连接基为2-羟丙基系列季铵盐双子表面活性剂的性能研究

doi:10.13218/j.cnki.csdc.2015.06.005

Abstract

Abstract: A Series of quaternary ammonium Gemini surfactants,8-3(OH)-8,8-3(OH)-12,8-3(OH)-16,12-3(OH)-12 and 16-3(OH)-16 were synthesized using epoxy chloropropane and various alkyl tertiary amines as starting materials.Surface activity,forming performance at various pH conditions,and emulsifying properties were investigated.The critical micelle concentration (cmc) of the five kinds of surfactant are 12.3×10^-5,15.5×10^-5,6.8×10^-5,2.9×10^-5 and 1.2×10^-5 mol/L respectively,and their equilibrium surface tension (γ_cmc) are 46.04,37.20,39.61,39.34 and 38.12 mN/m respectively.The surfactant 8-3(OH)-12 displays outstanding foaming and emulsifying properties in both neutral and acidic condition (pH=2).The foam performance and emulsifying property of these Gemini surfactants could be promoted greatly under acidic condition.

Key words: Gemini surfactant, quaternary ammonium salt, performance

CLC Number:

TQ423.12

YU Peng-ming, ZHANG Wei, WANG Feng-shou, DONG Wan-tian. Properties of a series of bis(quaternary ammonium) Gemini surfactant with 2－hydroxypropyl group as spacer[J].China Surfactant Detergent & Cosmetics, 2015, 45(6): 319-322.

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Properties of a series of bis(quaternary ammonium) Gemini surfactant with 2－hydroxypropyl group as spacer

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