfactants Detergents, 2019, 56(3) : 237-243. doi: 10.3139/113.110621
[13]	Dierker M, SchaFer H J. Surfactants from oleic, erucic and petroselinic acid: Synjournal and properties[J]. European Journal of Lipid Science & Technology, 2010, 112(1) : 122-136.
[14]	Feng Z P. Study of detergent solution, cleaning and rinse behavior in washing machine[D]. Wuxi: Jiangnan University, 2012.
[15]	Zhao X, Hu X Y, Fang Y, et al. Unique physicochemical properties of sodium 9,10,12,13-tetrahydroxyl stearate in cold hard water and under neutral pH condition[J]. Fine Chemicals, 2013 (9) : 57-61.

样品	初始泡沫高度/mL	5 min后泡沫高度/mL
SDHS	0	0
SDS	14.0	14.0
SDBS	16.0	16.0
硬脂酸钠	7.0	6.5

样品	沉降所需时间/s
AEO9	36
SDHS	3 215
硬脂酸钠	>7 200
油酸钠	4 034

洗涤剂名称	去污力
洗涤剂名称	炭黑污布	蛋白污布	皮脂污布
标准洗衣液	12.05	4.48	6.01
SDHS	17.75	8.09	22.29
硬脂酸钠	10.39	3.22	3.64
油酸钠	15.84	5.18	19.27
SDBS	16.65	4.02	10.91

Study on the performance of sodium 9, 10-dihydroxystearate

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